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HomeMy WebLinkAboutECS Revised Sandmine GW Report 2-27-19REPORT OF ENVIRONMENTAL ASSESSMENT
CASTLE HAYNE – SAND MINE
4117 CASTLE HAYNE ROAD
CASTLE HAYNE, NEW HANOVER COUNTY, NORTH CAROLINA
ECS PROJECT 49:8748
PREPARED FOR:
HILTON PROPERTIES, LLC
REVISED FEBURARY 27, 2019
Revised February 27, 2019
Ms. Jennifer Martin and Mr. David Fort Hilton Properties, LLC 404 Fairway Road Myrtle Beach, South Carolina 29572
Reference: Report of Environmental Assessment Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina ECS Project Number 49:8748
Dear Ms. Martin and Mr. Fort:
ECS Southeast, LLP (ECS) is pleased to provide Hilton Properties, LLC with the results of our Environmental Assessment for the above-referenced site. ECS’s services were provided in accordance with ECS proposal No. 49:12920P dated January 22, 2019 and the accepted Terms and Conditions dated January 28, 2019. ECS appreciates the opportunity to provide our services to you. If there are questions regarding this report, or a need for further information, please contact us.
Respectfully submitted,
ECS SOUTHEAST, LLP
Sarah Kordon Fraser
Environmental Staff Project Manager
skordon@ecslimited.com
919-616-8145
Matthew H. McDuffie, P.G.
Principal Geologist
mmcduffie@ecslimited.com
704-525-5152
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
1
TABLE OF CONTENTS
1.0 PROJECT INFORMATION .................................................................................................................... 1
2.0 SCOPE OF SERVICES ............................................................................................................................ 1
3.0 ASSESSMENT RESULTS ....................................................................................................................... 3
4.0 CONCLUSIONS .................................................................................................................................... 4
5.0 RECOMMENDATIONS ......................................................................................................................... 4
6.0 QUALIFICATIONS OF REPORT ............................................................................................................. 4
FIGURES
Figure 1 Topographic Location Map Figure 2 Groundwater Sample Location Map
TABLES
Table 1 Summary of VOC Results in Groundwater Table 2 Summary of Inorganic Results in Groundwater
APPENDICES
Appendix A Photograph Log Appendix B GW-1 Forms – Well Construction Records Appendix C GW-30 Form – Well Abandonment Record Appendix D Laboratory Analytical Data and Chain of Custody (COC) Record
1
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
1.0 PROJECT INFORMATION
The site consists of vacant wooded acreage along the western-most portion of an approximately 63-acre
land tract near Sledge Road and Castle Hayne Road in Castle Hayne, New Hanover County, North
Carolina (Figure 10. The New Hanover County Geographic Information Systems (GIS) identifies the
property with parcel identification number (PIN) R00900-001-002-000 and indicates the property is
owned by Hilton Properties Limited Partnership and is addressed as 4117 Castle Hayne Road. ECS
further understands that proposed redevelopment incudes the use of the site as a sand mine.
ECS has been requested to assess groundwater quality on the western-most portion, deemed ‘Phase I,’
of proposed sand mine development in relation to known areas of contamination in the portion deemed
‘Phase II.’ The areas depicted as Phase I and Phase II are included in Figure 2. Project information was
obtained from conversations between Mr. William Toole of Robinson Bradshaw and ECS.
ECS conducted a previous geotechnical engineering assessment of the property (ECS Project 22:26252
Dated February 6, 2018). The report described current site conditions as moderately wooded with a
path around the perimeter with a cleared portion near the northern corner of the site. Groundwater
depths measured at the time of geotechnical drilling ranged from 12.5 to 22.0 feet below ground
surface (bgs). However, the groundwater levels may have been influenced by the use of drilling fluids.
ECS also was provided a copy of the 2017 Annual Water Monitoring Report of the Northwest Site Area
of the General Electric/Global Nuclear Fuel (GE/GNF) Site, which is located adjacent to the subject site
(Amec Foster Wheeler Environment & Infrastructure, Inc. (Amec Foster Wheeler) Project 6550-16-
0001.02 dated May 22, 2018). The northwest site area is situated more than one mile from the active
portion of the GE/GNF facility and the Northeast Cape Fear River. There are two areas of concern in the
Northwest Site Area. These areas include the Former Calcium Fluoride Storage Area and the Former
Lubricants Storage Area, as shown in Figures 1 and 2. These former storage areas were operated in the
1960s and 1970s and were subsequently removed upon cessation of operations. The former operations
resulted in the unintended release of volatile organic compounds (VOCs), fluoride, and uranium to soils.
The sources of the releases were either removed through excavation, or have depleted over time
through natural attenuation. On behalf of GE/GNF, Amec Foster Wheeler conducted semiannual
sampling events of 14 wells conducted in January and August 2017 with seven additional wells sampled
annually in August in the Northwest Site Area. The 2017 monitoring results were generally consistent
with previous monitoring and assessment results. Amec Foster Wheeler reported that the 2017
groundwater sampling and analysis data indicated that the concentrations are generally stable and
attenuating through natural processes. Groundwater flow has been measured to flow to the north-
northwest – towards adjacent swampy areas off-site – encroaching on to the subject site.
Water samples were collected for analysis of VOCs from five groundwater monitoring wells and three
surface water sampling locations near the former lubricants area. Numerous VOCs including vinyl
chloride, cis-1,2-dichloroethylene, and trichloroethylene were detected above laboratory reporting
limits or their respective NCAC 2L groundwater quality standard (NC2LGWQS) on-site and off-site.
2
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
Fluoride was detected in groundwater from well CAF-6B (2.3 milligrams per liter (mg/L)) in January 2017
and 2.6 mg/L in August 2017) and from well CAF-8B (2.3 mg/L in August) in excess of the 2 mg/L
NC2LGWQS. CAF-6B is located immediately north of the former storage area and CAF-8B is located to
the east CAF-6B on the Northwest Site Area.
