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HomeMy WebLinkAboutECS Revised Sandmine GW Report 2-27-19REPORT OF ENVIRONMENTAL ASSESSMENT CASTLE HAYNE – SAND MINE 4117 CASTLE HAYNE ROAD CASTLE HAYNE, NEW HANOVER COUNTY, NORTH CAROLINA ECS PROJECT 49:8748 PREPARED FOR: HILTON PROPERTIES, LLC REVISED FEBURARY 27, 2019 Revised February 27, 2019 Ms. Jennifer Martin and Mr. David Fort Hilton Properties, LLC 404 Fairway Road Myrtle Beach, South Carolina 29572 Reference: Report of Environmental Assessment Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Dear Ms. Martin and Mr. Fort: ECS Southeast, LLP (ECS) is pleased to provide Hilton Properties, LLC with the results of our Environmental Assessment for the above-referenced site. ECS’s services were provided in accordance with ECS proposal No. 49:12920P dated January 22, 2019 and the accepted Terms and Conditions dated January 28, 2019. ECS appreciates the opportunity to provide our services to you. If there are questions regarding this report, or a need for further information, please contact us. Respectfully submitted, ECS SOUTHEAST, LLP Sarah Kordon Fraser Environmental Staff Project Manager skordon@ecslimited.com 919-616-8145 Matthew H. McDuffie, P.G. Principal Geologist mmcduffie@ecslimited.com 704-525-5152 Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 1 TABLE OF CONTENTS 1.0 PROJECT INFORMATION .................................................................................................................... 1 2.0 SCOPE OF SERVICES ............................................................................................................................ 1 3.0 ASSESSMENT RESULTS ....................................................................................................................... 3 4.0 CONCLUSIONS .................................................................................................................................... 4 5.0 RECOMMENDATIONS ......................................................................................................................... 4 6.0 QUALIFICATIONS OF REPORT ............................................................................................................. 4 FIGURES Figure 1 Topographic Location Map Figure 2 Groundwater Sample Location Map TABLES Table 1 Summary of VOC Results in Groundwater Table 2 Summary of Inorganic Results in Groundwater APPENDICES Appendix A Photograph Log Appendix B GW-1 Forms – Well Construction Records Appendix C GW-30 Form – Well Abandonment Record Appendix D Laboratory Analytical Data and Chain of Custody (COC) Record 1 Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 1.0 PROJECT INFORMATION The site consists of vacant wooded acreage along the western-most portion of an approximately 63-acre land tract near Sledge Road and Castle Hayne Road in Castle Hayne, New Hanover County, North Carolina (Figure 10. The New Hanover County Geographic Information Systems (GIS) identifies the property with parcel identification number (PIN) R00900-001-002-000 and indicates the property is owned by Hilton Properties Limited Partnership and is addressed as 4117 Castle Hayne Road. ECS further understands that proposed redevelopment incudes the use of the site as a sand mine. ECS has been requested to assess groundwater quality on the western-most portion, deemed ‘Phase I,’ of proposed sand mine development in relation to known areas of contamination in the portion deemed ‘Phase II.’ The areas depicted as Phase I and Phase II are included in Figure 2. Project information was obtained from conversations between Mr. William Toole of Robinson Bradshaw and ECS. ECS conducted a previous geotechnical engineering assessment of the property (ECS Project 22:26252 Dated February 6, 2018). The report described current site conditions as moderately wooded with a path around the perimeter with a cleared portion near the northern corner of the site. Groundwater depths measured at the time of geotechnical drilling ranged from 12.5 to 22.0 feet below ground surface (bgs). However, the groundwater levels may have been influenced by the use of drilling fluids. ECS also was provided a copy of the 2017 Annual Water Monitoring Report of the Northwest Site Area of the General Electric/Global Nuclear Fuel (GE/GNF) Site, which is located adjacent to the subject site (Amec Foster Wheeler Environment & Infrastructure, Inc. (Amec Foster Wheeler) Project 6550-16- 0001.02 dated May 22, 2018). The northwest site area is situated more than one mile from the active portion of the GE/GNF facility and the Northeast Cape Fear River. There are two areas of concern in the Northwest Site Area. These areas include the Former Calcium Fluoride Storage Area and the Former Lubricants Storage Area, as shown in Figures 1 and 2. These former storage areas were operated in the 1960s and 1970s and were subsequently removed upon cessation of operations. The former operations resulted in the unintended release of volatile organic compounds (VOCs), fluoride, and uranium to soils. The sources of the releases were either removed through excavation, or have depleted over time through natural attenuation. On behalf of GE/GNF, Amec Foster Wheeler conducted semiannual sampling events of 14 wells conducted in January and August 2017 with seven additional wells sampled annually in August in the Northwest Site Area. The 2017 monitoring results were generally consistent with previous monitoring and assessment results. Amec Foster Wheeler reported that the 2017 groundwater sampling and analysis data indicated that the concentrations are generally stable and attenuating through natural processes. Groundwater flow has been measured to flow to the north- northwest – towards adjacent swampy areas off-site – encroaching on to the subject site. Water samples were collected for analysis of VOCs from five groundwater monitoring wells and three surface water sampling locations near the former lubricants area. Numerous VOCs including vinyl chloride, cis-1,2-dichloroethylene, and trichloroethylene were detected above laboratory reporting limits or their respective NCAC 2L groundwater quality standard (NC2LGWQS) on-site and off-site. 2 Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 Fluoride was detected in groundwater from well CAF-6B (2.3 milligrams per liter (mg/L)) in January 2017 and 2.6 mg/L in August 2017) and from well CAF-8B (2.3 mg/L in August) in excess of the 2 mg/L NC2LGWQS. CAF-6B is located immediately north of the former storage area and CAF-8B is located to the east CAF-6B on the Northwest Site Area. Of the 21 groundwater samples collected and analyzed for uranium, one sample from well CAF-7A at 0.06 mg/L was found to exceed the project-specific guideline value for the site of 0.045 mg/L. The uranium results for the two downgradient wells indicate that OCW-4A and OCW-4B (located off the property), did not exceed the 0.045 mg/L value, indicating that uranium is not migrating off of the property. Twelve of the 21 samples were measured for isotopic uranium. These 12 samples were found in excess of the natural abundance of 235U. These samples were collected from wells CAF-6A, CAF-6B, CAF-7A, CAF-8A, CAF-8B, CAF-12A, and OCW-4B. Historical data indicates uranium concentration trends have been relatively stable over time. These trends were consistent with the understanding that uranium is relatively immobile and remain at low concentrations in the Northwest Site Area. The report concluded that results demonstrated no evidence of new chemical releases and that human health and protection of the environment has been achieved and the current concentrations are not predicted to pose a significant threat to human health or the environment. ECS has been requested to sample groundwater at the Phase I proposed sand mine to assess for potential impacts from the adjacent GE/GNF Former Calcium Fluoride Storage Area and the Former Lubricants Storage Area. 2.0 SCOPE OF SERVICES The environmental assessment consisted of collecting groundwater samples. However, ECS originally proposed the collection of groundwater samples using a Geoprobe® by a subcontractor: Quantex, LLC, however, several paths transecting the site were altered by recent precipitation events. Due to the access limitations for the heavy drilling machinery, the temporary groundwater monitoring wells were advanced manually utilizing a decontaminated hand auger by Quantex, LLC on January 30, 2019. A photograph log documenting field activities is provided in Appendix A. 2.1 Public Utility Locate Prior to implementing the field activities, ECS contacted North Carolina One Call to locate/mark public utilities at the site. Required separation distances between subsurface activities and marked utilities (typically 30-inches) were maintained during the field activities. 2.2 Temporary Monitoring Well Installation and Abandonment Activities ECS supervised the manual installation of five temporary monitoring wells (TMW-1 through TMW-5) to collect five groundwater samples from the Phase I area at the subject site. Temporary monitoring wells TMW-1 through TMW-3 were installed in central wooded positions. Temporary monitoring well TMW-4 was installed near the down-gradient clearing at the northern portion of the subject site. Temporary monitoring well TMW-5 was installed near the Phase I/II boundary and property boundary shared by the adjacent GE/GNF property near the Former Calcium Fluoride Storage Area. The locations of the temporary monitoring wells are shown on Figure 2. Monitoring Well Construction Forms are included in Appendix B. 3 Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 Temporary monitoring wells TMW-1, 2, and 5 were installed to a total depth of 20 feet bgs., temporary monitoring well TMW-3 was installed to a depth of 15 feet bgs., and temporary monitoring well TMW-4 was installed to a depth of 6 feet bgs. The temporary wells were constructed with one-inch inner diameter Schedule 40 PVC flush-threaded casing and screen. The PVC screen and casing were lowered into the open borehole. Lengths of slotted well screen with machined 0.010-inch slot widths and a threaded bottom plug were installed at the bottom of each well. A solid section of PVC casing was placed above the screened interval and extended to a point just above the ground surface. The annular space around each well was filled with a washed and graded, medium sand to approximately two feet above the top of the screen. Groundwater was encountered at depths ranging from 1.52 feet bgs to 16.61 feet bgs, as relatively gauged from the top of casing. Following the completion of the groundwater gauging and sampling activities, temporary monitoring well borings were properly abandoned and grouted. Copies of the well abandonment forms are included in Appendix C. 2.3 Groundwater Sample Collection Groundwater was purged and sampled subsequent to being pumped to the surface using a peristaltic pump with dedicated disposable polyethylene tubing lowered through the temporary monitoring well casing. Groundwater samples TMW-1 through TMW-5 were placed directly into laboratory prepared containers at each sample location. Groundwater sample containers were labeled with ECS project number, sample identification, sample date and time, and requested analytical analysis. The containers were properly packaged and placed into a cooler with ice to maintain the samples at approximately 4° Celsius (C°). Groundwater samples were submitted for chemical analysis for VOCs using EPA method 8260, fluoride using EPA method 300.0, total uranium using ASTM Standard D5174, and isotopic uranium using HSL 300. Groundwater laboratory analysis was conducted by Pace Analytical Services, LLC (Pace) located in Huntersville and Asheville, North Carolina and Greensburg, Pennsylvania. ECS maintained proper COC procedures throughout the sample collection and transportation process. Copies of the COCs are included in Appendix D. 3.0 ASSESSMENT RESULTS •Laboratory analysis of the groundwater samples collected from temporary monitoring wells TMW-1 through TMW-5 did not report detections of VOCs above laboratory reporting limits. •Laboratory analysis of the groundwater samples collected from temporary monitoring wells TMW-1 through TMW-3 did not report detections of fluoride above laboratory reporting limits. Fluoride was detected at 0.36 and 0.39 mg/L in the groundwater samples collected from temporary monitoring wells TMW-4 and TMW-5, respectively, below the NC2LGWQS of 2 mg/L. o ECS notes that the presence of fluoride in groundwater is the result of natural and/or anthropogenic sources. Natural sources are associated to the geological conditions of an area. Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 4 •Laboratory analysis of the groundwater samples collected from temporary monitoring wells TMW-1 through TMW-5 reported detectable concentrations of uranium in groundwater ranging from 0.000138 mg/L to 0.00711 mg/L, below the Environmental Protection Agency (EPA) maximum contaminant level (MCL) for National Primary Drinking Water Regulations for uranium of 0.03 mg/L. A summary of the groundwater analytical results are provided on Tables 1 and 2. The laboratory analytical package is included in Appendix D. 4.0 CONCLUSIONS Based on the results of the field activities and laboratory analysis, the detected concentrations of inorganic compounds such as fluoride and uranium, in areas where assessed, were not reported at concentrations exceeding their regulatory standards. VOCs were not detected at concentrations above laboratory reporting limits in each of the groundwater samples. The concentrations of fluoride and uranium, in areas where assessed, are considered consistent with the findings of the 2017 Annual Water Monitoring Report of the Northwest Site Area of the General Electric/Global Nuclear Fuel (GE/GNF) Site, which concluded that analytical results did not demonstrate evidence of a significant threat to human health or the environment. 5.0 RECOMMENDATIONS Based on the results of the environmental assessment, ECS recommends the following: •A copy of this report should be shared with property owners. •Based on a review of available historical data as well as the findings of this report, no further assessment appears warranted at this time. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in environmental assessment projects of this type. Our evaluation of site conditions has been based on our understanding of the site project information and the data obtained during our field activities. This report was prepared for the express use of Hilton Properties, LLC. Use of this report by other individuals or companies implies their acceptance of the General Conditions of Service of the original contract. Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 5 FIGURES TMW-2 PHASE I FIGURE 1 TOPOGRAPHIC LOCATION MAP CASTLE HAYNE – SAND MINE 4117 CASTLE HAYNE ROAD CASTLE HAYNE, NEW HANOVER COUNTY NORTH CAROLINA ECS PROJECT 49:8748 SOURCE: 2017 Annual Water Monitoring Report (AMEC REPORT DATED MAY 22, 2018) TMW-1 Approximate Location of Former Calcium Fluoride Storage Area (Granted Unrestricted Area by at U.S. NRC in 2000) Approximate Location of Former Lubricants Storage Area PHASE II SITE TMW-3 TMW-4 TMW-5 TMW-2 PHASE I FIGURE 2 GROUNDWATER SAMPLE LOCATION MAP CASTLE HAYNE – SAND MINE 4117 CASTLE HAYNE ROAD CASTLE HAYNE, NEW HANOVER COUNTY NORTH CAROLINA ECS PROJECT 49:8748 SOURCE: NEW HANOVER COUNTY GIS 2016 TMW-1 Approximate Location of Former Calcium Fluoride Storage Area (Granted Unrestricted Area by at U.S. NRC in 2000) LEGEND Approximate Location of Temporary Monitoring Well (TMW) Approximate Location of Former Lubricants Storage Area PHASE II SITE TMW-3 TMW-4 TMW-5 Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 6 TABLES Sample ID TMW-1 TMW-2 TMW-3 TMW-4 TMW-5 Sample Date Method (Parameter) Targeted VOC Analytes ND ND ND ND ND -- Notes: ND = Not Detected VOC = Volatile Organic Compounds NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 GCL = NCDEQ's Gross Contamination Levels for Groundwater as of April 16, 2012 1/30/2019 NC2LGWQS GCL EPA Method 8260 TABLE 1 SUMMARY OF VOC RESULTS IN GROUNDWATER CASTLE HAYNE – SAND MINE 4117 CASTLE HAYNE ROAD CASTLE HAYNE, NEW HANOVER COUNTY, NORTH CAROLINA ECS PROJECT: 49:8748 Sample ID TMW-1 TMW-2 TMW-3 TMW-4 TMW-5 Sample Date Method (Parameter) Fluoride ND ND ND 0.36 0.39 2 - Method (Parameter) Total Uranium 0.000138 0.00388 0.00711 0.00497 0.00355 -0.03 Method (Parameter) Uranium-234 0.000141 0.002475 0.004965 0.002865 0.003720 -- Uranium-235 0.000065 0.000164 0.000378 0.000266 0.000299 -- Uranium-238 0.000057 0.002295 0.004830 0.002655 0.003090 -- Notes: Results are presented in milligrams per liter (mg/L) NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013 EPA MCL - Environmental Protection Agency Maximum Contaminant Level for National Primary Drinking Water Regulatio pCi/L have been converted to mg/L for data illustraion purposes. *** = Uranium 235 isotopic abundance is calculated by dividing the 235U concentration by the total uranium concentrati NE = Not Established ND = Not Detected Values shown in the bold font exceed their respective water quality standard. 1/30/2019 TABLE 2 SUMMARY OF INORGANIC RESULTS IN GROUNDWATER CASTLE HAYNE – SAND MINE 4117 CASTLE HAYNE ROAD CASTLE HAYNE, NEW HANOVER COUNTY, NORTH CAROLINA ECS PROJECT: 49:8748 ASTM D5174 EPA Method 300.0 HSL-300 NC2LGWQS EPA MCL Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 7 APPENDIX A SITE PHOTOGRAPHS Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Photograph 1: View of the monitoring wells (presumably OCW-4A and OCW-4B) located on Phase II portion of subject site. Photograph 2: View of subject property (left) and view of GE/GNF property (right). SITE PHOTOGRAPHS Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Photograph 3: View of the bore hole associated with temporary monitoring well TMW-2. Photograph 4: Additional view of off-site monitoring wells. Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 8 APPENDIX B *"!&'%('"!%"% !-.7+361(&2'*97*)+367.2,0*361908.40*;*007 361# 368-&630.2&*4&681*283+2:.6321*28&2)&896&0*7396(*7>.:.7.323+#&8*69&0.8=*:.7*)&2  *188;:?=-/?;=:2;=9-?5;:  #*003286&(836&1* #*003286&(836*68.+.(&8.3291'*6  314&2=&1* *188;:>?=@/?5;:#1=95? 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NA ✔ 1/30/19 TMW-1 CastleHayneSandMills NA SledgeRoad,CastleHayne,NC28429 NewHanover NA 34.33808777.956837 ✔ ✔ fivetotal 20' NA ~2.5" HandAugerMethod 15 16 TanFineSANDS 0 10 1 Sch40PVC 10 20 1 0.010Sch40PVC 0 8 neat cement 45lbs.pour 8 9 Bentonite 20lbs.pour 9 20 #2sandPour 0 6 Lt.GreySiltySandyClay 6 20 TanFineSANDS tempwellpropelyabandonedper2Crules,sameday. 2/15/19 *"!&'%('"!%"% !-.7+361(&2'*97*)+367.2,0*361908.40*;*007 361# 368-&630.2&*4&681*283+2:.6321*28&2)&896&0*7396(*7>.:.7.323+#&8*69&0.8=*:.7*)&2  *188;:?=-/?;=:2;=9-?5;:  #*003286&(836&1* #*003286&(836*68.+.(&8.3291'*6  314&2=&1* *188;:>?=@/?5;:#1=95? List all applicable well construction permits (i.e. County, State, Variance, etc.) *188(>1/41/7B188@>1 *-?1=&@<<8D*188 @,6.(90896&0@92.(.4&09'0.( @*38-*61&0*&8.2,330.2, 9440=@*7.)*28.&0#&8*6 9440=7.2,0* @2)9786.&0311*6(.&0@*7.)*28.&0#&8*6 9440=7-&6*) @66.,&8.32 !;:*-?1=&@<<8D*188 @32.836.2,@*(3:*6= :61/?5;:*188 @59.+*6*(-&6,*@6392);&8*6*1*).&8.32 @59.+*6 836&,*&2)*(3:*6=@ &0.2.8=&66.*6 @59.+*6!*78 @ 8361;&8*66&.2&,* @<4*6.1*28&0!*(-2303,=@ 9'7.)*2(*328630 @*38-*61&0037*)334@!6&(*6 @*38-*61&0*&8.2,330.2,*8962@8-*6*<40&.292)*6 *1&6/7 -?1*188>;9<81?10 *188;/-?5;:  &(.0.8=;2*6&1*&(.0.8=.+&440.(&'0*  -=7.(&0))6*77.8=&2)%.4  3928=&6(*0)*28.+.(&8.323 .-?5?@01-:0;:35?@015:013=11> 95:@?1> >1/;:0>;=01/59-8013=11> .+;*00+.*0)32*0&8032,.779++.(.*28  !* >-=1?41B188>F#1=9-:1:?;=F'19<;=-=D >?45>-=1<-5=?;-:1C5>?5:3B188F+1>;=F!; If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. !@9.1=;2B188>/;:>?=@/?10 For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. ';?-8B18801<?4.18;B8-:0>@=2-/12? For multiple wells list all depths if different (example- 3@200’ and 2@100? &?-?5/B-?1=81A18.18;B?;<;2/->5:32?If water level is above casing, use “+”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y signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner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nnningthishhhhhh formIherebycertifythatthe well(s)was(we _______________ JamesD.Barker 3106A Quantex,Inc. NA ✔ 1/30/19 TMW-2 CastleHayneSandMills NA SledgeRoad,CastleHayne,NC28429 NewHanover NA 34.33808777.956837 ✔ ✔ fivetotal 20' NA ~2.5" DirectPushMethod 15 16 TanFineSANDS 0 10 1 Sch40PVC 10 20 1 0.010Sch40PVC 0 8 neat cement 25lbs.pour 8 9 Bentonite 15lbs.pour 9 20 #2sandPour 0 8 Lt.GreySiltySandyClay 8 20 TanFineSANDS tempwellpropelyabandonedper2Crules,sameday. 2/15/19 *"!&'%('"!%"% !-.7+361(&2'*97*)+367.2,0*361908.40*;*007 361# 368-&630.2&*4&681*283+2:.6321*28&2)&896&0*7396(*7>.:.7.323+#&8*69&0.8=*:.7*)&2  *188;:?=-/?;=:2;=9-?5;:  #*003286&(836&1* #*003286&(836*68.+.(&8.3291'*6  314&2=&1* *188;:>?=@/?5;:#1=95? List all applicable well construction permits (i.e. County, State, Variance, etc.) *188(>1/41/7B188@>1 *-?1=&@<<8D*188 @,6.(90896&0@92.(.4&09'0.( @*38-*61&0*&8.2,330.2, 9440=@*7.)*28.&0#&8*6 9440=7.2,0* @2)9786.&0311*6(.&0@*7.)*28.&0#&8*6 9440=7-&6*) @66.,&8.32 !;:*-?1=&@<<8D*188 @32.836.2,@*(3:*6= :61/?5;:*188 @59.+*6*(-&6,*@6392);&8*6*1*).&8.32 @59.+*6 836&,*&2)*(3:*6=@ &0.2.8=&66.*6 @59.+*6!*78 @ 8361;&8*66&.2&,* @<4*6.1*28&0!*(-2303,=@ 9'7.)*2(*328630 @*38-*61&0037*)334@!6&(*6 @*38-*61&0*&8.2,330.2,*8962@8-*6*<40&.292)*6 *1&6/7 -?1*188>;9<81?10 *188;/-?5;:  &(.0.8=;2*6&1*&(.0.8=.+&440.(&'0*  -=7.(&0))6*77.8=&2)%.4  3928=&6(*0)*28.+.(&8.323 .-?5?@01-:0;:35?@015:013=11> 95:@?1> >1/;:0>;=01/59-8013=11> .+;*00+.*0)32*0&8032,.779++.(.*28  !* >-=1?41B188>F#1=9-:1:?;=F'19<;=-=D >?45>-=1<-5=?;-:1C5>?5:3B188F+1>;=F!; If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. !@9.1=;2B188>/;:>?=@/?10 For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. ';?-8B18801<?4.18;B8-:0>@=2-/12? For multiple wells list all depths if different (example- 3@200’ and 2@100? &?-?5/B-?1=81A18.18;B?;<;2/->5:32?If water level is above casing, use “+”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y signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner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nnningthishhhhhh formIherebycertifythatthe well(s)was(we _______________ JamesD.Barker 3106A Quantex,Inc. NA ✔ 1/30/19 TMW-3 CastleHayneSandMills NA SledgeRoad,CastleHayne,NC28429 NewHanover NA 34.33808777.956837 ✔ ✔ fivetotal 15' NA ~2.5" DirectPushMethod 8 9 TanFineSANDS 0 5 1 Sch40PVC 5 15 1 0.010Sch40PVC 0 3 neat cement 10lbs.pour 3 4 Bentonite 12lbs.pour 4 15 #2sandPour 0 6 Lt.GreySandyClay 6 15 TanFineSANDS tempwellpropelyabandonedper2Crules,sameday. 2/15/19 *"!&'%('"!%"% !-.7+361(&2'*97*)+367.2,0*361908.40*;*007 361# 368-&630.2&*4&681*283+2:.6321*28&2)&896&0*7396(*7>.:.7.323+#&8*69&0.8=*:.7*)&2  *188;:?=-/?;=:2;=9-?5;:  #*003286&(836&1* #*003286&(836*68.+.(&8.3291'*6  314&2=&1* *188;:>?=@/?5;:#1=95? List all applicable well construction permits (i.e. County, State, Variance, etc.) *188(>1/41/7B188@>1 *-?1=&@<<8D*188 @,6.(90896&0@92.(.4&09'0.( @*38-*61&0*&8.2,330.2, 9440=@*7.)*28.&0#&8*6 9440=7.2,0* @2)9786.&0311*6(.&0@*7.)*28.&0#&8*6 9440=7-&6*) @66.,&8.32 !;:*-?1=&@<<8D*188 @32.836.2,@*(3:*6= :61/?5;:*188 @59.+*6*(-&6,*@6392);&8*6*1*).&8.32 @59.+*6 836&,*&2)*(3:*6=@ &0.2.8=&66.*6 @59.+*6!*78 @ 8361;&8*66&.2&,* @<4*6.1*28&0!*(-2303,=@ 9'7.)*2(*328630 @*38-*61&0037*)334@!6&(*6 @*38-*61&0*&8.2,330.2,*8962@8-*6*<40&.292)*6 *1&6/7 -?1*188>;9<81?10 *188;/-?5;:  &(.0.8=;2*6&1*&(.0.8=.+&440.(&'0*  -=7.(&0))6*77.8=&2)%.4  3928=&6(*0)*28.+.(&8.323 .-?5?@01-:0;:35?@015:013=11> 95:@?1> >1/;:0>;=01/59-8013=11> .+;*00+.*0)32*0&8032,.779++.(.*28  !* >-=1?41B188>F#1=9-:1:?;=F'19<;=-=D >?45>-=1<-5=?;-:1C5>?5:3B188F+1>;=F!; If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. !@9.1=;2B188>/;:>?=@/?10 For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. ';?-8B18801<?4.18;B8-:0>@=2-/12? For multiple wells list all depths if different (example- 3@200’ and 2@100? &?-?5/B-?1=81A18.18;B?;<;2/->5:32?If water level is above casing, use “+”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y signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner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nnningthishhhhhh formIherebycertifythatthe well(s)was(we _______________ JamesD.Barker 3106A Quantex,Inc. NA ✔ 1/30/19 TMW-4 CastleHayneSandMills NA SledgeRoad,CastleHayne,NC28429 NewHanover NA 34.33808777.956837 ✔ ✔ fivetotal 6' NA ~2.5" HandAugerMethod 4 5 Tan/GreySANDS 0 4 1 Sch40PVC 4 6 1 0.010Sch40PVC 0 2.5 neat cement 15lbs.pour 2.5 3 Bentonite 15lbs.pour 3 6 #2sandPour 0 6 Tan/GreySANDS tempwellpropelyabandonedper2Crules,sameday. 2/15/19 *"!&'%('"!%"% !-.7+361(&2'*97*)+367.2,0*361908.40*;*007 361# 368-&630.2&*4&681*283+2:.6321*28&2)&896&0*7396(*7>.:.7.323+#&8*69&0.8=*:.7*)&2  *188;:?=-/?;=:2;=9-?5;:  #*003286&(836&1* #*003286&(836*68.+.(&8.3291'*6  314&2=&1* *188;:>?=@/?5;:#1=95? List all applicable well construction permits (i.e. County, State, Variance, etc.) *188(>1/41/7B188@>1 *-?1=&@<<8D*188 @,6.(90896&0@92.(.4&09'0.( @*38-*61&0*&8.2,330.2, 9440=@*7.)*28.&0#&8*6 9440=7.2,0* @2)9786.&0311*6(.&0@*7.)*28.&0#&8*6 9440=7-&6*) @66.,&8.32 !;:*-?1=&@<<8D*188 @32.836.2,@*(3:*6= :61/?5;:*188 @59.+*6*(-&6,*@6392);&8*6*1*).&8.32 @59.+*6 836&,*&2)*(3:*6=@ &0.2.8=&66.*6 @59.+*6!