Of the 21 groundwater samples collected and analyzed for uranium, one sample from well CAF-7A at
0.06 mg/L was found to exceed the project-specific guideline value for the site of 0.045 mg/L. The
uranium results for the two downgradient wells indicate that OCW-4A and OCW-4B (located off the
property), did not exceed the 0.045 mg/L value, indicating that uranium is not migrating off of the
property. Twelve of the 21 samples were measured for isotopic uranium. These 12 samples were found
in excess of the natural abundance of 235U. These samples were collected from wells CAF-6A, CAF-6B,
CAF-7A, CAF-8A, CAF-8B, CAF-12A, and OCW-4B. Historical data indicates uranium concentration trends
have been relatively stable over time. These trends were consistent with the understanding that
uranium is relatively immobile and remain at low concentrations in the Northwest Site Area. The report
concluded that results demonstrated no evidence of new chemical releases and that human health and
protection of the environment has been achieved and the current concentrations are not predicted to
pose a significant threat to human health or the environment.
ECS has been requested to sample groundwater at the Phase I proposed sand mine to assess for
potential impacts from the adjacent GE/GNF Former Calcium Fluoride Storage Area and the Former
Lubricants Storage Area.
2.0 SCOPE OF SERVICES
The environmental assessment consisted of collecting groundwater samples. However, ECS originally
proposed the collection of groundwater samples using a Geoprobe® by a subcontractor: Quantex, LLC,
however, several paths transecting the site were altered by recent precipitation events. Due to the
access limitations for the heavy drilling machinery, the temporary groundwater monitoring wells were
advanced manually utilizing a decontaminated hand auger by Quantex, LLC on January 30, 2019. A
photograph log documenting field activities is provided in Appendix A.
2.1 Public Utility Locate
Prior to implementing the field activities, ECS contacted North Carolina One Call to locate/mark public
utilities at the site. Required separation distances between subsurface activities and marked utilities
(typically 30-inches) were maintained during the field activities.
2.2 Temporary Monitoring Well Installation and Abandonment Activities
ECS supervised the manual installation of five temporary monitoring wells (TMW-1 through TMW-5) to
collect five groundwater samples from the Phase I area at the subject site. Temporary monitoring wells
TMW-1 through TMW-3 were installed in central wooded positions. Temporary monitoring well TMW-4
was installed near the down-gradient clearing at the northern portion of the subject site. Temporary
monitoring well TMW-5 was installed near the Phase I/II boundary and property boundary shared by the
adjacent GE/GNF property near the Former Calcium Fluoride Storage Area. The locations of the temporary
monitoring wells are shown on Figure 2. Monitoring Well Construction Forms are included in Appendix B.
3
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
Temporary monitoring wells TMW-1, 2, and 5 were installed to a total depth of 20 feet bgs., temporary
monitoring well TMW-3 was installed to a depth of 15 feet bgs., and temporary monitoring well TMW-4 was
installed to a depth of 6 feet bgs.
The temporary wells were constructed with one-inch inner diameter Schedule 40 PVC flush-threaded casing
and screen. The PVC screen and casing were lowered into the open borehole. Lengths of slotted well screen
with machined 0.010-inch slot widths and a threaded bottom plug were installed at the bottom of each
well. A solid section of PVC casing was placed above the screened interval and extended to a point just
above the ground surface. The annular space around each well was filled with a washed and graded,
medium sand to approximately two feet above the top of the screen. Groundwater was encountered at
depths ranging from 1.52 feet bgs to 16.61 feet bgs, as relatively gauged from the top of casing.
Following the completion of the groundwater gauging and sampling activities, temporary monitoring well
borings were properly abandoned and grouted. Copies of the well abandonment forms are included in
Appendix C.
2.3 Groundwater Sample Collection
Groundwater was purged and sampled subsequent to being pumped to the surface using a peristaltic
pump with dedicated disposable polyethylene tubing lowered through the temporary monitoring well
casing. Groundwater samples TMW-1 through TMW-5 were placed directly into laboratory prepared
containers at each sample location.
Groundwater sample containers were labeled with ECS project number, sample identification, sample
date and time, and requested analytical analysis. The containers were properly packaged and placed
into a cooler with ice to maintain the samples at approximately 4° Celsius (C°). Groundwater samples
were submitted for chemical analysis for VOCs using EPA method 8260, fluoride using EPA method
300.0, total uranium using ASTM Standard D5174, and isotopic uranium using HSL 300. Groundwater
laboratory analysis was conducted by Pace Analytical Services, LLC (Pace) located in Huntersville and
Asheville, North Carolina and Greensburg, Pennsylvania. ECS maintained proper COC procedures
throughout the sample collection and transportation process. Copies of the COCs are included in Appendix
D.
3.0 ASSESSMENT RESULTS
•Laboratory analysis of the groundwater samples collected from temporary monitoring wells
TMW-1 through TMW-5 did not report detections of VOCs above laboratory reporting limits.
•Laboratory analysis of the groundwater samples collected from temporary monitoring wells
TMW-1 through TMW-3 did not report detections of fluoride above laboratory reporting limits.
Fluoride was detected at 0.36 and 0.39 mg/L in the groundwater samples collected from
temporary monitoring wells TMW-4 and TMW-5, respectively, below the NC2LGWQS of 2 mg/L.
o ECS notes that the presence of fluoride in groundwater is the result of natural and/or
anthropogenic sources. Natural sources are associated to the geological conditions of an
area.
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
4
•Laboratory analysis of the groundwater samples collected from temporary monitoring wells
TMW-1 through TMW-5 reported detectable concentrations of uranium in groundwater ranging
from 0.000138 mg/L to 0.00711 mg/L, below the Environmental Protection Agency (EPA)
maximum contaminant level (MCL) for National Primary Drinking Water Regulations for uranium
of 0.03 mg/L.
A summary of the groundwater analytical results are provided on Tables 1 and 2. The laboratory
analytical package is included in Appendix D.
4.0 CONCLUSIONS
Based on the results of the field activities and laboratory analysis, the detected concentrations of
inorganic compounds such as fluoride and uranium, in areas where assessed, were not reported at
concentrations exceeding their regulatory standards. VOCs were not detected at concentrations above
laboratory reporting limits in each of the groundwater samples.
The concentrations of fluoride and uranium, in areas where assessed, are considered consistent with the
findings of the 2017 Annual Water Monitoring Report of the Northwest Site Area of the General
Electric/Global Nuclear Fuel (GE/GNF) Site, which concluded that analytical results did not demonstrate
evidence of a significant threat to human health or the environment.
5.0 RECOMMENDATIONS
Based on the results of the environmental assessment, ECS recommends the following:
•A copy of this report should be shared with property owners.
•Based on a review of available historical data as well as the findings of this report, no further
assessment appears warranted at this time.
6.0 QUALIFICATIONS OF REPORT
The activities and evaluative approaches used in this assessment are consistent with those normally employed in environmental assessment projects of this type. Our evaluation of site conditions has been based on our understanding of the site project information and the data obtained during our field activities.
This report was prepared for the express use of Hilton Properties, LLC. Use of this report by other individuals or companies implies their acceptance of the General Conditions of Service of the original contract.
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
5
FIGURES
TMW-2
PHASE I
FIGURE 1
TOPOGRAPHIC LOCATION MAP
CASTLE HAYNE – SAND MINE
4117 CASTLE HAYNE ROAD
CASTLE HAYNE, NEW HANOVER COUNTY
NORTH CAROLINA
ECS PROJECT 49:8748
SOURCE:
2017 Annual Water
Monitoring Report
(AMEC REPORT DATED
MAY 22, 2018)
TMW-1
Approximate Location of Former Calcium Fluoride Storage Area
(Granted Unrestricted Area by at U.S. NRC in 2000)
Approximate Location of Former
Lubricants Storage Area
PHASE II
SITE
TMW-3
TMW-4
TMW-5
TMW-2
PHASE I
FIGURE 2
GROUNDWATER SAMPLE LOCATION MAP
CASTLE HAYNE – SAND MINE
4117 CASTLE HAYNE ROAD
CASTLE HAYNE, NEW HANOVER COUNTY
NORTH CAROLINA
ECS PROJECT 49:8748
SOURCE:
NEW HANOVER COUNTY GIS
2016
TMW-1
Approximate Location of Former Calcium Fluoride Storage Area
(Granted Unrestricted Area by at U.S. NRC in 2000)
LEGEND
Approximate Location of Temporary
Monitoring Well (TMW)
Approximate Location of Former
Lubricants Storage Area
PHASE II
SITE
TMW-3
TMW-4
TMW-5
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
6
TABLES
Sample ID TMW-1 TMW-2 TMW-3 TMW-4 TMW-5
Sample Date
Method (Parameter)
Targeted VOC Analytes ND ND ND ND ND --
Notes:
ND = Not Detected
VOC = Volatile Organic Compounds
NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013
GCL = NCDEQ's Gross Contamination Levels for Groundwater as of April 16, 2012
1/30/2019 NC2LGWQS GCL
EPA Method 8260
TABLE 1
SUMMARY OF VOC RESULTS IN GROUNDWATER
CASTLE HAYNE – SAND MINE
4117 CASTLE HAYNE ROAD
CASTLE HAYNE, NEW HANOVER COUNTY, NORTH CAROLINA
ECS PROJECT: 49:8748
Sample ID TMW-1 TMW-2 TMW-3 TMW-4 TMW-5
Sample Date
Method (Parameter)
Fluoride ND ND ND 0.36 0.39 2 -
Method (Parameter)
Total Uranium 0.000138 0.00388 0.00711 0.00497 0.00355 -0.03
Method (Parameter)
Uranium-234 0.000141 0.002475 0.004965 0.002865 0.003720 --
Uranium-235 0.000065 0.000164 0.000378 0.000266 0.000299 --
Uranium-238 0.000057 0.002295 0.004830 0.002655 0.003090 --
Notes:
Results are presented in milligrams per liter (mg/L)
NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of April 1, 2013
EPA MCL - Environmental Protection Agency Maximum Contaminant Level for National Primary Drinking Water Regulatio
pCi/L have been converted to mg/L for data illustraion purposes.
*** = Uranium 235 isotopic abundance is calculated by dividing the 235U concentration by the total uranium concentrati
NE = Not Established
ND = Not Detected
Values shown in the bold font exceed their respective water quality standard.
1/30/2019
TABLE 2
SUMMARY OF INORGANIC RESULTS IN GROUNDWATER
CASTLE HAYNE – SAND MINE
4117 CASTLE HAYNE ROAD
CASTLE HAYNE, NEW HANOVER COUNTY, NORTH CAROLINA
ECS PROJECT: 49:8748
ASTM D5174
EPA Method 300.0
HSL-300
NC2LGWQS EPA MCL
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
7
APPENDIX A
SITE PHOTOGRAPHS
Castle Hayne – Sand Mine
4117 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748
Photograph 1: View of the monitoring wells (presumably OCW-4A and OCW-4B) located on Phase II portion of subject site.
Photograph 2: View of subject property (left) and view of GE/GNF property (right).
SITE PHOTOGRAPHS
Castle Hayne – Sand Mine
4117 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748
Photograph 3: View of the bore hole associated with temporary monitoring well TMW-2.
Photograph 4: Additional view of off-site monitoring wells.
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
8
APPENDIX B
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_______________
JamesD.Barker
3106A
Quantex,Inc.
NA
✔
1/30/19 TMW-1
CastleHayneSandMills NA
SledgeRoad,CastleHayne,NC28429
NewHanover NA
34.33808777.956837
✔
✔
fivetotal
20'
NA
~2.5"
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!@9.1=;2B188>/;:>?=@/?10
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.
';?-8B18801<?4.18;B8-:0>@=2-/12?
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.,2&896*3+*68.+.*)#*003286&(836&8*By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
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nnningthishhhhhh formIherebycertifythatthe well(s)was(we
_______________
JamesD.Barker
3106A
Quantex,Inc.
NA
✔
1/30/19 TMW-2
CastleHayneSandMills NA
SledgeRoad,CastleHayne,NC28429
NewHanover NA
34.33808777.956837
✔
✔
fivetotal
20'
NA
~2.5"
DirectPushMethod
15 16 TanFineSANDS
0 10 1 Sch40PVC
10 20 1 0.010Sch40PVC
0 8 neat cement 25lbs.pour
8 9 Bentonite 15lbs.pour
9 20 #2sandPour
0 8 Lt.GreySiltySandyClay
8 20 TanFineSANDS
tempwellpropelyabandonedper2Crules,sameday.
2/15/19
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!@9.1=;2B188>/;:>?=@/?10
For multiple injection or non-water supply wells ONLY with the same construction, you can
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';?-8B18801<?4.18;B8-:0>@=2-/12?