*78 @ 8361;&8*66&.2&,* @<4*6.1*28&0!*(-2303,=@ 9'7.)*2(*328630 @*38-*61&0037*)334@!6&(*6 @*38-*61&0*&8.2,330.2,*8962@8-*6*<40&.292)*6 *1&6/7 -?1*188>;9<81?10 *188;/-?5;:  &(.0.8=;2*6&1*&(.0.8=.+&440.(&'0*  -=7.(&0))6*77.8=&2)%.4  3928=&6(*0)*28.+.(&8.323 .-?5?@01-:0;:35?@015:013=11> 95:@?1> >1/;:0>;=01/59-8013=11> .+;*00+.*0)32*0&8032,.779++.(.*28  !* >-=1?41B188>F#1=9-:1:?;=F'19<;=-=D >?45>-=1<-5=?;-:1C5>?5:3B188F+1>;=F!; If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. !@9.1=;2B188>/;:>?=@/?10 For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. ';?-8B18801<?4.18;B8-:0>@=2-/12? For multiple wells list all depths if different (example- 3@200’ and 2@100? &?-?5/B-?1=81A18.18;B?;<;2/->5:32?If water level is above casing, use “+”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y signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner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nnningthishhhhhh formIherebycertifythatthe well(s)was(we _______________ JamesD.Barker 3106A Quantex,Inc. NA ✔ 1/30/19 TMW-5 CastleHayneSandMills NA SledgeRoad,CastleHayne,NC28429 NewHanover NA 34.33808777.956837 ✔ ✔ fivetotal 20' NA ~2.5" HandAugerMethod 16 17 TanFineSANDS 0 10 1 Sch40PVC 10 20 1 0.010Sch40PVC 0 8 neat cement 40lbs.pour 8 9 Bentonite 15lbs.pour 9 20 #2sandPour 0 7 Lt.GreySiltySandyClay 7 20 TanFineSANDS tempwellpropelyabandonedper2Crules,sameday. 2/15/19 Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 9 APPENDIX C W E L L A B AND ON M E N T R E C O R D This form can be used for single or multiple wells Form GW-30 North Carolina Department of Environment and Natural Resources Division of Water Quality Revised March 2013 1. Well Contractor Information: Well Contractor Name (or well owner personally abandoning well on his/her property) NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. County, State, Variance, etc.) if known 3. Well use (check well use): Water Supply Well: Agricultural Municipal/Public Geothermal (Heating/Cooling Supply) Residential Water Supply (single) Industrial/Commercial Residential Water Supply (shared) Irrigation Non-Water Supply Well: Monitoring Recovery Injection Well: Aquifer Recharge Groundwater Remediation Aquifer Storage and Recovery Salinity Barrier Aquifer Test Stormwater Drainage Experimental Technology Subsidence Control Geothermal (Closed Loop) Tracer Geothermal (Heating/Cooling Return) Other (explain under 7g) 4. Date well(s) abandoned: 5a. Well location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W CONST RUCTI O N DE TA ILS OF W EL L(S) BEING AB ANDONED Attach well construction record(s) if available. For multiple injection or non-water supply wells ONLY with the same construction/abandonment, you can submit one form. 6a. Well ID#: 6b. Total well depth: (ft.) 6c. Borehole diameter: (in.) 6d. Water level below ground surface: (ft.) 6e. Outer casing length (if known): (ft.) 6f. Inner casing/tubing length (if known): (ft.) 6g. Screen length (if known): (ft.) W ELL ABA NDONMENT DET AILS 7a. Number of wells being abandoned: For multiple injection or non-water supply wells ONLY with the same construction/abandonment, you can submit one form. 7b. Approximate volume of water remaining in well(s): (gal.) F OR W AT ER SUPPLY WEL LS ONL Y: 7c. Type of disinfectant used: 7d. Amount of disinfectant used: 7e. Sealing materials used (check all that apply): Neat Cement Grout Bentonite Chips or Pellets Sand Cement Grout Dry Clay Concrete Grout Drill Cuttings Specialty Grout Gravel Bentonite Slurry Other (explain under 7g) 7f. For each material selected above, provide amount of materials used: 7g. Provide a brief description of the abandonment procedure: 8. Certification: Signature of Certified Well Contractor or Well Owner Date By signing this form, I hereby certify that the well(s) was (were) abandoned in accordance with 15A NCAC 02C .0100 or 2C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 9. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well abandonment details. You may also attach additional pages if necessary. SUBMITT AL INSTRUC TIONS 10a. For All Wells: Submit this form within 30 days of completion of well abandonment to the following: Division of Water Quality, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617! 10b. For Injection Wells: In addition to sending the form to the address in 10a above, also submit one copy of this form within 30 days of completion of well abandonment to the following: Division of Water Quality, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636! 10c. For Water Supply & Injection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well abandonment to the county health department of the county where abandoned. For Internal Use ONLY: Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019 10 APPENDIX D #=CL# February 13, 2019 LIMS USE: FR - SARAH KORDON LIMS OBJECT ID: 92416093 92416093 Project: Pace Project No.: RE: Sarah Kordon ECS Southeast 9001 Glenwood Ave Raleigh, NC 27617 Castle Hayne Sand Mine Dear Sarah Kordon: Enclosed are the analytical results for sample(s) received by the laboratory on February 01, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Ezell taylor.ezell@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 26 #=CP# CERTIFICATIONS Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Pennsylvania Certification IDs 1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601 ANAB DOD-ELAP Rad Accreditation #: L2417 Alabama Certification #: 41590 Arizona Certification #: AZ0734 Arkansas Certification California Certification #: 04222CA Colorado Certification #: PA01547 Connecticut Certification #: PH-0694 Delaware Certification EPA Region 4 DW Rad Florida/TNI Certification #: E87683 Georgia Certification #: C040 Guam Certification Hawaii Certification Idaho Certification Illinois Certification Indiana Certification Iowa Certification #: 391 Kansas/TNI Certification #: E-10358 Kentucky Certification #: KY90133 KY WW Permit #: KY0098221 KY WW Permit #: KY0000221 Louisiana DHH/TNI Certification #: LA180012 Louisiana DEQ/TNI Certification #: 4086 Maine Certification #: 2017020 Maryland Certification #: 308 Massachusetts Certification #: M-PA1457 Michigan/PADEP Certification #: 9991 Missouri Certification #: 235 Montana Certification #: Cert0082 Nebraska Certification #: NE-OS-29-14 Nevada Certification #: PA014572018-1 New Hampshire/TNI Certification #: 297617 New Jersey/TNI Certification #: PA051 New Mexico Certification #: PA01457 New York/TNI Certification #: 10888 North Carolina Certification #: 42706 North Dakota Certification #: R-190 Ohio EPA Rad Approval: #41249 Oregon/TNI Certification #: PA200002-010 Pennsylvania/TNI Certification #: 65-00282 Puerto Rico Certification #: PA01457 Rhode Island Certification #: 65-00282 South Dakota Certification Tennessee Certification #: 02867 Texas/TNI Certification #: T104704188-17-3 Utah/TNI Certification #: PA014572017-9 USDA Soil Permit #: P330-17-00091 Vermont Dept. of Health: ID# VT-0282 Virgin Island/PADEP Certification Virginia/VELAP Certification #: 9526 Washington Certification #: C868 West Virginia DEP Certification #: 143 West Virginia DHHR Certification #: 9964C Wisconsin Approve List for Rad Wyoming Certification #: 8TMS-L Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 26 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92416093001 TMW-1 EPA 8260B 63 PASI-CSAS ASTM D5174-97 1 PASI-PARMK HSL-300 3 PASI-PALAL EPA 300.0 Rev 2.1 1993 1 PASI-ACDC 92416093002 TMW-2 EPA 8260B 63 PASI-CSAS ASTM D5174-97 1 PASI-PARMK HSL-300 3 PASI-PALAL EPA 300.0 Rev 2.1 1993 1 PASI-ACDC 92416093003 TMW-3 EPA 8260B 63 PASI-CSAS ASTM D5174-97 1 PASI-PARMK HSL-300 3 PASI-PALAL EPA 300.0 Rev 2.1 1993 1 PASI-ACDC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 26 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92416093001 TMW-1 Total Uranium 0.138 ± 0.009 (0.262) C:NA T:NA ug/L 02/13/19 13:57ASTM D5174-97 Uranium-234 0.094 ± 0.056 (0.066) C:NA T:95% pCi/L 02/12/19 14:24 N2HSL-300 Uranium-235 0.043 ± 0.040 (0.054) C:NA T:95% pCi/L 02/12/19 14:24 N2HSL-300 Uranium-238 0.038 ± 0.029(0.015) C:NA T:95% pCi/L 02/12/19 14:24 N2HSL-300 92416093002 TMW-2 Total Uranium 3.88 ± 0.150 (0.262) C:NA T:NA ug/L 02/13/19 13:59ASTM D5174-97 Uranium-234 1.65 ± 0.297 (0.041) C:NA T:93% pCi/L 02/12/19 14:20 N2HSL-300 Uranium-235 0.109 ± 0.057 (0.020) C:NA T:93% pCi/L 02/12/19 14:20 N2HSL-300 Uranium-238 1.53 ± 0.279 (0.041) C:NA T:93% pCi/L 02/12/19 14:20 N2HSL-300 92416093003 TMW-3 Total Uranium 7.11 ± 0.280(0.262) C:NA T:NA ug/L 02/13/19 14:02ASTM D5174-97 Uranium-234 3.31 ± 0.619 (0.139) C:NA T:79% pCi/L 02/12/19 14:20 N2HSL-300 Uranium-235 0.252 ± 0.148 (0.157) C:NA T:79% pCi/L 02/12/19 14:20 N2HSL-300 Uranium-238 3.22 ± 0.603 (0.095) C:NA T:79% pCi/L 02/12/19 14:20 N2HSL-300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-1 Lab ID:92416093001 Collected:01/30/19 14:15 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Acetone ND ug/L 02/05/19 17:43 67-64-125.0 1 Benzene ND ug/L 02/05/19 17:43 71-43-21.0 1 Bromobenzene ND ug/L 02/05/19 17:43 108-86-11.0 1 Bromochloromethane ND ug/L 02/05/19 17:43 74-97-51.0 1 Bromodichloromethane ND ug/L 02/05/19 17:43 75-27-41.0 1 Bromoform ND ug/L 02/05/19 17:43 75-25-21.0 1 Bromomethane ND ug/L 02/05/19 17:43 74-83-92.0 1 2-Butanone (MEK)ND ug/L 02/05/19 17:43 78-93-35.0 1 Carbon tetrachloride ND ug/L 02/05/19 17:43 56-23-51.0 1 Chlorobenzene ND ug/L 02/05/19 17:43 108-90-71.0 1 Chloroethane ND ug/L 02/05/19 17:43 75-00-31.0 1 Chloroform ND ug/L 02/05/19 17:43 67-66-35.0 1 Chloromethane ND ug/L 02/05/19 17:43 74-87-31.0 1 2-Chlorotoluene ND ug/L 02/05/19 17:43 95-49-81.0 1 4-Chlorotoluene ND ug/L 02/05/19 17:43 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 17:43 96-12-82.0 1 Dibromochloromethane ND ug/L 02/05/19 17:43 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 02/05/19 17:43 106-93-41.0 1 Dibromomethane ND ug/L 02/05/19 17:43 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 02/05/19 17:43 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 02/05/19 17:43 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 02/05/19 17:43 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 02/05/19 17:43 75-71-81.0 1 1,1-Dichloroethane ND ug/L 02/05/19 17:43 75-34-31.0 1 1,2-Dichloroethane ND ug/L 02/05/19 17:43 107-06-21.0 1 1,1-Dichloroethene ND ug/L 02/05/19 17:43 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 02/05/19 17:43 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 02/05/19 17:43 156-60-51.0 1 1,2-Dichloropropane ND ug/L 02/05/19 17:43 78-87-51.0 1 1,3-Dichloropropane ND ug/L 02/05/19 17:43 142-28-91.0 1 2,2-Dichloropropane ND ug/L 02/05/19 17:43 594-20-71.0 1 1,1-Dichloropropene ND ug/L 02/05/19 17:43 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 02/05/19 17:43 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 02/05/19 17:43 10061-02-61.0 1 Diisopropyl ether ND ug/L 02/05/19 17:43 108-20-31.0 1 Ethylbenzene ND ug/L 02/05/19 17:43 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 02/05/19 17:43 87-68-31.0 1 2-Hexanone ND ug/L 02/05/19 17:43 591-78-65.0 1 p-Isopropyltoluene ND ug/L 02/05/19 17:43 99-87-61.0 1 Methylene Chloride ND ug/L 02/05/19 17:43 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 17:43 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 02/05/19 17:43 1634-04-41.0 1 Naphthalene ND ug/L 02/05/19 17:43 91-20-31.0 1 Styrene ND ug/L 02/05/19 17:43 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 17:43 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 17:43 79-34-51.0 1 Tetrachloroethene ND ug/L 02/05/19 17:43 127-18-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-1 Lab ID:92416093001 Collected:01/30/19 14:15 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Toluene ND ug/L 02/05/19 17:43 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 02/05/19 17:43 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 02/05/19 17:43 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 02/05/19 17:43 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 02/05/19 17:43 79-00-51.0 1 Trichloroethene ND ug/L 02/05/19 17:43 79-01-61.0 1 Trichlorofluoromethane ND ug/L 02/05/19 17:43 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 02/05/19 17:43 96-18-41.0 1 Vinyl acetate ND ug/L 02/05/19 17:43 108-05-42.0 1 Vinyl chloride ND ug/L 02/05/19 17:43 75-01-41.0 1 Xylene (Total)ND ug/L 02/05/19 17:43 1330-20-71.0 1 m&p-Xylene ND ug/L 02/05/19 17:43 179601-23-12.0 1 o-Xylene ND ug/L 02/05/19 17:43 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)101 %02/05/19 17:43 460-00-470-130 1 1,2-Dichloroethane-d4 (S)96 %02/05/19 17:43 17060-07-070-130 1 Toluene-d8 (S)99 %02/05/19 17:43 2037-26-570-130 1 Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days Fluoride ND mg/L 02/02/19 20:41 16984-48-80.