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.,2&896*3+*68.+.*)#*003286&(836&8*By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
&5?105-3=-9;=-005?5;:-8B18801?-58>
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nnningthishhhhhh formIherebycertifythatthe well(s)was(we
_______________
JamesD.Barker
3106A
Quantex,Inc.
NA
✔
1/30/19 TMW-3
CastleHayneSandMills NA
SledgeRoad,CastleHayne,NC28429
NewHanover NA
34.33808777.956837
✔
✔
fivetotal
15'
NA
~2.5"
DirectPushMethod
8 9 TanFineSANDS
0 5 1 Sch40PVC
5 15 1 0.010Sch40PVC
0 3 neat cement 10lbs.pour
3 4 Bentonite 12lbs.pour
4 15 #2sandPour
0 6 Lt.GreySandyClay
6 15 TanFineSANDS
tempwellpropelyabandonedper2Crules,sameday.
2/15/19
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List all applicable well construction permits (i.e. County, State, Variance, etc.)
*188(>1/41/7B188@>1
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If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
!@9.1=;2B188>/;:>?=@/?10
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.
';?-8B18801<?4.18;B8-:0>@=2-/12?
For multiple wells list all depths if different (example- 3@200’ and 2@100?
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.,2&896*3+*68.+.*)#*003286&(836&8*By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
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nnningthishhhhhh formIherebycertifythatthe well(s)was(we
_______________
JamesD.Barker
3106A
Quantex,Inc.
NA
✔
1/30/19 TMW-4
CastleHayneSandMills NA
SledgeRoad,CastleHayne,NC28429
NewHanover NA
34.33808777.956837
✔
✔
fivetotal
6'
NA
~2.5"
HandAugerMethod
4 5 Tan/GreySANDS
0 4 1 Sch40PVC
4 6 1 0.010Sch40PVC
0 2.5 neat cement 15lbs.pour
2.5 3 Bentonite 15lbs.pour
3 6 #2sandPour
0 6 Tan/GreySANDS
tempwellpropelyabandonedper2Crules,sameday.
2/15/19
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!@9.1=;2B188>/;:>?=@/?10
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.
';?-8B18801<?4.18;B8-:0>@=2-/12?
For multiple wells list all depths if different (example- 3@200’ and 2@100?
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copy of this record has been provided to the well owner.
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.;=:61/?5;:*188>2&)).8.32837*2).2,8-*+361838-*&))6*77.2
&
&'3:*&07379'1.8&(34=3+8-.7+361;.8-.2 )&=73+(3140*8.323+;*00
(327869(8.32838-*+3003;.2,
5A5>5;:;2*-?1=$@-85?D(:01=3=;@:0:61/?5;:;:?=;8#=;3=-9
-58&1=A5/11:?1=%-81534!
/;=*-?1=&@<<8D
*188>2&)).8.32837*2).2,8-*+36183
8-*&))6*77*7&'3:*&07379'1.832*(34=3+8-.7+361;.8-.2 )&=73+
(3140*8.323+;*00(327869(8.32838-*(3928=-*&08-)*4&681*283+8-*(3928=
;-*6*(327869(8*)
3628*62&0"7*$
1111=?5222222222222225/5/5/5/5/5/5/5/5/5//5//55555 -??-?-??-?-??-?-?-??-??-?-?-?-??-?????-?-5;:
9996*3+*68.+.*)#*003286&(836
nnningthishhhhhh formIherebycertifythatthe well(s)was(we
_______________
JamesD.Barker
3106A
Quantex,Inc.
NA
✔
1/30/19 TMW-5
CastleHayneSandMills NA
SledgeRoad,CastleHayne,NC28429
NewHanover NA
34.33808777.956837
✔
✔
fivetotal
20'
NA
~2.5"
HandAugerMethod
16 17 TanFineSANDS
0 10 1 Sch40PVC
10 20 1 0.010Sch40PVC
0 8 neat cement 40lbs.pour
8 9 Bentonite 15lbs.pour
9 20 #2sandPour
0 7 Lt.GreySiltySandyClay
7 20 TanFineSANDS
tempwellpropelyabandonedper2Crules,sameday.
2/15/19
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
9
APPENDIX C
W E L L A B AND ON M E N T R E C O R D
This form can be used for single or multiple wells
Form GW-30 North Carolina Department of Environment and Natural Resources Division of Water Quality Revised March 2013
1. Well Contractor Information:
Well Contractor Name (or well owner personally abandoning well on his/her property)
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. County, State, Variance, etc.) if known
3. Well use (check well use):
Water Supply Well:
Agricultural Municipal/Public
Geothermal (Heating/Cooling Supply) Residential Water Supply (single)
Industrial/Commercial Residential Water Supply (shared)
Irrigation
Non-Water Supply Well:
Monitoring Recovery
Injection Well:
Aquifer Recharge Groundwater Remediation
Aquifer Storage and Recovery Salinity Barrier
Aquifer Test Stormwater Drainage
Experimental Technology Subsidence Control
Geothermal (Closed Loop) Tracer
Geothermal (Heating/Cooling Return) Other (explain under 7g)
4. Date well(s) abandoned:
5a. Well location:
Facility/Owner Name Facility ID# (if applicable)
Physical Address, City, and Zip
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
N W
CONST RUCTI O N DE TA ILS OF W EL L(S) BEING AB ANDONED
Attach well construction record(s) if available. For multiple injection or non-water supply
wells ONLY with the same construction/abandonment, you can submit one form.
6a. Well ID#:
6b. Total well depth: (ft.)
6c. Borehole diameter: (in.)
6d. Water level below ground surface: (ft.)
6e. Outer casing length (if known): (ft.)
6f. Inner casing/tubing length (if known): (ft.)
6g. Screen length (if known): (ft.)
W ELL ABA NDONMENT DET AILS
7a. Number of wells being abandoned:
For multiple injection or non-water supply wells ONLY with the same
construction/abandonment, you can submit one form.
7b. Approximate volume of water remaining in well(s): (gal.) F OR W AT ER SUPPLY WEL LS ONL Y:
7c. Type of disinfectant used:
7d. Amount of disinfectant used:
7e. Sealing materials used (check all that apply):
Neat Cement Grout Bentonite Chips or Pellets
Sand Cement Grout Dry Clay
Concrete Grout Drill Cuttings
Specialty Grout Gravel
Bentonite Slurry Other (explain under 7g)
7f. For each material selected above, provide amount of materials used:
7g. Provide a brief description of the abandonment procedure:
8. Certification:
Signature of Certified Well Contractor or Well Owner Date
By signing this form, I hereby certify that the well(s) was (were) abandoned in
accordance with 15A NCAC 02C .0100 or 2C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
9. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
abandonment details. You may also attach additional pages if necessary.
SUBMITT AL INSTRUC TIONS
10a. For All Wells: Submit this form within 30 days of completion of well
abandonment to the following:
Division of Water Quality, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617!
10b. For Injection Wells: In addition to sending the form to the address in 10a
above, also submit one copy of this form within 30 days of completion of well
abandonment to the following:
Division of Water Quality, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636!
10c. For Water Supply & Injection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
completion of well abandonment to the county health department of the county
where abandoned.
For Internal Use ONLY:
Report of Environmental Assessment - Castle Hayne – Sand Mine 4117 Castle Hayne Road Castle Hayne, New Hanover County, North Carolina
ECS Project Number 49:8748 Private and Confidential Revised February 27, 2019
10
APPENDIX D
#=CL#
February 13, 2019
LIMS USE: FR - SARAH KORDON
LIMS OBJECT ID: 92416093
92416093
Project:
Pace Project No.:
RE:
Sarah Kordon
ECS Southeast
9001 Glenwood Ave
Raleigh, NC 27617
Castle Hayne Sand Mine
Dear Sarah Kordon:
Enclosed are the analytical results for sample(s) received by the laboratory on February 01, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
taylor.ezell@pacelabs.com
Project Manager
(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 1 of 26
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Pennsylvania Certification IDs
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Guam Certification
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PA014572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TNI Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/TNI Certification #: PA200002-010
Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
Tennessee Certification #: 02867
Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
West Virginia DEP Certification #: 143
West Virginia DHHR Certification #: 9964C
Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 2 of 26
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92416093001 TMW-1 EPA 8260B 63 PASI-CSAS
ASTM D5174-97 1 PASI-PARMK
HSL-300 3 PASI-PALAL
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92416093002 TMW-2 EPA 8260B 63 PASI-CSAS
ASTM D5174-97 1 PASI-PARMK
HSL-300 3 PASI-PALAL
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92416093003 TMW-3 EPA 8260B 63 PASI-CSAS
ASTM D5174-97 1 PASI-PARMK
HSL-300 3 PASI-PALAL
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 3 of 26
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92416093001 TMW-1
Total Uranium 0.138 ±
0.009
(0.262)
C:NA T:NA
ug/L 02/13/19 13:57ASTM D5174-97
Uranium-234 0.094 ±
0.056
(0.066)
C:NA T:95%
pCi/L 02/12/19 14:24 N2HSL-300
Uranium-235 0.043 ±
0.040
(0.054)
C:NA T:95%
pCi/L 02/12/19 14:24 N2HSL-300
Uranium-238 0.038 ±
0.029(0.015)
C:NA T:95%
pCi/L 02/12/19 14:24 N2HSL-300
92416093002 TMW-2
Total Uranium 3.88 ±
0.150
(0.262)
C:NA T:NA
ug/L 02/13/19 13:59ASTM D5174-97
Uranium-234 1.65 ±
0.297
(0.041)
C:NA T:93%
pCi/L 02/12/19 14:20 N2HSL-300
Uranium-235 0.109 ±
0.057
(0.020)
C:NA T:93%
pCi/L 02/12/19 14:20 N2HSL-300
Uranium-238 1.53 ±
0.279
(0.041)
C:NA T:93%
pCi/L 02/12/19 14:20 N2HSL-300
92416093003 TMW-3
Total Uranium 7.11 ±
0.280(0.262)
C:NA T:NA
ug/L 02/13/19 14:02ASTM D5174-97
Uranium-234 3.31 ±
0.619
(0.139)
C:NA T:79%
pCi/L 02/12/19 14:20 N2HSL-300
Uranium-235 0.252 ±
0.148
(0.157)
C:NA T:79%
pCi/L 02/12/19 14:20 N2HSL-300
Uranium-238 3.22 ±
0.603
(0.095)
C:NA T:79%
pCi/L 02/12/19 14:20 N2HSL-300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 4 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-1 Lab ID:92416093001 Collected:01/30/19 14:15 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Acetone ND ug/L 02/05/19 17:43 67-64-125.0 1
Benzene ND ug/L 02/05/19 17:43 71-43-21.0 1
Bromobenzene ND ug/L 02/05/19 17:43 108-86-11.0 1
Bromochloromethane ND ug/L 02/05/19 17:43 74-97-51.0 1
Bromodichloromethane ND ug/L 02/05/19 17:43 75-27-41.0 1
Bromoform ND ug/L 02/05/19 17:43 75-25-21.0 1
Bromomethane ND ug/L 02/05/19 17:43 74-83-92.0 1
2-Butanone (MEK)ND ug/L 02/05/19 17:43 78-93-35.0 1
Carbon tetrachloride ND ug/L 02/05/19 17:43 56-23-51.0 1
Chlorobenzene ND ug/L 02/05/19 17:43 108-90-71.0 1
Chloroethane ND ug/L 02/05/19 17:43 75-00-31.0 1
Chloroform ND ug/L 02/05/19 17:43 67-66-35.0 1
Chloromethane ND ug/L 02/05/19 17:43 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/05/19 17:43 95-49-81.0 1
4-Chlorotoluene ND ug/L 02/05/19 17:43 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 17:43 96-12-82.0 1
Dibromochloromethane ND ug/L 02/05/19 17:43 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 02/05/19 17:43 106-93-41.0 1