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-2 Lab ID:92416093002 Collected:01/30/19 14:30 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Acetone ND ug/L 02/05/19 18:00 67-64-125.0 1 Benzene ND ug/L 02/05/19 18:00 71-43-21.0 1 Bromobenzene ND ug/L 02/05/19 18:00 108-86-11.0 1 Bromochloromethane ND ug/L 02/05/19 18:00 74-97-51.0 1 Bromodichloromethane ND ug/L 02/05/19 18:00 75-27-41.0 1 Bromoform ND ug/L 02/05/19 18:00 75-25-21.0 1 Bromomethane ND ug/L 02/05/19 18:00 74-83-92.0 1 2-Butanone (MEK)ND ug/L 02/05/19 18:00 78-93-35.0 1 Carbon tetrachloride ND ug/L 02/05/19 18:00 56-23-51.0 1 Chlorobenzene ND ug/L 02/05/19 18:00 108-90-71.0 1 Chloroethane ND ug/L 02/05/19 18:00 75-00-31.0 1 Chloroform ND ug/L 02/05/19 18:00 67-66-35.0 1 Chloromethane ND ug/L 02/05/19 18:00 74-87-31.0 1 2-Chlorotoluene ND ug/L 02/05/19 18:00 95-49-81.0 1 4-Chlorotoluene ND ug/L 02/05/19 18:00 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 18:00 96-12-82.0 1 Dibromochloromethane ND ug/L 02/05/19 18:00 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 02/05/19 18:00 106-93-41.0 1 Dibromomethane ND ug/L 02/05/19 18:00 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 02/05/19 18:00 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 02/05/19 18:00 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 02/05/19 18:00 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 02/05/19 18:00 75-71-81.0 1 1,1-Dichloroethane ND ug/L 02/05/19 18:00 75-34-31.0 1 1,2-Dichloroethane ND ug/L 02/05/19 18:00 107-06-21.0 1 1,1-Dichloroethene ND ug/L 02/05/19 18:00 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 02/05/19 18:00 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 02/05/19 18:00 156-60-51.0 1 1,2-Dichloropropane ND ug/L 02/05/19 18:00 78-87-51.0 1 1,3-Dichloropropane ND ug/L 02/05/19 18:00 142-28-91.0 1 2,2-Dichloropropane ND ug/L 02/05/19 18:00 594-20-71.0 1 1,1-Dichloropropene ND ug/L 02/05/19 18:00 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 02/05/19 18:00 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 02/05/19 18:00 10061-02-61.0 1 Diisopropyl ether ND ug/L 02/05/19 18:00 108-20-31.0 1 Ethylbenzene ND ug/L 02/05/19 18:00 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 02/05/19 18:00 87-68-31.0 1 2-Hexanone ND ug/L 02/05/19 18:00 591-78-65.0 1 p-Isopropyltoluene ND ug/L 02/05/19 18:00 99-87-61.0 1 Methylene Chloride ND ug/L 02/05/19 18:00 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 18:00 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 02/05/19 18:00 1634-04-41.0 1 Naphthalene ND ug/L 02/05/19 18:00 91-20-31.0 1 Styrene ND ug/L 02/05/19 18:00 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 18:00 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 18:00 79-34-51.0 1 Tetrachloroethene ND ug/L 02/05/19 18:00 127-18-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-2 Lab ID:92416093002 Collected:01/30/19 14:30 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Toluene ND ug/L 02/05/19 18:00 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 02/05/19 18:00 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 02/05/19 18:00 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 02/05/19 18:00 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 02/05/19 18:00 79-00-51.0 1 Trichloroethene ND ug/L 02/05/19 18:00 79-01-61.0 1 Trichlorofluoromethane ND ug/L 02/05/19 18:00 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 02/05/19 18:00 96-18-41.0 1 Vinyl acetate ND ug/L 02/05/19 18:00 108-05-42.0 1 Vinyl chloride ND ug/L 02/05/19 18:00 75-01-41.0 1 Xylene (Total)ND ug/L 02/05/19 18:00 1330-20-71.0 1 m&p-Xylene ND ug/L 02/05/19 18:00 179601-23-12.0 1 o-Xylene ND ug/L 02/05/19 18:00 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)98 %02/05/19 18:00 460-00-470-130 1 1,2-Dichloroethane-d4 (S)97 %02/05/19 18:00 17060-07-070-130 1 Toluene-d8 (S)101 %02/05/19 18:00 2037-26-570-130 1 Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days Fluoride ND mg/L 02/02/19 20:57 16984-48-80.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-3 Lab ID:92416093003 Collected:01/30/19 14:45 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Acetone ND ug/L 02/05/19 18:17 67-64-125.0 1 Benzene ND ug/L 02/05/19 18:17 71-43-21.0 1 Bromobenzene ND ug/L 02/05/19 18:17 108-86-11.0 1 Bromochloromethane ND ug/L 02/05/19 18:17 74-97-51.0 1 Bromodichloromethane ND ug/L 02/05/19 18:17 75-27-41.0 1 Bromoform ND ug/L 02/05/19 18:17 75-25-21.0 1 Bromomethane ND ug/L 02/05/19 18:17 74-83-92.0 1 2-Butanone (MEK)ND ug/L 02/05/19 18:17 78-93-35.0 1 Carbon tetrachloride ND ug/L 02/05/19 18:17 56-23-51.0 1 Chlorobenzene ND ug/L 02/05/19 18:17 108-90-71.0 1 Chloroethane ND ug/L 02/05/19 18:17 75-00-31.0 1 Chloroform ND ug/L 02/05/19 18:17 67-66-35.0 1 Chloromethane ND ug/L 02/05/19 18:17 74-87-31.0 1 2-Chlorotoluene ND ug/L 02/05/19 18:17 95-49-81.0 1 4-Chlorotoluene ND ug/L 02/05/19 18:17 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 18:17 96-12-82.0 1 Dibromochloromethane ND ug/L 02/05/19 18:17 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 02/05/19 18:17 106-93-41.0 1 Dibromomethane ND ug/L 02/05/19 18:17 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 02/05/19 18:17 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 02/05/19 18:17 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 02/05/19 18:17 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 02/05/19 18:17 75-71-81.0 1 1,1-Dichloroethane ND ug/L 02/05/19 18:17 75-34-31.0 1 1,2-Dichloroethane ND ug/L 02/05/19 18:17 107-06-21.0 1 1,1-Dichloroethene ND ug/L 02/05/19 18:17 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 02/05/19 18:17 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 02/05/19 18:17 156-60-51.0 1 1,2-Dichloropropane ND ug/L 02/05/19 18:17 78-87-51.0 1 1,3-Dichloropropane ND ug/L 02/05/19 18:17 142-28-91.0 1 2,2-Dichloropropane ND ug/L 02/05/19 18:17 594-20-71.0 1 1,1-Dichloropropene ND ug/L 02/05/19 18:17 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 02/05/19 18:17 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 02/05/19 18:17 10061-02-61.0 1 Diisopropyl ether ND ug/L 02/05/19 18:17 108-20-31.0 1 Ethylbenzene ND ug/L 02/05/19 18:17 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 02/05/19 18:17 87-68-31.0 1 2-Hexanone ND ug/L 02/05/19 18:17 591-78-65.0 1 p-Isopropyltoluene ND ug/L 02/05/19 18:17 99-87-61.0 1 Methylene Chloride ND ug/L 02/05/19 18:17 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 18:17 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 02/05/19 18:17 1634-04-41.0 1 Naphthalene ND ug/L 02/05/19 18:17 91-20-31.0 1 Styrene ND ug/L 02/05/19 18:17 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 18:17 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 18:17 79-34-51.0 1 Tetrachloroethene ND ug/L 02/05/19 18:17 127-18-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 26 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-3 Lab ID:92416093003 Collected:01/30/19 14:45 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Toluene ND ug/L 02/05/19 18:17 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 02/05/19 18:17 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 02/05/19 18:17 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 02/05/19 18:17 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 02/05/19 18:17 79-00-51.0 1 Trichloroethene ND ug/L 02/05/19 18:17 79-01-61.0 1 Trichlorofluoromethane ND ug/L 02/05/19 18:17 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 02/05/19 18:17 96-18-41.0 1 Vinyl acetate ND ug/L 02/05/19 18:17 108-05-42.0 1 Vinyl chloride ND ug/L 02/05/19 18:17 75-01-41.0 1 Xylene (Total)ND ug/L 02/05/19 18:17 1330-20-71.0 1 m&p-Xylene ND ug/L 02/05/19 18:17 179601-23-12.0 1 o-Xylene ND ug/L 02/05/19 18:17 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)98 %02/05/19 18:17 460-00-470-130 1 1,2-Dichloroethane-d4 (S)97 %02/05/19 18:17 17060-07-070-130 1 Toluene-d8 (S)103 %02/05/19 18:17 2037-26-570-130 1 Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days Fluoride ND mg/L 02/02/19 21:13 16984-48-80.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 456399 EPA 8260B EPA 8260B 8260 MSV Low Level Associated Lab Samples:92416093001, 92416093002, 92416093003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2490025 Associated Lab Samples:92416093001, 92416093002, 92416093003 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09 1,1,1-Trichloroethane ug/L ND 1.0 02/05/19 13:09 1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09 1,1,2-Trichloroethane ug/L ND 1.0 02/05/19 13:09 1,1-Dichloroethane ug/L ND 1.0 02/05/19 13:09 1,1-Dichloroethene ug/L ND 1.0 02/05/19 13:09 1,1-Dichloropropene ug/L ND 1.0 02/05/19 13:09 1,2,3-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2,3-Trichloropropane ug/L ND 1.0 02/05/19 13:09 1,2,4-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2-Dibromo-3-chloropropane ug/L ND 2.0 02/05/19 13:09 1,2-Dibromoethane (EDB)ug/L ND 1.0 02/05/19 13:09 1,2-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2-Dichloroethane ug/L ND 1.0 02/05/19 13:09 1,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09 1,3-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,3-Dichloropropane ug/L ND 1.0 02/05/19 13:09 1,4-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 2,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09 2-Butanone (MEK)ug/L ND 5.0 02/05/19 13:09 2-Chlorotoluene ug/L ND 1.0 02/05/19 13:09 2-Hexanone ug/L ND 5.0 02/05/19 13:09 4-Chlorotoluene ug/L ND 1.0 02/05/19 13:09 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/05/19 13:09 Acetone ug/L ND 25.0 02/05/19 13:09 Benzene ug/L ND 1.0 02/05/19 13:09 Bromobenzene ug/L ND 1.0 02/05/19 13:09 Bromochloromethane ug/L ND 1.0 02/05/19 13:09 Bromodichloromethane ug/L ND 1.0 02/05/19 13:09 Bromoform ug/L ND 1.0 02/05/19 13:09 Bromomethane ug/L ND 2.0 02/05/19 13:09 Carbon tetrachloride ug/L ND 1.0 02/05/19 13:09 Chlorobenzene ug/L ND 1.0 02/05/19 13:09 Chloroethane ug/L ND 1.0 02/05/19 13:09 Chloroform ug/L ND 5.0 02/05/19 13:09 Chloromethane ug/L ND 1.0 02/05/19 13:09 cis-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09 cis-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09 Dibromochloromethane ug/L ND 1.0 02/05/19 13:09 Dibromomethane ug/L ND 1.0 02/05/19 13:09 Dichlorodifluoromethane ug/L ND 1.0 02/05/19 13:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2490025 Associated Lab Samples:92416093001, 92416093002, 92416093003 Matrix:Water Analyzed Diisopropyl ether ug/L ND 1.0 02/05/19 13:09 Ethylbenzene ug/L ND 1.0 02/05/19 13:09 Hexachloro-1,3-butadiene ug/L ND 1.0 02/05/19 13:09 m&p-Xylene ug/L ND 2.0 02/05/19 13:09 Methyl-tert-butyl ether ug/L ND 1.0 02/05/19 13:09 Methylene Chloride ug/L ND 5.0 02/05/19 13:09 Naphthalene ug/L ND 1.0 02/05/19 13:09 o-Xylene ug/L ND 1.0 02/05/19 13:09 p-Isopropyltoluene ug/L ND 1.0 02/05/19 13:09 Styrene ug/L ND 1.0 02/05/19 13:09 Tetrachloroethene ug/L ND 1.0 02/05/19 13:09 Toluene ug/L ND 1.0 02/05/19 13:09 trans-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09 trans-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09 Trichloroethene ug/L ND 1.0 02/05/19 13:09 Trichlorofluoromethane ug/L ND 1.0 02/05/19 13:09 Vinyl acetate ug/L ND 2.0 02/05/19 13:09 Vinyl chloride ug/L ND 1.0 02/05/19 13:09 Xylene (Total)ug/L ND 1.0 02/05/19 13:09 1,2-Dichloroethane-d4 (S)%95 70-130 02/05/19 13:09 4-Bromofluorobenzene (S)%99 70-130 02/05/19 13:09 Toluene-d8 (S)%100 70-130 02/05/19 13:09 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2490026LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 52.550 105 70-130 1,1,1-Trichloroethane ug/L 49.450 99 70-130 1,1,2,2-Tetrachloroethane ug/L 51.150 102 70-130 1,1,2-Trichloroethane ug/L 51.050 102 70-130 1,1-Dichloroethane ug/L 48.650 97 70-130 1,1-Dichloroethene ug/L 50.850 102 70-130 1,1-Dichloropropene ug/L 47.850 96 70-130 1,2,3-Trichlorobenzene ug/L 52.750 105 70-130 1,2,3-Trichloropropane ug/L 49.550 99 70-130 1,2,4-Trichlorobenzene ug/L 51.850 104 70-130 1,2-Dibromo-3-chloropropane ug/L 47.650 95 70-130 1,2-Dibromoethane (EDB)ug/L 52.750 105 70-130 1,2-Dichlorobenzene ug/L 48.750 97 70-130 1,2-Dichloroethane ug/L 43.950 88 70-130 1,2-Dichloropropane ug/L 48.850 98 70-130 1,3-Dichlorobenzene ug/L 47.950 96 70-130 1,3-Dichloropropane ug/L 51.850 104 70-131 1,4-Dichlorobenzene ug/L 47.750 95 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2490026LABORATORY CONTROL SAMPLE: LCSSpike 2,2-Dichloropropane ug/L 50.150 100 69-130 2-Butanone (MEK)ug/L 105100 105 64-135 2-Chlorotoluene ug/L 47.950 96 70-130 2-Hexanone ug/L 103100 103 66-135 4-Chlorotoluene ug/L 47.450 95 70-130 4-Methyl-2-pentanone (MIBK)ug/L 98.7100 99 70-130 Acetone ug/L 93.0100 93 61-157 Benzene ug/L 49.550 99 70-130 Bromobenzene ug/L 