Dibromomethane ND ug/L 02/05/19 17:43 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 02/05/19 17:43 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 02/05/19 17:43 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 02/05/19 17:43 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 02/05/19 17:43 75-71-81.0 1
1,1-Dichloroethane ND ug/L 02/05/19 17:43 75-34-31.0 1
1,2-Dichloroethane ND ug/L 02/05/19 17:43 107-06-21.0 1
1,1-Dichloroethene ND ug/L 02/05/19 17:43 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 02/05/19 17:43 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 02/05/19 17:43 156-60-51.0 1
1,2-Dichloropropane ND ug/L 02/05/19 17:43 78-87-51.0 1
1,3-Dichloropropane ND ug/L 02/05/19 17:43 142-28-91.0 1
2,2-Dichloropropane ND ug/L 02/05/19 17:43 594-20-71.0 1
1,1-Dichloropropene ND ug/L 02/05/19 17:43 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 02/05/19 17:43 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 02/05/19 17:43 10061-02-61.0 1
Diisopropyl ether ND ug/L 02/05/19 17:43 108-20-31.0 1
Ethylbenzene ND ug/L 02/05/19 17:43 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 02/05/19 17:43 87-68-31.0 1
2-Hexanone ND ug/L 02/05/19 17:43 591-78-65.0 1
p-Isopropyltoluene ND ug/L 02/05/19 17:43 99-87-61.0 1
Methylene Chloride ND ug/L 02/05/19 17:43 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 17:43 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 02/05/19 17:43 1634-04-41.0 1
Naphthalene ND ug/L 02/05/19 17:43 91-20-31.0 1
Styrene ND ug/L 02/05/19 17:43 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 17:43 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 17:43 79-34-51.0 1
Tetrachloroethene ND ug/L 02/05/19 17:43 127-18-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 5 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-1 Lab ID:92416093001 Collected:01/30/19 14:15 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Toluene ND ug/L 02/05/19 17:43 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 02/05/19 17:43 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 02/05/19 17:43 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 02/05/19 17:43 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 02/05/19 17:43 79-00-51.0 1
Trichloroethene ND ug/L 02/05/19 17:43 79-01-61.0 1
Trichlorofluoromethane ND ug/L 02/05/19 17:43 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/05/19 17:43 96-18-41.0 1
Vinyl acetate ND ug/L 02/05/19 17:43 108-05-42.0 1
Vinyl chloride ND ug/L 02/05/19 17:43 75-01-41.0 1
Xylene (Total)ND ug/L 02/05/19 17:43 1330-20-71.0 1
m&p-Xylene ND ug/L 02/05/19 17:43 179601-23-12.0 1
o-Xylene ND ug/L 02/05/19 17:43 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)101 %02/05/19 17:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %02/05/19 17:43 17060-07-070-130 1
Toluene-d8 (S)99 %02/05/19 17:43 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride ND mg/L 02/02/19 20:41 16984-48-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 6 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-2 Lab ID:92416093002 Collected:01/30/19 14:30 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Acetone ND ug/L 02/05/19 18:00 67-64-125.0 1
Benzene ND ug/L 02/05/19 18:00 71-43-21.0 1
Bromobenzene ND ug/L 02/05/19 18:00 108-86-11.0 1
Bromochloromethane ND ug/L 02/05/19 18:00 74-97-51.0 1
Bromodichloromethane ND ug/L 02/05/19 18:00 75-27-41.0 1
Bromoform ND ug/L 02/05/19 18:00 75-25-21.0 1
Bromomethane ND ug/L 02/05/19 18:00 74-83-92.0 1
2-Butanone (MEK)ND ug/L 02/05/19 18:00 78-93-35.0 1
Carbon tetrachloride ND ug/L 02/05/19 18:00 56-23-51.0 1
Chlorobenzene ND ug/L 02/05/19 18:00 108-90-71.0 1
Chloroethane ND ug/L 02/05/19 18:00 75-00-31.0 1
Chloroform ND ug/L 02/05/19 18:00 67-66-35.0 1
Chloromethane ND ug/L 02/05/19 18:00 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/05/19 18:00 95-49-81.0 1
4-Chlorotoluene ND ug/L 02/05/19 18:00 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 18:00 96-12-82.0 1
Dibromochloromethane ND ug/L 02/05/19 18:00 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 02/05/19 18:00 106-93-41.0 1
Dibromomethane ND ug/L 02/05/19 18:00 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 02/05/19 18:00 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 02/05/19 18:00 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 02/05/19 18:00 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 02/05/19 18:00 75-71-81.0 1
1,1-Dichloroethane ND ug/L 02/05/19 18:00 75-34-31.0 1
1,2-Dichloroethane ND ug/L 02/05/19 18:00 107-06-21.0 1
1,1-Dichloroethene ND ug/L 02/05/19 18:00 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 02/05/19 18:00 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 02/05/19 18:00 156-60-51.0 1
1,2-Dichloropropane ND ug/L 02/05/19 18:00 78-87-51.0 1
1,3-Dichloropropane ND ug/L 02/05/19 18:00 142-28-91.0 1
2,2-Dichloropropane ND ug/L 02/05/19 18:00 594-20-71.0 1
1,1-Dichloropropene ND ug/L 02/05/19 18:00 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 02/05/19 18:00 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 02/05/19 18:00 10061-02-61.0 1
Diisopropyl ether ND ug/L 02/05/19 18:00 108-20-31.0 1
Ethylbenzene ND ug/L 02/05/19 18:00 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 02/05/19 18:00 87-68-31.0 1
2-Hexanone ND ug/L 02/05/19 18:00 591-78-65.0 1
p-Isopropyltoluene ND ug/L 02/05/19 18:00 99-87-61.0 1
Methylene Chloride ND ug/L 02/05/19 18:00 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 18:00 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 02/05/19 18:00 1634-04-41.0 1
Naphthalene ND ug/L 02/05/19 18:00 91-20-31.0 1
Styrene ND ug/L 02/05/19 18:00 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 18:00 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 18:00 79-34-51.0 1
Tetrachloroethene ND ug/L 02/05/19 18:00 127-18-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
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Page 7 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-2 Lab ID:92416093002 Collected:01/30/19 14:30 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Toluene ND ug/L 02/05/19 18:00 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 02/05/19 18:00 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 02/05/19 18:00 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 02/05/19 18:00 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 02/05/19 18:00 79-00-51.0 1
Trichloroethene ND ug/L 02/05/19 18:00 79-01-61.0 1
Trichlorofluoromethane ND ug/L 02/05/19 18:00 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/05/19 18:00 96-18-41.0 1
Vinyl acetate ND ug/L 02/05/19 18:00 108-05-42.0 1
Vinyl chloride ND ug/L 02/05/19 18:00 75-01-41.0 1
Xylene (Total)ND ug/L 02/05/19 18:00 1330-20-71.0 1
m&p-Xylene ND ug/L 02/05/19 18:00 179601-23-12.0 1
o-Xylene ND ug/L 02/05/19 18:00 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)98 %02/05/19 18:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %02/05/19 18:00 17060-07-070-130 1
Toluene-d8 (S)101 %02/05/19 18:00 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride ND mg/L 02/02/19 20:57 16984-48-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 8 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-3 Lab ID:92416093003 Collected:01/30/19 14:45 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Acetone ND ug/L 02/05/19 18:17 67-64-125.0 1
Benzene ND ug/L 02/05/19 18:17 71-43-21.0 1
Bromobenzene ND ug/L 02/05/19 18:17 108-86-11.0 1
Bromochloromethane ND ug/L 02/05/19 18:17 74-97-51.0 1
Bromodichloromethane ND ug/L 02/05/19 18:17 75-27-41.0 1
Bromoform ND ug/L 02/05/19 18:17 75-25-21.0 1
Bromomethane ND ug/L 02/05/19 18:17 74-83-92.0 1
2-Butanone (MEK)ND ug/L 02/05/19 18:17 78-93-35.0 1
Carbon tetrachloride ND ug/L 02/05/19 18:17 56-23-51.0 1
Chlorobenzene ND ug/L 02/05/19 18:17 108-90-71.0 1
Chloroethane ND ug/L 02/05/19 18:17 75-00-31.0 1
Chloroform ND ug/L 02/05/19 18:17 67-66-35.0 1
Chloromethane ND ug/L 02/05/19 18:17 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/05/19 18:17 95-49-81.0 1
4-Chlorotoluene ND ug/L 02/05/19 18:17 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 18:17 96-12-82.0 1
Dibromochloromethane ND ug/L 02/05/19 18:17 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 02/05/19 18:17 106-93-41.0 1
Dibromomethane ND ug/L 02/05/19 18:17 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 02/05/19 18:17 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 02/05/19 18:17 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 02/05/19 18:17 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 02/05/19 18:17 75-71-81.0 1
1,1-Dichloroethane ND ug/L 02/05/19 18:17 75-34-31.0 1
1,2-Dichloroethane ND ug/L 02/05/19 18:17 107-06-21.0 1
1,1-Dichloroethene ND ug/L 02/05/19 18:17 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 02/05/19 18:17 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 02/05/19 18:17 156-60-51.0 1
1,2-Dichloropropane ND ug/L 02/05/19 18:17 78-87-51.0 1
1,3-Dichloropropane ND ug/L 02/05/19 18:17 142-28-91.0 1
2,2-Dichloropropane ND ug/L 02/05/19 18:17 594-20-71.0 1
1,1-Dichloropropene ND ug/L 02/05/19 18:17 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 02/05/19 18:17 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 02/05/19 18:17 10061-02-61.0 1
Diisopropyl ether ND ug/L 02/05/19 18:17 108-20-31.0 1
Ethylbenzene ND ug/L 02/05/19 18:17 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 02/05/19 18:17 87-68-31.0 1
2-Hexanone ND ug/L 02/05/19 18:17 591-78-65.0 1
p-Isopropyltoluene ND ug/L 02/05/19 18:17 99-87-61.0 1
Methylene Chloride ND ug/L 02/05/19 18:17 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 18:17 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 02/05/19 18:17 1634-04-41.0 1
Naphthalene ND ug/L 02/05/19 18:17 91-20-31.0 1
Styrene ND ug/L 02/05/19 18:17 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 18:17 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 18:17 79-34-51.0 1
Tetrachloroethene ND ug/L 02/05/19 18:17 127-18-41.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 9 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-3 Lab ID:92416093003 Collected:01/30/19 14:45 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Toluene ND ug/L 02/05/19 18:17 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 02/05/19 18:17 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 02/05/19 18:17 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 02/05/19 18:17 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 02/05/19 18:17 79-00-51.0 1
Trichloroethene ND ug/L 02/05/19 18:17 79-01-61.0 1
Trichlorofluoromethane ND ug/L 02/05/19 18:17 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/05/19 18:17 96-18-41.0 1
Vinyl acetate ND ug/L 02/05/19 18:17 108-05-42.0 1
Vinyl chloride ND ug/L 02/05/19 18:17 75-01-41.0 1
Xylene (Total)ND ug/L 02/05/19 18:17 1330-20-71.0 1
m&p-Xylene ND ug/L 02/05/19 18:17 179601-23-12.0 1
o-Xylene ND ug/L 02/05/19 18:17 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)98 %02/05/19 18:17 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %02/05/19 18:17 17060-07-070-130 1
Toluene-d8 (S)103 %02/05/19 18:17 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride ND mg/L 02/02/19 21:13 16984-48-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 10 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456399
EPA 8260B
EPA 8260B
8260 MSV Low Level
Associated Lab Samples:92416093001, 92416093002, 92416093003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2490025