48.350 97 70-130 Bromochloromethane ug/L 49.850 100 70-130 Bromodichloromethane ug/L 49.150 98 70-130 Bromoform ug/L 50.550 101 70-130 Bromomethane ug/L 43.050 86 38-130 Carbon tetrachloride ug/L 48.150 96 70-130 Chlorobenzene ug/L 49.050 98 70-130 Chloroethane ug/L 45.050 90 37-142 Chloroform ug/L 45.450 91 70-130 Chloromethane ug/L 45.950 92 48-130 cis-1,2-Dichloroethene ug/L 47.450 95 70-130 cis-1,3-Dichloropropene ug/L 51.850 104 70-130 Dibromochloromethane ug/L 47.250 94 70-130 Dibromomethane ug/L 49.950 100 70-130 Dichlorodifluoromethane ug/L 48.850 98 53-134 Diisopropyl ether ug/L 48.950 98 70-135 Ethylbenzene ug/L 49.050 98 70-130 Hexachloro-1,3-butadiene ug/L 51.050 102 68-132 m&p-Xylene ug/L 98.5100 98 70-130 Methyl-tert-butyl ether ug/L 51.250 102 70-130 Methylene Chloride ug/L 45.250 90 67-132 Naphthalene ug/L 50.450 101 70-130 o-Xylene ug/L 50.750 101 70-130 p-Isopropyltoluene ug/L 48.950 98 70-130 Styrene ug/L 51.650 103 70-130 Tetrachloroethene ug/L 52.250 104 69-130 Toluene ug/L 46.450 93 70-130 trans-1,2-Dichloroethene ug/L 48.150 96 70-130 trans-1,3-Dichloropropene ug/L 51.450 103 70-130 Trichloroethene ug/L 50.950 102 70-130 Trichlorofluoromethane ug/L 46.350 93 63-130 Vinyl acetate ug/L 106100 106 55-143 Vinyl chloride ug/L 49.350 99 70-131 Xylene (Total)ug/L 149150 99 70-130 1,2-Dichloroethane-d4 (S)%95 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%97 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92415883006 2490028 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 500 106 73-134105 1500ND530527 1,1,1-Trichloroethane ug/L 500 104 82-143107 2500ND522534 1,1,2,2-Tetrachloroethane ug/L 500 101 70-136103 2500ND503515 1,1,2-Trichloroethane ug/L 500 102 70-135106 4500ND511532 1,1-Dichloroethane ug/L 500 101 70-139102 2500ND503511 1,1-Dichloroethene ug/L 500 105 70-154108 2500ND526538 1,1-Dichloropropene ug/L 500 100 70-149101 2500ND498506 1,2,3-Trichlorobenzene ug/L 500 119 70-135110 8500ND597550 1,2,3-Trichloropropane ug/L 500 103 71-13798 5500ND515491 1,2,4-Trichlorobenzene ug/L 500 114 73-140108 6500ND572540 1,2-Dibromo-3-chloropropane ug/L 500 101 65-134101 0500ND504505 1,2-Dibromoethane (EDB)ug/L 500 104 70-137106 2500ND520530 1,2-Dichlorobenzene ug/L 500 105 70-133102 3500ND526508 1,2-Dichloroethane ug/L 500 89 70-13796 7500ND446479 1,2-Dichloropropane ug/L 500 102 70-140102 1500ND508512 1,3-Dichlorobenzene ug/L 500 104 70-135103 1500ND519514 1,3-Dichloropropane ug/L 500 106 70-143106 0500ND530529 1,4-Dichlorobenzene ug/L 500 103 70-133100 3500ND514501 2,2-Dichloropropane ug/L 500 80 61-14879 1500ND399396 2-Butanone (MEK)ug/L 1000 99 60-139104 51000ND9901040 2-Chlorotoluene ug/L 500 104 70-144104 0500ND520519 2-Hexanone ug/L 1000 99 65-138101 21000ND9871010 4-Chlorotoluene ug/L 500 104 70-137102 1500ND518512 4-Methyl-2-pentanone (MIBK)ug/L 1000 94 65-13597 31000ND943969 Acetone ug/L 1000 94 60-14895 11000ND939950 Benzene ug/L 500 104 70-151105 1500ND518523 Bromobenzene ug/L 500 104 70-136104 0500ND519521 Bromochloromethane ug/L 500 108 70-141109 1500ND538544 Bromodichloromethane ug/L 500 98 70-138100 1500ND491499 Bromoform ug/L 500 93 63-13096 3500ND463478 Bromomethane ug/L 500 99 15-15295 4500ND493476 Carbon tetrachloride ug/L 500 101 70-143103 2500ND505514 Chlorobenzene ug/L 500 103 70-138104 1500ND514519 Chloroethane ug/L 500 108 52-163108 0500ND540541 Chloroform ug/L 500 93 70-13995 2500ND482493 Chloromethane ug/L 500 101 41-139100 1500ND505499 cis-1,2-Dichloroethene ug/L 500 101 70-141104 35008.6J 516 529 cis-1,3-Dichloropropene ug/L 500 98 70-13799 1500ND488494 Dibromochloromethane ug/L 500 98 70-13497 1500ND489485 Dibromomethane ug/L 500 102 70-138105 3500ND508523 Dichlorodifluoromethane ug/L 500 103 47-155104 2500ND513521 Diisopropyl ether ug/L 500 97 63-14499 2500ND485493 Ethylbenzene ug/L 500 103 66-153104 0500ND517520 Hexachloro-1,3-butadiene ug/L 500 120 65-149111 8500ND602557 m&p-Xylene ug/L 1000 104 69-152104 01000ND10401040 Methyl-tert-butyl ether ug/L 500 100 54-156101 0500ND501503 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92415883006 2490028 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L 500 93 42-15993 0500ND498498 Naphthalene ug/L 500 112 61-148105 7500ND559523 o-Xylene ug/L 500 108 70-148107 1500ND539535 p-Isopropyltoluene ug/L 500 108 70-146106 2500ND542530 Styrene ug/L 500 104 70-135103 2500ND521513 Tetrachloroethene ug/L E50013559-143547 48500262033005360 Toluene ug/L 500 98 59-14899 2500ND488497 trans-1,2-Dichloroethene ug/L 500 103 70-146105 3500ND513526 trans-1,3-Dichloropropene ug/L 500 95 70-13598 3500ND476489 Trichloroethene ug/L 500 107 70-147114 650011.8J 548 580 Trichlorofluoromethane ug/L 500 101 70-148101 0500ND503503 Vinyl acetate ug/L 1000 99 49-15196 31000ND990962 Vinyl chloride ug/L 500 109 70-156107 2500ND544534 Xylene (Total)ug/L 1500 105 63-158105 01500ND15801580 1,2-Dichloroethane-d4 (S)%95 70-13094 4-Bromofluorobenzene (S)%100 70-130100 Toluene-d8 (S)%97 70-13096 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 26 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 456010 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 300.0 IC Anions Associated Lab Samples:92416093001, 92416093002, 92416093003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2488458 Associated Lab Samples:92416093001, 92416093002, 92416093003 Matrix:Water Analyzed Fluoride mg/L ND 0.10 02/02/19 12:57 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2488459LABORATORY CONTROL SAMPLE: LCSSpike Fluoride mg/L 2.52.5 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 2488460MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92416071001 2488461 MSD Result MSD % Rec RPD MSDMS Spike Conc. Fluoride mg/L 2.5 103 90-110104 12.5ND 2.6 2.6 Parameter Units MS Result % Rec Limits Qual% RecConc. 2488462MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92416071011 2488463 MSD Result MSD % Rec RPD MSDMS Spike Conc. Fluoride mg/L 2.5 100 90-110100 12.5ND 2.5 2.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 26 #=ARR# ANALYTICAL RESULTS - RADIOCHEMISTRY Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-1 Lab ID:92416093001 Collected:01/30/19 14:15 Received:02/01/19 10:00 Matrix:Water Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod PWS:Site ID:Sample Type: Total Uranium 0.138 ± 0.009 (0.262) C:NA T:NA ug/L 02/13/19 13:57 7440-61-1ASTM D5174-97 Uranium-234 0.094 ± 0.056 (0.066) C:NA T:95%pCi/L 02/12/19 14:24 13966-29-5 N2HSL-300 Uranium-235 0.043 ± 0.040 (0.054) C:NA T:95%pCi/L 02/12/19 14:24 15117-96-1 N2HSL-300 Uranium-238 0.038 ± 0.029 (0.015) C:NA T:95% pCi/L 02/12/19 14:24 N2HSL-300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 26 #=ARR# ANALYTICAL RESULTS - RADIOCHEMISTRY Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-2 Lab ID:92416093002 Collected:01/30/19 14:30 Received:02/01/19 10:00 Matrix:Water Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod PWS:Site ID:Sample Type: Total Uranium 3.88 ± 0.150 (0.262) C:NA T:NA ug/L 02/13/19 13:59 7440-61-1ASTM D5174-97 Uranium-234 1.65 ± 0.297 (0.041) C:NA T:93%pCi/L 02/12/19 14:20 13966-29-5 N2HSL-300 Uranium-235 0.109 ± 0.057 (0.020) C:NA T:93%pCi/L 02/12/19 14:20 15117-96-1 N2HSL-300 Uranium-238 1.53 ± 0.279 (0.041) C:NA T:93% pCi/L 02/12/19 14:20 N2HSL-300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 26 #=ARR# ANALYTICAL RESULTS - RADIOCHEMISTRY Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Sample:TMW-3 Lab ID:92416093003 Collected:01/30/19 14:45 Received:02/01/19 10:00 Matrix:Water Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod PWS:Site ID:Sample Type: Total Uranium 7.11 ± 0.280 (0.262) C:NA T:NA ug/L 02/13/19 14:02 7440-61-1ASTM D5174-97 Uranium-234 3.31 ± 0.619 (0.139) C:NA T:79%pCi/L 02/12/19 14:20 13966-29-5 N2HSL-300 Uranium-235 0.252 ± 0.148 (0.157) C:NA T:79%pCi/L 02/12/19 14:20 15117-96-1 N2HSL-300 Uranium-238 3.22 ± 0.603 (0.095) C:NA T:79% pCi/L 02/12/19 14:20 N2HSL-300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 26 #=QCR# QUALITY CONTROL - RADIOCHEMISTRY Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 329379 ASTM D5174-97 ASTM D5174-97 D5174.97 Total Uranium KPA Associated Lab Samples:92416093001, 92416093002, 92416093003 Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers METHOD BLANK:1602577 Associated Lab Samples:92416093001, 92416093002, 92416093003 Matrix:Water Analyzed Total Uranium ug/L 02/13/19 13:180.085 ± 0.006 (0.262) C:NA T:NA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 26 #=QCR# QUALITY CONTROL - RADIOCHEMISTRY Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 329227 HSL-300 HSL-300 HSL300(AS) Actinides Associated Lab Samples:92416093001, 92416093002, 92416093003 Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers METHOD BLANK:1601815 Associated Lab Samples:92416093001, 92416093002, 92416093003 Matrix:Water Analyzed Uranium-234 pCi/L N202/12/19 14:200.072 ± 0.047 (0.054) C:NA T:87% Uranium-235 pCi/L N202/12/19 14:200.031 ± 0.037 (0.056) C:NA T:87% Uranium-238 pCi/L N202/12/19 14:200.012 ± 0.040 (0.077) C:NA T:87% REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 26 #=QL# QUALIFIERS Pace Project No.: Project: 92416093 Castle Hayne Sand Mine DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Act - Activity Unc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval). Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval) (MDC) - Minimum Detectable Concentration Trac - Tracer Recovery (%) Carr - Carrier Recovery (%) Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - GreensburgPASI-PA ANALYTE QUALIFIERS Analyte concentration exceeded the calibration range. The reported result is estimated.E The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 26 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92416093 Castle Hayne Sand Mine Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92416093001 456399TMW-1 EPA 8260B 92416093002 456399TMW-2 EPA 8260B 92416093003 456399TMW-3 EPA 8260B 92416093001 329379TMW-1 ASTM D5174-97 92416093002 329379TMW-2 ASTM D5174-97 92416093003 329379TMW-3 ASTM D5174-97 92416093001 329227TMW-1 HSL-300 92416093002 329227TMW-2 HSL-300 92416093003 329227TMW-3 HSL-300 92416093001 456010TMW-1 EPA 300.0 Rev 2.1 1993 92416093002 456010TMW-2 EPA 300.0 Rev 2.1 1993 92416093003 456010TMW-3 EPA 300.0 Rev 2.1 1993 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 26 Page 24 of 26 Page 25 of 26 Page 26 of 26 #=CL# February 13, 2019 LIMS USE: FR - SARAH KORDON LIMS OBJECT ID: 92416096 92416096 Project: Pace Project No.: RE: Sarah Kordon ECS Southeast 9001 Glenwood Ave Raleigh, NC 27617 Castle Hayne Sand Mine II Dear Sarah Kordon: Enclosed are the analytical results for sample(s) received by the laboratory on February 01, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Ezell taylor.ezell@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 20 #=CP# CERTIFICATIONS Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Pennsylvania Certification IDs 1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601 ANAB DOD-ELAP Rad Accreditation #: L2417 Alabama Certification #: 41590 Arizona Certification #: AZ0734 Arkansas Certification California Certification #: 04222CA Colorado Certification #: PA01547 Connecticut Certification #: PH-0694 Delaware Certification EPA Region 4 DW Rad Florida/TNI Certification #: E87683 Georgia Certification #: C040 Guam Certification Hawaii Certification Idaho Certification Illinois Certification Indiana Certification Iowa Certification #: 391 Kansas/TNI Certification #: E-10358 Kentucky Certification #: KY90133 KY WW Permit #: KY0098221 KY WW Permit #: KY0000221 Louisiana DHH/TNI Certification #: LA180012 Louisiana DEQ/TNI Certification #: 4086 Maine Certification #: 2017020 Maryland Certification #: 308 Massachusetts Certification #: M-PA1457 Michigan/PADEP Certification #: 9991 Missouri Certification #: 235 Montana Certification #: Cert0082 Nebraska Certification #: NE-OS-29-14 Nevada Certification #: PA014572018-1 New Hampshire/TNI Certification #: 297617 New Jersey/TNI Certification #: PA051 New Mexico Certification #: PA01457 New York/TNI Certification #: 10888 North Carolina Certification #: 42706 North Dakota Certification #: R-190 Ohio EPA Rad Approval: #41249 Oregon/TNI Certification #: PA200002-010 Pennsylvania/TNI Certification #: 65-00282 Puerto Rico Certification #: PA01457 Rhode Island Certification #: 65-00282 South Dakota Certification Tennessee Certification #: 02867 Texas/TNI Certification #: T104704188-17-3 Utah/TNI Certification #: PA014572017-9 USDA Soil Permit #: P330-17-00091 Vermont Dept. of Health: ID# VT-0282 Virgin Island/PADEP Certification Virginia/VELAP Certification #: 9526 Washington Certification #: C868 West Virginia DEP Certification #: 143 West Virginia DHHR Certification #: 9964C Wisconsin Approve List for Rad Wyoming Certification #: 8TMS-L Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 20 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92416096001 TMW-4 EPA 8260B 63 PASI-CSAS ASTM D5174-97 1 PASI-PARMK HSL-300 3 PASI-PALAL EPA 300.0 Rev 2.1 1993 1 PASI-ACDC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 20 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92416096001 TMW-4 Total Uranium 4.97 ± 0.194 (0.262) C:NA T:NA ug/L 02/13/19 14:06ASTM D5174-97 Uranium-234 1.91 ± 0.399 (0.137) C:NA T:90% pCi/L 02/12/19 14:20 N2HSL-300 Uranium-235 0.177 ± 0.104 (0.040) C:NA T:90% pCi/L 02/12/19 14:20 N2HSL-300 Uranium-238 1.77 ± 0.377(0.123) C:NA T:90% pCi/L 02/12/19 14:20 N2HSL-300 Fluoride 0.36 mg/L 02/02/19 21:450.10EPA 300.0 Rev 2.1 1993 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Sample:TMW-4 Lab ID:92416096001 Collected:01/30/19 12:00 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Acetone ND ug/L 02/05/19 18:51 67-64-125.0 1 Benzene ND ug/L 02/05/19 18:51 71-43-21.0 1 Bromobenzene ND ug/L 02/05/19 18:51 108-86-11.0 1 Bromochloromethane ND ug/L 02/05/19 18:51 74-97-51.0 1 Bromodichloromethane ND ug/L 02/05/19 18:51 75-27-41.0 1 Bromoform ND ug/L 02/05/19 18:51 75-25-21.0 1 Bromomethane ND ug/L 02/05/19 18:51 74-83-92.0 1 2-Butanone (MEK)ND ug/L 02/05/19 18:51 78-93-35.0 1 Carbon tetrachloride ND ug/L 02/05/19 18:51 56-23-51.0 1 Chlorobenzene ND ug/L 02/05/19 18:51 108-90-71.0 1 Chloroethane ND ug/L 02/05/19 18:51 75-00-31.0 1 Chloroform ND ug/L 02/05/19 18:51 67-66-35.0 1 Chloromethane ND ug/L 02/05/19 18:51 74-87-31.0 1 2-Chlorotoluene ND ug/L 02/05/19 18:51 95-49-81.0 1 4-Chlorotoluene ND ug/L 02/05/19 18:51 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 18:51 96-12-82.0 1 Dibromochloromethane ND ug/L 02/05/19 18:51 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 02/05/19 18:51 106-93-41.0 1 Dibromomethane ND ug/L 02/05/19 18:51 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 02/05/19 18:51 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 02/05/19 18:51 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 02/05/19 18:51 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 02/05/19 18:51 75-71-81.0 1 1,1-Dichloroethane ND ug/L 02/05/19 18:51 75-34-31.0 1 1,2-Dichloroethane ND ug/L 02/05/19 18:51 107-06-21.0 1 1,1-Dichloroethene ND ug/L 02/05/19 18:51 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 02/05/19 18:51 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 02/05/19 18:51 156-60-51.0 1 1,2-Dichloropropane ND ug/L 02/05/19 18:51 78-87-51.0 1 1,3-Dichloropropane ND ug/L 02/05/19 18:51 142-28-91.0 1 2,2-Dichloropropane ND ug/L 02/05/19 18:51 594-20-71.0 1 1,1-Dichloropropene ND ug/L 02/05/19 18:51 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 02/05/19 18:51 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 02/05/19 18:51 10061-02-61.0 1 Diisopropyl ether ND ug/L 02/05/19 18:51 108-20-31.0 1 Ethylbenzene ND ug/L 02/05/19 18:51 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 02/05/19 18:51 87-68-31.0 1 2-Hexanone ND ug/L 02/05/19 18:51 591-78-65.0 1 p-Isopropyltoluene ND ug/L 02/05/19 18:51 99-87-61.0 1 Methylene Chloride ND ug/L 02/05/19 18:51 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 18:51 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 02/05/19 18:51 1634-04-41.0 1 Naphthalene ND ug/L 02/05/19 18:51 91-20-31.0 1 Styrene ND ug/L 02/05/19 18:51 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 18:51 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 18:51 79-34-51.0 1 Tetrachloroethene ND ug/L 02/05/19 18:51 127-18-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Sample:TMW-4 Lab ID:92416096001 Collected:01/30/19 12:00 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Toluene ND ug/L 02/05/19 18:51 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 02/05/19 18:51 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 02/05/19 18:51 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 02/05/19 18:51 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 02/05/19 18:51 79-00-51.0 1 Trichloroethene ND ug/L 02/05/19 18:51 79-01-61.0 1 Trichlorofluoromethane ND ug/L 02/05/19 18:51 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 02/05/19 18:51 96-18-41.0 1 Vinyl acetate ND ug/L 02/05/19 18:51 108-05-42.0 1 Vinyl chloride ND ug/L 02/05/19 18:51 75-01-41.0 1 Xylene (Total)ND ug/L 02/05/19 18:51 1330-20-71.0 1 m&p-Xylene ND ug/L 02/05/19 18:51 179601-23-12.0 1 o-Xylene ND ug/L 02/05/19 18:51 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %02/05/19 18:51 460-00-470-130 1 1,2-Dichloroethane-d4 (S)98 %02/05/19 18:51 17060-07-070-130 1 Toluene-d8 (S)101 %02/05/19 18:51 2037-26-570-130 1 Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days Fluoride 0.36 mg/L 02/02/19 21:45 16984-48-80.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 456399 EPA 8260B EPA 8260B 8260 MSV Low Level Associated Lab Samples:92416096001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2490025 Associated Lab Samples:92416096001 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09 1,1,1-Trichloroethane ug/L ND 1.0 02/05/19 13:09 1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09 1,1,2-Trichloroethane ug/L ND 1.0 02/05/19 13:09 1,1-Dichloroethane ug/L ND 1.0 02/05/19 13:09 1,1-Dichloroethene ug/L ND 1.0 02/05/19 13:09 1,1-Dichloropropene ug/L ND 1.0 02/05/19 13:09 1,2,3-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2,3-Trichloropropane ug/L ND 1.0 02/05/19 13:09 1,2,4-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2-Dibromo-3-chloropropane ug/L ND 2.0 02/05/19 13:09 1,2-Dibromoethane (EDB)ug/L ND 1.0 02/05/19 13:09 1,2-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2-Dichloroethane ug/L ND 1.0 02/05/19 13:09 1,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09 1,3-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,3-Dichloropropane ug/L ND 1.0 02/05/19 13:09 1,4-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 2,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09 2-Butanone (MEK)ug/L ND 5.0 02/05/19 13:09 2-Chlorotoluene ug/L ND 1.0 02/05/19 13:09 2-Hexanone ug/L ND 5.0 02/05/19 13:09 4-Chlorotoluene ug/L ND 1.0 02/05/19 13:09 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/05/19 13:09 Acetone ug/L ND 25.0 02/05/19 13:09 Benzene ug/L ND 1.0 02/05/19 13:09 Bromobenzene ug/L ND 1.0 02/05/19 13:09 Bromochloromethane ug/L ND 1.0 02/05/19 13:09 Bromodichloromethane ug/L ND 1.0 02/05/19 13:09 Bromoform ug/L ND 1.0 02/05/19 13:09 Bromomethane ug/L ND 2.0 02/05/19 13:09 Carbon tetrachloride ug/L ND 1.0 02/05/19 13:09 Chlorobenzene ug/L ND 1.0 02/05/19 13:09 Chloroethane ug/L ND 1.0 02/05/19 13:09 Chloroform ug/L ND 5.0 02/05/19 13:09 Chloromethane ug/L ND 1.0 02/05/19 13:09 cis-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09 cis-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09 Dibromochloromethane ug/L ND 1.0 02/05/19 13:09 Dibromomethane ug/L ND 1.0 02/05/19 13:09 Dichlorodifluoromethane ug/L ND 1.0 02/05/19 13:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2490025 Associated Lab Samples:92416096001 Matrix:Water Analyzed Diisopropyl ether ug/L ND 1.0 02/05/19 13:09 Ethylbenzene ug/L ND 1.0 02/05/19 13:09 Hexachloro-1,3-butadiene ug/L ND 1.0 02/05/19 13:09 m&p-Xylene ug/L ND 2.0 02/05/19 13:09 Methyl-tert-butyl ether ug/L ND 1.0 02/05/19 13:09 Methylene Chloride ug/L ND 5.0 02/05/19 13:09 Naphthalene ug/L ND 1.0 02/05/19 13:09 o-Xylene ug/L ND 1.0 02/05/19 13:09 p-Isopropyltoluene ug/L ND 1.0 02/05/19 13:09 Styrene ug/L ND 1.0 02/05/19 13:09 Tetrachloroethene ug/L ND 1.0 02/05/19 13:09 Toluene ug/L ND 1.0 02/05/19 13:09 trans-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09 trans-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09 Trichloroethene ug/L ND 1.0 02/05/19 13:09 Trichlorofluoromethane ug/L ND 1.0 02/05/19 13:09 Vinyl acetate ug/L ND 2.0 02/05/19 13:09 Vinyl chloride ug/L ND 1.0 02/05/19 13:09 Xylene (Total)ug/L ND 1.0 02/05/19 13:09 1,2-Dichloroethane-d4 (S)%95 70-130 02/05/19 13:09 4-Bromofluorobenzene (S)%99 70-130 02/05/19 13:09 Toluene-d8 (S)%100 70-130 02/05/19 13:09 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2490026LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 52.550 105 70-130 1,1,1-Trichloroethane ug/L 49.450 99 70-130 1,1,2,2-Tetrachloroethane ug/L 51.150 102 70-130 1,1,2-Trichloroethane ug/L 51.050 102 70-130 1,1-Dichloroethane ug/L 48.650 97 70-130 1,1-Dichloroethene ug/L 50.850 102 70-130 1,1-Dichloropropene ug/L 47.850 96 70-130 1,2,3-Trichlorobenzene ug/L 52.750 105 70-130 1,2,3-Trichloropropane ug/L 49.550 99 70-130 1,2,4-Trichlorobenzene ug/L 51.850 104 70-130 1,2-Dibromo-3-chloropropane ug/L 47.650 95 70-130 1,2-Dibromoethane (EDB)ug/L 52.750 105 70-130 1,2-Dichlorobenzene ug/L 48.750 97 70-130 1,2-Dichloroethane ug/L 43.950 88 70-130 1,2-Dichloropropane ug/L 48.850 98 70-130 1,3-Dichlorobenzene ug/L 47.950 96 70-130 1,3-Dichloropropane ug/L 51.850 104 70-131 1,4-Dichlorobenzene ug/L 47.750 95 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2490026LABORATORY CONTROL SAMPLE: LCSSpike 2,2-Dichloropropane ug/L 50.150 100 69-130 2-Butanone (MEK)ug/L 105100 105 64-135 2-Chlorotoluene ug/L 47.950 96 70-130 2-Hexanone ug/L 103100 103 66-135 4-Chlorotoluene ug/L 47.450 95 70-130 4-Methyl-2-pentanone (MIBK)ug/L 98.7100 99 70-130 Acetone ug/L 93.0100 93 61-157 Benzene ug/L 49.550 99 70-130 Bromobenzene ug/L 48.350 97 70-130 Bromochloromethane ug/L 49.850 100 70-130 Bromodichloromethane ug/L 49.150 98 70-130 Bromoform ug/L 50.550 101 70-130 Bromomethane ug/L 43.050 86 38-130 Carbon tetrachloride ug/L 48.150 96 70-130 Chlorobenzene ug/L 49.050 98 70-130 Chloroethane ug/L 45.050 90 37-142 Chloroform ug/L 45.450 91 70-130 Chloromethane ug/L 45.950 92 48-130 cis-1,2-Dichloroethene ug/L 47.450 95 70-130 cis-1,3-Dichloropropene ug/L 51.850 104 70-130 Dibromochloromethane ug/L 47.250 94 70-130 Dibromomethane ug/L 49.950 100 70-130 Dichlorodifluoromethane ug/L 48.850 98 53-134 Diisopropyl ether ug/L 48.950 98 70-135 Ethylbenzene ug/L 49.050 98 70-130 Hexachloro-1,3-butadiene ug/L 51.050 102 68-132 m&p-Xylene ug/L 98.5100 98 70-130 Methyl-tert-butyl ether ug/L 51.250 102 70-130 Methylene Chloride ug/L 45.250 90 67-132 Naphthalene ug/L 50.450 101 70-130 o-Xylene ug/L 50.750 101 70-130 p-Isopropyltoluene ug/L 48.950 98 70-130 Styrene ug/L 51.650 103 70-130 Tetrachloroethene ug/L 52.250 104 69-130 Toluene ug/L 46.450 93 70-130 trans-1,2-Dichloroethene ug/L 48.150 96 70-130 trans-1,3-Dichloropropene ug/L 51.450 103 70-130 Trichloroethene ug/L 50.950 102 70-130 Trichlorofluoromethane ug/L 46.350 93 63-130 Vinyl acetate ug/L 106100 106 55-143 Vinyl chloride ug/L 49.350 99 70-131 Xylene (Total)ug/L 149150 99 70-130 1,2-Dichloroethane-d4 (S)%95 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%97 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92415883006 2490028 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 500 106 73-134105 1500ND530527 1,1,1-Trichloroethane ug/L 500 104 82-143107 2500ND522534 1,1,2,2-Tetrachloroethane ug/L 500 101 70-136103 2500ND503515 1,1,2-Trichloroethane ug/L 500 102 70-135106 4500ND511532 1,1-Dichloroethane ug/L 500 101 70-139102 2500ND503511 1,1-Dichloroethene ug/L 500 105 70-154108 2500ND526538 1,1-Dichloropropene ug/L 500 100 70-149101 2500ND498506 1,2,3-Trichlorobenzene ug/L 500 119 70-135110 8500ND597550 1,2,3-Trichloropropane ug/L 500 103 71-13798 5500ND515491 1,2,4-Trichlorobenzene ug/L 500 114 73-140108 6500ND572540 1,2-Dibromo-3-chloropropane ug/L 500 101 65-134101 0500ND504505 1,2-Dibromoethane (EDB)ug/L 500 104 70-137106 2500ND520530 1,2-Dichlorobenzene ug/L 500 105 70-133102 3500ND526508 1,2-Dichloroethane ug/L 500 89 70-13796 7500ND446479 1,2-Dichloropropane ug/L 500 102 70-140102 1500ND508512 1,3-Dichlorobenzene ug/L 500 104 70-135103 1500ND519514 1,3-Dichloropropane ug/L 500 106 70-143106 0500ND530529 1,4-Dichlorobenzene ug/L 500 103 70-133100 3500ND514501 2,2-Dichloropropane ug/L 500 80 61-14879 1500ND399396 2-Butanone (MEK)ug/L 1000 99 60-139104 51000ND9901040 2-Chlorotoluene ug/L 500 104 70-144104 0500ND520519 2-Hexanone ug/L 1000 99 65-138101 21000ND9871010 4-Chlorotoluene ug/L 500 104 70-137102 1500ND518512 4-Methyl-2-pentanone (MIBK)ug/L 1000 94 65-13597 31000ND943969 Acetone ug/L 1000 94 60-14895 11000ND939950 Benzene ug/L 500 104 70-151105 1500ND518523 Bromobenzene ug/L 500 104 70-136104 0500ND519521 Bromochloromethane ug/L 500 108 70-141109 1500ND538544 Bromodichloromethane ug/L 500 98 70-138100 1500ND491499 Bromoform ug/L 500 93 63-13096 3500ND463478 Bromomethane ug/L 500 99 15-15295 4500ND493476 Carbon tetrachloride ug/L 500 101 70-143103 2500ND505514 Chlorobenzene ug/L 500 103 70-138104 1500ND514519 Chloroethane ug/L 500 108 52-163108 0500ND540541 Chloroform ug/L 500 93 70-13995 2500ND482493 Chloromethane ug/L 500 101 41-139100 1500ND505499 cis-1,2-Dichloroethene ug/L 500 101 70-141104 35008.6J 516 529 cis-1,3-Dichloropropene ug/L 500 98 70-13799 1500ND488494 Dibromochloromethane ug/L 500 98 70-13497 1500ND489485 Dibromomethane ug/L 500 102 70-138105 3500ND508523 Dichlorodifluoromethane ug/L 500 103 47-155104 2500ND513521 Diisopropyl ether ug/L 500 97 63-14499 2500ND485493 Ethylbenzene ug/L 500 103 66-153104 0500ND517520 Hexachloro-1,3-butadiene ug/L 500 120 65-149111 8500ND602557 m&p-Xylene ug/L 1000 104 69-152104 01000ND10401040 Methyl-tert-butyl ether ug/L 500 100 54-156101 0500ND501503 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92415883006 2490028 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L 500 93 42-15993 0500ND498498 Naphthalene ug/L 500 112 61-148105 7500ND559523 o-Xylene ug/L 500 108 70-148107 1500ND539535 p-Isopropyltoluene ug/L 500 108 70-146106 2500ND542530 Styrene ug/L 500 104 70-135103 2500ND521513 Tetrachloroethene ug/L E50013559-143547 48500262033005360 Toluene ug/L 500 98 59-14899 2500ND488497 trans-1,2-Dichloroethene ug/L 500 103 70-146105 3500ND513526 trans-1,3-Dichloropropene ug/L 500 95 70-13598 3500ND476489 Trichloroethene ug/L 500 107 70-147114 650011.8J 548 580 Trichlorofluoromethane ug/L 500 101 70-148101 0500ND503503 Vinyl acetate ug/L 1000 99 49-15196 31000ND990962 Vinyl chloride ug/L 500 109 70-156107 2500ND544534 Xylene (Total)ug/L 1500 105 63-158105 01500ND15801580 1,2-Dichloroethane-d4 (S)%95 70-13094 4-Bromofluorobenzene (S)%100 70-130100 Toluene-d8 (S)%97 70-13096 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 456010 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 300.0 IC Anions Associated Lab Samples:92416096001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2488458 Associated Lab Samples:92416096001 Matrix:Water Analyzed Fluoride mg/L ND 0.10 02/02/19 12:57 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2488459LABORATORY CONTROL SAMPLE: LCSSpike Fluoride mg/L 2.52.5 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 2488460MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92416071001 2488461 MSD Result MSD % Rec RPD MSDMS Spike Conc. Fluoride mg/L 2.5 103 90-110104 12.5ND 2.6 2.6 Parameter Units MS Result % Rec Limits Qual% RecConc. 2488462MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92416071011 2488463 MSD Result MSD % Rec RPD MSDMS Spike Conc. Fluoride mg/L 2.5 100 90-110100 12.5ND 2.5 2.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 20 #=ARR# ANALYTICAL RESULTS - RADIOCHEMISTRY Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Sample:TMW-4 Lab ID:92416096001 Collected:01/30/19 12:00 Received:02/01/19 10:00 Matrix:Water Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod PWS:Site ID:Sample Type: Total Uranium 4.97 ± 0.194 (0.262) C:NA T:NA ug/L 02/13/19 14:06 7440-61-1ASTM D5174-97 Uranium-234 1.91 ± 0.399 (0.137) C:NA T:90%pCi/L 02/12/19 14:20 13966-29-5 N2HSL-300 Uranium-235 0.177 ± 0.104 (0.040) C:NA T:90%pCi/L 02/12/19 14:20 15117-96-1 N2HSL-300 Uranium-238 1.77 ± 0.377 (0.123) C:NA T:90% pCi/L 02/12/19 14:20 N2HSL-300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 20 #=QCR# QUALITY CONTROL - RADIOCHEMISTRY Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 329379 ASTM D5174-97 ASTM D5174-97 D5174.97 Total Uranium KPA Associated Lab Samples:92416096001 Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers METHOD BLANK:1602577 Associated Lab Samples:92416096001 Matrix:Water Analyzed Total Uranium ug/L 02/13/19 13:180.085 ± 0.006 (0.262) C:NA T:NA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 20 #=QCR# QUALITY CONTROL - RADIOCHEMISTRY Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 329227 HSL-300 HSL-300 HSL300(AS) Actinides Associated Lab Samples:92416096001 Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers METHOD BLANK:1601815 Associated Lab Samples:92416096001 Matrix:Water Analyzed Uranium-234 pCi/L N202/12/19 14:200.072 ± 0.047 (0.054) C:NA T:87% Uranium-235 pCi/L N202/12/19 14:200.031 ± 0.037 (0.056) C:NA T:87% Uranium-238 pCi/L N202/12/19 14:200.012 ± 0.040 (0.077) C:NA T:87% REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 20 #=QL# QUALIFIERS Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Act - Activity Unc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval). Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval) (MDC) - Minimum Detectable Concentration Trac - Tracer Recovery (%) Carr - Carrier Recovery (%) Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - GreensburgPASI-PA ANALYTE QUALIFIERS Analyte concentration exceeded the calibration range. The reported result is estimated.E The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 20 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92416096 Castle Hayne Sand Mine II Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92416096001 456399TMW-4 EPA 8260B 92416096001 329379TMW-4 ASTM D5174-97 92416096001 329227TMW-4 HSL-300 92416096001 456010TMW-4 EPA 300.0 Rev 2.1 1993 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 20 Page 18 of 20 Page 19 of 20 Page 20 of 20 #=CL# February 13, 2019 LIMS USE: FR - SARAH KORDON LIMS OBJECT ID: 92416095 92416095 Project: Pace Project No.: RE: Sarah Kordon ECS Southeast 9001 Glenwood Ave Raleigh, NC 27617 Castle Hayne Sand Mine III Dear Sarah Kordon: Enclosed are the analytical results for sample(s) received by the laboratory on February 01, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Ezell taylor.ezell@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 20 #=CP# CERTIFICATIONS Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Pennsylvania Certification IDs 1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601 ANAB DOD-ELAP Rad Accreditation #: L2417 Alabama Certification #: 41590 Arizona Certification #: AZ0734 Arkansas Certification California Certification #: 04222CA Colorado Certification #: PA01547 Connecticut Certification #: PH-0694 Delaware Certification EPA Region 4 DW Rad Florida/TNI Certification #: E87683 Georgia Certification #: C040 Guam Certification Hawaii Certification Idaho Certification Illinois Certification Indiana Certification Iowa Certification #: 391 Kansas/TNI Certification #: E-10358 Kentucky Certification #: KY90133 KY WW Permit #: KY0098221 KY WW Permit #: KY0000221 Louisiana DHH/TNI Certification #: LA180012 Louisiana DEQ/TNI Certification #: 4086 Maine Certification #: 2017020 Maryland Certification #: 308 Massachusetts Certification #: M-PA1457 Michigan/PADEP Certification #: 9991 Missouri Certification #: 235 Montana Certification #: Cert0082 Nebraska Certification #: NE-OS-29-14 Nevada Certification #: PA014572018-1 New Hampshire/TNI Certification #: 297617 New Jersey/TNI Certification #: PA051 New Mexico Certification #: PA01457 New York/TNI Certification #: 10888 North Carolina Certification #: 42706 North Dakota Certification #: R-190 Ohio EPA Rad Approval: #41249 Oregon/TNI Certification #: PA200002-010 Pennsylvania/TNI Certification #: 65-00282 Puerto Rico Certification #: PA01457 Rhode Island Certification #: 65-00282 South Dakota Certification Tennessee Certification #: 02867 Texas/TNI Certification #: T104704188-17-3 Utah/TNI Certification #: PA014572017-9 USDA Soil Permit #: P330-17-00091 Vermont Dept. of Health: ID# VT-0282 Virgin Island/PADEP Certification Virginia/VELAP Certification #: 9526 Washington Certification #: C868 West Virginia DEP Certification #: 143 West Virginia DHHR Certification #: 9964C Wisconsin Approve List for Rad Wyoming Certification #: 8TMS-L Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 20 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92416095001 TMW-5 EPA 8260B 63 PASI-CSAS ASTM D5174-97 1 PASI-PARMK HSL-300 3 PASI-PALAL EPA 300.0 Rev 2.1 1993 1 PASI-ACDC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 20 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92416095001 TMW-5 Total Uranium 3.55 ± 0.178 (0.262) C:NA T:NA ug/L 02/13/19 14:04ASTM D5174-97 Uranium-234 2.48 ± 0.498 (0.167) C:NA T:84% pCi/L 02/12/19 14:20 N2HSL-300 Uranium-235 0.199 ± 0.116 (0.045) C:NA T:84% pCi/L 02/12/19 14:20 N2HSL-300 Uranium-238 2.06 ± 0.432(0.118) C:NA T:84% pCi/L 02/12/19 14:20 N2HSL-300 Fluoride 0.39 mg/L 02/02/19 21:290.10EPA 300.0 Rev 2.1 1993 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Sample:TMW-5 Lab ID:92416095001 Collected:01/30/19 17:00 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Acetone ND ug/L 02/05/19 18:34 67-64-125.0 1 Benzene ND ug/L 02/05/19 18:34 71-43-21.0 1 Bromobenzene ND ug/L 02/05/19 18:34 108-86-11.0 1 Bromochloromethane ND ug/L 02/05/19 18:34 74-97-51.0 1 Bromodichloromethane ND ug/L 02/05/19 18:34 75-27-41.0 1 Bromoform ND ug/L 02/05/19 18:34 75-25-21.0 1 Bromomethane ND ug/L 02/05/19 18:34 74-83-92.0 1 2-Butanone (MEK)ND ug/L 02/05/19 18:34 78-93-35.0 1 Carbon tetrachloride ND ug/L 02/05/19 18:34 56-23-51.0 1 Chlorobenzene ND ug/L 02/05/19 18:34 108-90-71.0 1 Chloroethane ND ug/L 02/05/19 18:34 75-00-31.0 1 Chloroform ND ug/L 02/05/19 18:34 67-66-35.0 1 Chloromethane ND ug/L 02/05/19 18:34 74-87-31.0 1 2-Chlorotoluene ND ug/L 02/05/19 18:34 95-49-81.0 1 4-Chlorotoluene ND ug/L 02/05/19 18:34 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 18:34 96-12-82.0 1 Dibromochloromethane ND ug/L 02/05/19 18:34 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 02/05/19 18:34 106-93-41.0 1 Dibromomethane ND ug/L 02/05/19 18:34 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 02/05/19 18:34 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 02/05/19 18:34 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 02/05/19 18:34 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 02/05/19 18:34 75-71-81.0 1 1,1-Dichloroethane ND ug/L 02/05/19 18:34 75-34-31.0 1 1,2-Dichloroethane ND ug/L 02/05/19 18:34 107-06-21.0 1 1,1-Dichloroethene ND ug/L 02/05/19 18:34 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 02/05/19 18:34 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 02/05/19 18:34 156-60-51.0 1 1,2-Dichloropropane ND ug/L 02/05/19 18:34 78-87-51.0 1 1,3-Dichloropropane ND ug/L 02/05/19 18:34 142-28-91.0 1 2,2-Dichloropropane ND ug/L 02/05/19 18:34 594-20-71.0 1 1,1-Dichloropropene ND ug/L 02/05/19 18:34 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 02/05/19 18:34 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 02/05/19 18:34 10061-02-61.0 1 Diisopropyl ether ND ug/L 02/05/19 18:34 108-20-31.0 1 Ethylbenzene ND ug/L 02/05/19 18:34 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 02/05/19 18:34 87-68-31.0 1 2-Hexanone ND ug/L 02/05/19 18:34 591-78-65.0 1 p-Isopropyltoluene ND ug/L 02/05/19 18:34 99-87-61.0 1 Methylene Chloride ND ug/L 02/05/19 18:34 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 18:34 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 02/05/19 18:34 1634-04-41.0 1 Naphthalene ND ug/L 02/05/19 18:34 91-20-31.0 1 Styrene ND ug/L 02/05/19 18:34 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 18:34 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 18:34 79-34-51.0 1 Tetrachloroethene ND ug/L 02/05/19 18:34 127-18-41.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 20 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Sample:TMW-5 Lab ID:92416095001 Collected:01/30/19 17:00 Received:02/01/19 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260B8260 MSV Low Level Toluene ND ug/L 02/05/19 18:34 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 02/05/19 18:34 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 02/05/19 18:34 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 02/05/19 18:34 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 02/05/19 18:34 79-00-51.0 1 Trichloroethene ND ug/L 02/05/19 18:34 79-01-61.0 1 Trichlorofluoromethane ND ug/L 02/05/19 18:34 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 02/05/19 18:34 96-18-41.0 1 Vinyl acetate ND ug/L 02/05/19 18:34 108-05-42.0 1 Vinyl chloride ND ug/L 02/05/19 18:34 75-01-41.0 1 Xylene (Total)ND ug/L 02/05/19 18:34 1330-20-71.0 1 m&p-Xylene ND ug/L 02/05/19 18:34 179601-23-12.0 1 o-Xylene ND ug/L 02/05/19 18:34 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)99 %02/05/19 18:34 460-00-470-130 1 1,2-Dichloroethane-d4 (S)97 %02/05/19 18:34 17060-07-070-130 1 Toluene-d8 (S)99 %02/05/19 18:34 2037-26-570-130 1 Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days Fluoride 0.39 mg/L 02/02/19 21:29 16984-48-80.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 456399 EPA 8260B EPA 8260B 8260 MSV Low Level Associated Lab Samples:92416095001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2490025 Associated Lab Samples:92416095001 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09 1,1,1-Trichloroethane ug/L ND 1.0 02/05/19 13:09 1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09 1,1,2-Trichloroethane ug/L ND 1.0 02/05/19 13:09 1,1-Dichloroethane ug/L ND 1.0 02/05/19 13:09 1,1-Dichloroethene ug/L ND 1.0 02/05/19 13:09 1,1-Dichloropropene ug/L ND 1.0 02/05/19 13:09 1,2,3-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2,3-Trichloropropane ug/L ND 1.0 02/05/19 13:09 1,2,4-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2-Dibromo-3-chloropropane ug/L ND 2.0 02/05/19 13:09 1,2-Dibromoethane (EDB)ug/L ND 1.0 02/05/19 13:09 1,2-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,2-Dichloroethane ug/L ND 1.0 02/05/19 13:09 1,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09 1,3-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 1,3-Dichloropropane ug/L ND 1.0 02/05/19 13:09 1,4-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09 2,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09 2-Butanone (MEK)ug/L ND 5.0 02/05/19 13:09 2-Chlorotoluene ug/L ND 1.0 02/05/19 13:09 2-Hexanone ug/L ND 5.0 02/05/19 13:09 4-Chlorotoluene ug/L ND 1.0 02/05/19 13:09 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/05/19 13:09 Acetone ug/L ND 25.0 02/05/19 13:09 Benzene ug/L ND 1.0 02/05/19 13:09 Bromobenzene ug/L ND 1.0 02/05/19 13:09 Bromochloromethane ug/L ND 1.0 02/05/19 13:09 Bromodichloromethane ug/L ND 1.0 02/05/19 13:09 Bromoform ug/L ND 1.0 02/05/19 13:09 Bromomethane ug/L ND 2.0 02/05/19 13:09 Carbon tetrachloride ug/L ND 1.0 02/05/19 13:09 Chlorobenzene ug/L ND 1.0 02/05/19 13:09 Chloroethane ug/L ND 1.0 02/05/19 13:09 Chloroform ug/L ND 5.0 02/05/19 13:09 Chloromethane ug/L ND 1.0 02/05/19 13:09 cis-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09 cis-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09 Dibromochloromethane ug/L ND 1.0 02/05/19 13:09 Dibromomethane ug/L ND 1.0 02/05/19 13:09 Dichlorodifluoromethane ug/L ND 1.0 02/05/19 13:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2490025 Associated Lab Samples:92416095001 Matrix:Water Analyzed Diisopropyl ether ug/L ND 1.0 02/05/19 13:09 Ethylbenzene ug/L ND 1.0 02/05/19 13:09 Hexachloro-1,3-butadiene ug/L ND 1.0 02/05/19 13:09 m&p-Xylene ug/L ND 2.0 02/05/19 13:09 Methyl-tert-butyl ether ug/L ND 1.0 02/05/19 13:09 Methylene Chloride ug/L ND 5.0 02/05/19 13:09 Naphthalene ug/L ND 1.0 02/05/19 13:09 o-Xylene ug/L ND 1.0 02/05/19 13:09 p-Isopropyltoluene ug/L ND 1.0 02/05/19 13:09 Styrene ug/L ND 1.0 02/05/19 13:09 Tetrachloroethene ug/L ND 1.0 02/05/19 13:09 Toluene ug/L ND 1.0 02/05/19 13:09 trans-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09 trans-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09 Trichloroethene ug/L ND 1.0 02/05/19 13:09 Trichlorofluoromethane ug/L ND 1.0 02/05/19 13:09 Vinyl acetate ug/L ND 2.0 02/05/19 13:09 Vinyl chloride ug/L ND 1.0 02/05/19 13:09 Xylene (Total)ug/L ND 1.0 02/05/19 13:09 1,2-Dichloroethane-d4 (S)%95 70-130 02/05/19 13:09 4-Bromofluorobenzene (S)%99 70-130 02/05/19 13:09 Toluene-d8 (S)%100 70-130 02/05/19 13:09 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2490026LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 52.550 105 70-130 1,1,1-Trichloroethane ug/L 49.450 99 70-130 1,1,2,2-Tetrachloroethane ug/L 51.150 102 70-130 1,1,2-Trichloroethane ug/L 51.050 102 70-130 1,1-Dichloroethane ug/L 48.650 97 70-130 1,1-Dichloroethene ug/L 50.850 102 70-130 1,1-Dichloropropene ug/L 47.850 96 70-130 1,2,3-Trichlorobenzene ug/L 52.750 105 70-130 1,2,3-Trichloropropane ug/L 49.550 99 70-130 1,2,4-Trichlorobenzene ug/L 51.850 104 70-130 1,2-Dibromo-3-chloropropane ug/L 47.650 95 70-130 1,2-Dibromoethane (EDB)ug/L 52.750 105 70-130 1,2-Dichlorobenzene ug/L 48.750 97 70-130 1,2-Dichloroethane ug/L 43.950 88 70-130 1,2-Dichloropropane ug/L 48.850 98 70-130 1,3-Dichlorobenzene ug/L 47.950 96 70-130 1,3-Dichloropropane ug/L 51.850 104 70-131 1,4-Dichlorobenzene ug/L 47.750 95 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2490026LABORATORY CONTROL SAMPLE: LCSSpike 2,2-Dichloropropane ug/L 50.150 100 69-130 2-Butanone (MEK)ug/L 105100 105 64-135 2-Chlorotoluene ug/L 47.950 96 70-130 2-Hexanone ug/L 103100 103 66-135 4-Chlorotoluene ug/L 47.450 95 70-130 4-Methyl-2-pentanone (MIBK)ug/L 98.7100 99 70-130 Acetone ug/L 93.0100 93 61-157 Benzene ug/L 49.550 99 70-130 Bromobenzene ug/L 48.350 97 70-130 Bromochloromethane ug/L 49.850 100 70-130 Bromodichloromethane ug/L 49.150 98 70-130 Bromoform ug/L 50.550 101 70-130 Bromomethane ug/L 43.050 86 38-130 Carbon tetrachloride ug/L 48.150 96 70-130 Chlorobenzene ug/L 49.050 98 70-130 Chloroethane ug/L 45.050 90 37-142 Chloroform ug/L 45.450 91 70-130 Chloromethane ug/L 45.950 92 48-130 cis-1,2-Dichloroethene ug/L 47.450 95 70-130 cis-1,3-Dichloropropene ug/L 51.850 104 70-130 Dibromochloromethane ug/L 47.250 94 70-130 Dibromomethane ug/L 49.950 100 70-130 Dichlorodifluoromethane ug/L 48.850 98 53-134 Diisopropyl ether ug/L 48.950 98 70-135 Ethylbenzene ug/L 49.050 98 70-130 Hexachloro-1,3-butadiene ug/L 51.050 102 68-132 m&p-Xylene ug/L 98.5100 98 70-130 Methyl-tert-butyl ether ug/L 51.250 102 70-130 Methylene Chloride ug/L 45.250 90 67-132 Naphthalene ug/L 50.450 101 70-130 o-Xylene ug/L 50.750 101 70-130 p-Isopropyltoluene ug/L 48.950 98 70-130 Styrene ug/L 51.650 103 70-130 Tetrachloroethene ug/L 52.250 104 69-130 Toluene ug/L 46.450 93 70-130 trans-1,2-Dichloroethene ug/L 48.150 96 70-130 trans-1,3-Dichloropropene ug/L 51.450 103 70-130 Trichloroethene ug/L 50.950 102 70-130 Trichlorofluoromethane ug/L 46.350 93 63-130 Vinyl acetate ug/L 106100 106 55-143 Vinyl chloride ug/L 49.350 99 70-131 Xylene (Total)ug/L 149150 99 70-130 1,2-Dichloroethane-d4 (S)%95 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%97 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92415883006 2490028 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 500 106 73-134105 1500ND530527 1,1,1-Trichloroethane ug/L 500 104 82-143107 2500ND522534 1,1,2,2-Tetrachloroethane ug/L 500 101 70-136103 2500ND503515 1,1,2-Trichloroethane ug/L 500 102 70-135106 4500ND511532 1,1-Dichloroethane ug/L 500 101 70-139102 2500ND503511 1,1-Dichloroethene ug/L 500 105 70-154108 2500ND526538 1,1-Dichloropropene ug/L 500 100 70-149101 2500ND498506 1,2,3-Trichlorobenzene ug/L 500 119 70-135110 8500ND597550 1,2,3-Trichloropropane ug/L 500 103 71-13798 5500ND515491 1,2,4-Trichlorobenzene ug/L 500 114 73-140108 6500ND572540 1,2-Dibromo-3-chloropropane ug/L 500 101 65-134101 0500ND504505 1,2-Dibromoethane (EDB)ug/L 500 104 70-137106 2500ND520530 1,2-Dichlorobenzene ug/L 500 105 70-133102 3500ND526508 1,2-Dichloroethane ug/L 500 89 70-13796 7500ND446479 1,2-Dichloropropane ug/L 500 102 70-140102 1500ND508512 1,3-Dichlorobenzene ug/L 500 104 70-135103 1500ND519514 1,3-Dichloropropane ug/L 500 106 70-143106 0500ND530529 1,4-Dichlorobenzene ug/L 500 103 70-133100 3500ND514501 2,2-Dichloropropane ug/L 500 80 61-14879 1500ND399396 2-Butanone (MEK)ug/L 1000 99 60-139104 51000ND9901040 2-Chlorotoluene ug/L 500 104 70-144104 0500ND520519 2-Hexanone ug/L 1000 99 65-138101 21000ND9871010 4-Chlorotoluene ug/L 500 104 70-137102 1500ND518512 4-Methyl-2-pentanone (MIBK)ug/L 1000 94 65-13597 31000ND943969 Acetone ug/L 1000 94 60-14895 11000ND939950 Benzene ug/L 500 104 70-151105 1500ND518523 Bromobenzene ug/L 500 104 70-136104 0500ND519521 Bromochloromethane ug/L 500 108 70-141109 1500ND538544 Bromodichloromethane ug/L 500 98 70-138100 1500ND491499 Bromoform ug/L 500 93 63-13096 3500ND463478 Bromomethane ug/L 500 99 15-15295 4500ND493476 Carbon tetrachloride ug/L 500 101 70-143103 2500ND505514 Chlorobenzene ug/L 500 103 70-138104 1500ND514519 Chloroethane ug/L 500 108 52-163108 0500ND540541 Chloroform ug/L 500 93 70-13995 2500ND482493 Chloromethane ug/L 500 101 41-139100 1500ND505499 cis-1,2-Dichloroethene ug/L 500 101 70-141104 35008.6J 516 529 cis-1,3-Dichloropropene ug/L 500 98 70-13799 1500ND488494 Dibromochloromethane ug/L 500 98 70-13497 1500ND489485 Dibromomethane ug/L 500 102 70-138105 3500ND508523 Dichlorodifluoromethane ug/L 500 103 47-155104 2500ND513521 Diisopropyl ether ug/L 500 97 63-14499 2500ND485493 Ethylbenzene ug/L 500 103 66-153104 0500ND517520 Hexachloro-1,3-butadiene ug/L 500 120 65-149111 8500ND602557 m&p-Xylene ug/L 1000 104 69-152104 01000ND10401040 Methyl-tert-butyl ether ug/L 500 100 54-156101 0500ND501503 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92415883006 2490028 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L 500 93 42-15993 0500ND498498 Naphthalene ug/L 500 112 61-148105 7500ND559523 o-Xylene ug/L 500 108 70-148107 1500ND539535 p-Isopropyltoluene ug/L 500 108 70-146106 2500ND542530 Styrene ug/L 500 104 70-135103 2500ND521513 Tetrachloroethene ug/L E50013559-143547 48500262033005360 Toluene ug/L 500 98 59-14899 2500ND488497 trans-1,2-Dichloroethene ug/L 500 103 70-146105 3500ND513526 trans-1,3-Dichloropropene ug/L 500 95 70-13598 3500ND476489 Trichloroethene ug/L 500 107 70-147114 650011.8J 548 580 Trichlorofluoromethane ug/L 500 101 70-148101 0500ND503503 Vinyl acetate ug/L 1000 99 49-15196 31000ND990962 Vinyl chloride ug/L 500 109 70-156107 2500ND544534 Xylene (Total)ug/L 1500 105 63-158105 01500ND15801580 1,2-Dichloroethane-d4 (S)%95 70-13094 4-Bromofluorobenzene (S)%100 70-130100 Toluene-d8 (S)%97 70-13096 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 20 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 456010 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 300.0 IC Anions Associated Lab Samples:92416095001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2488458 Associated Lab Samples:92416095001 Matrix:Water Analyzed Fluoride mg/L ND 0.10 02/02/19 12:57 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2488459LABORATORY CONTROL SAMPLE: LCSSpike Fluoride mg/L 2.52.5 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 2488460MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92416071001 2488461 MSD Result MSD % Rec RPD MSDMS Spike Conc. Fluoride mg/L 2.5 103 90-110104 12.5ND 2.6 2.6 Parameter Units MS Result % Rec Limits Qual% RecConc. 2488462MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92416071011 2488463 MSD Result MSD % Rec RPD MSDMS Spike Conc. Fluoride mg/L 2.5 100 90-110100 12.5ND 2.5 2.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 20 #=ARR# ANALYTICAL RESULTS - RADIOCHEMISTRY Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Sample:TMW-5 Lab ID:92416095001 Collected:01/30/19 17:00 Received:02/01/19 10:00 Matrix:Water Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod PWS:Site ID:Sample Type: Total Uranium 3.55 ± 0.178 (0.262) C:NA T:NA ug/L 02/13/19 14:04 7440-61-1ASTM D5174-97 Uranium-234 2.48 ± 0.498 (0.167) C:NA T:84%pCi/L 02/12/19 14:20 13966-29-5 N2HSL-300 Uranium-235 0.199 ± 0.116 (0.045) C:NA T:84%pCi/L 02/12/19 14:20 15117-96-1 N2HSL-300 Uranium-238 2.06 ± 0.432 (0.118) C:NA T:84% pCi/L 02/12/19 14:20 N2HSL-300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 20 #=QCR# QUALITY CONTROL - RADIOCHEMISTRY Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 329379 ASTM D5174-97 ASTM D5174-97 D5174.97 Total Uranium KPA Associated Lab Samples:92416095001 Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers METHOD BLANK:1602577 Associated Lab Samples:92416095001 Matrix:Water Analyzed Total Uranium ug/L 02/13/19 13:180.085 ± 0.006 (0.262) C:NA T:NA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 20 #=QCR# QUALITY CONTROL - RADIOCHEMISTRY Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 329227 HSL-300 HSL-300 HSL300(AS) Actinides Associated Lab Samples:92416095001 Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers METHOD BLANK:1601815 Associated Lab Samples:92416095001 Matrix:Water Analyzed Uranium-234 pCi/L N202/12/19 14:200.072 ± 0.047 (0.054) C:NA T:87% Uranium-235 pCi/L N202/12/19 14:200.031 ± 0.037 (0.056) C:NA T:87% Uranium-238 pCi/L N202/12/19 14:200.012 ± 0.040 (0.077) C:NA T:87% REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 20 #=QL# QUALIFIERS Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Act - Activity Unc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval). Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval) (MDC) - Minimum Detectable Concentration Trac - Tracer Recovery (%) Carr - Carrier Recovery (%) Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - GreensburgPASI-PA ANALYTE QUALIFIERS Analyte concentration exceeded the calibration range. The reported result is estimated.E The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 20 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92416095 Castle Hayne Sand Mine III Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92416095001 456399TMW-5 EPA 8260B 92416095001 329379TMW-5 ASTM D5174-97 92416095001 329227TMW-5 HSL-300 92416095001 456010TMW-5 EPA 300.0 Rev 2.1 1993 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 20 Page 18 of 20 Page 19 of 20 Page 20 of 20