Associated Lab Samples:92416093001, 92416093002, 92416093003
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09
1,1,1-Trichloroethane ug/L ND 1.0 02/05/19 13:09
1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09
1,1,2-Trichloroethane ug/L ND 1.0 02/05/19 13:09
1,1-Dichloroethane ug/L ND 1.0 02/05/19 13:09
1,1-Dichloroethene ug/L ND 1.0 02/05/19 13:09
1,1-Dichloropropene ug/L ND 1.0 02/05/19 13:09
1,2,3-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2,3-Trichloropropane ug/L ND 1.0 02/05/19 13:09
1,2,4-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2-Dibromo-3-chloropropane ug/L ND 2.0 02/05/19 13:09
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/05/19 13:09
1,2-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2-Dichloroethane ug/L ND 1.0 02/05/19 13:09
1,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09
1,3-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,3-Dichloropropane ug/L ND 1.0 02/05/19 13:09
1,4-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
2,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09
2-Butanone (MEK)ug/L ND 5.0 02/05/19 13:09
2-Chlorotoluene ug/L ND 1.0 02/05/19 13:09
2-Hexanone ug/L ND 5.0 02/05/19 13:09
4-Chlorotoluene ug/L ND 1.0 02/05/19 13:09
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/05/19 13:09
Acetone ug/L ND 25.0 02/05/19 13:09
Benzene ug/L ND 1.0 02/05/19 13:09
Bromobenzene ug/L ND 1.0 02/05/19 13:09
Bromochloromethane ug/L ND 1.0 02/05/19 13:09
Bromodichloromethane ug/L ND 1.0 02/05/19 13:09
Bromoform ug/L ND 1.0 02/05/19 13:09
Bromomethane ug/L ND 2.0 02/05/19 13:09
Carbon tetrachloride ug/L ND 1.0 02/05/19 13:09
Chlorobenzene ug/L ND 1.0 02/05/19 13:09
Chloroethane ug/L ND 1.0 02/05/19 13:09
Chloroform ug/L ND 5.0 02/05/19 13:09
Chloromethane ug/L ND 1.0 02/05/19 13:09
cis-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09
cis-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09
Dibromochloromethane ug/L ND 1.0 02/05/19 13:09
Dibromomethane ug/L ND 1.0 02/05/19 13:09
Dichlorodifluoromethane ug/L ND 1.0 02/05/19 13:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 11 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2490025
Associated Lab Samples:92416093001, 92416093002, 92416093003
Matrix:Water
Analyzed
Diisopropyl ether ug/L ND 1.0 02/05/19 13:09
Ethylbenzene ug/L ND 1.0 02/05/19 13:09
Hexachloro-1,3-butadiene ug/L ND 1.0 02/05/19 13:09
m&p-Xylene ug/L ND 2.0 02/05/19 13:09
Methyl-tert-butyl ether ug/L ND 1.0 02/05/19 13:09
Methylene Chloride ug/L ND 5.0 02/05/19 13:09
Naphthalene ug/L ND 1.0 02/05/19 13:09
o-Xylene ug/L ND 1.0 02/05/19 13:09
p-Isopropyltoluene ug/L ND 1.0 02/05/19 13:09
Styrene ug/L ND 1.0 02/05/19 13:09
Tetrachloroethene ug/L ND 1.0 02/05/19 13:09
Toluene ug/L ND 1.0 02/05/19 13:09
trans-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09
trans-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09
Trichloroethene ug/L ND 1.0 02/05/19 13:09
Trichlorofluoromethane ug/L ND 1.0 02/05/19 13:09
Vinyl acetate ug/L ND 2.0 02/05/19 13:09
Vinyl chloride ug/L ND 1.0 02/05/19 13:09
Xylene (Total)ug/L ND 1.0 02/05/19 13:09
1,2-Dichloroethane-d4 (S)%95 70-130 02/05/19 13:09
4-Bromofluorobenzene (S)%99 70-130 02/05/19 13:09
Toluene-d8 (S)%100 70-130 02/05/19 13:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2490026LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.550 105 70-130
1,1,1-Trichloroethane ug/L 49.450 99 70-130
1,1,2,2-Tetrachloroethane ug/L 51.150 102 70-130
1,1,2-Trichloroethane ug/L 51.050 102 70-130
1,1-Dichloroethane ug/L 48.650 97 70-130
1,1-Dichloroethene ug/L 50.850 102 70-130
1,1-Dichloropropene ug/L 47.850 96 70-130
1,2,3-Trichlorobenzene ug/L 52.750 105 70-130
1,2,3-Trichloropropane ug/L 49.550 99 70-130
1,2,4-Trichlorobenzene ug/L 51.850 104 70-130
1,2-Dibromo-3-chloropropane ug/L 47.650 95 70-130
1,2-Dibromoethane (EDB)ug/L 52.750 105 70-130
1,2-Dichlorobenzene ug/L 48.750 97 70-130
1,2-Dichloroethane ug/L 43.950 88 70-130
1,2-Dichloropropane ug/L 48.850 98 70-130
1,3-Dichlorobenzene ug/L 47.950 96 70-130
1,3-Dichloropropane ug/L 51.850 104 70-131
1,4-Dichlorobenzene ug/L 47.750 95 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 12 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2490026LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 50.150 100 69-130
2-Butanone (MEK)ug/L 105100 105 64-135
2-Chlorotoluene ug/L 47.950 96 70-130
2-Hexanone ug/L 103100 103 66-135
4-Chlorotoluene ug/L 47.450 95 70-130
4-Methyl-2-pentanone (MIBK)ug/L 98.7100 99 70-130
Acetone ug/L 93.0100 93 61-157
Benzene ug/L 49.550 99 70-130
Bromobenzene ug/L 48.350 97 70-130
Bromochloromethane ug/L 49.850 100 70-130
Bromodichloromethane ug/L 49.150 98 70-130
Bromoform ug/L 50.550 101 70-130
Bromomethane ug/L 43.050 86 38-130
Carbon tetrachloride ug/L 48.150 96 70-130
Chlorobenzene ug/L 49.050 98 70-130
Chloroethane ug/L 45.050 90 37-142
Chloroform ug/L 45.450 91 70-130
Chloromethane ug/L 45.950 92 48-130
cis-1,2-Dichloroethene ug/L 47.450 95 70-130
cis-1,3-Dichloropropene ug/L 51.850 104 70-130
Dibromochloromethane ug/L 47.250 94 70-130
Dibromomethane ug/L 49.950 100 70-130
Dichlorodifluoromethane ug/L 48.850 98 53-134
Diisopropyl ether ug/L 48.950 98 70-135
Ethylbenzene ug/L 49.050 98 70-130
Hexachloro-1,3-butadiene ug/L 51.050 102 68-132
m&p-Xylene ug/L 98.5100 98 70-130
Methyl-tert-butyl ether ug/L 51.250 102 70-130
Methylene Chloride ug/L 45.250 90 67-132
Naphthalene ug/L 50.450 101 70-130
o-Xylene ug/L 50.750 101 70-130
p-Isopropyltoluene ug/L 48.950 98 70-130
Styrene ug/L 51.650 103 70-130
Tetrachloroethene ug/L 52.250 104 69-130
Toluene ug/L 46.450 93 70-130
trans-1,2-Dichloroethene ug/L 48.150 96 70-130
trans-1,3-Dichloropropene ug/L 51.450 103 70-130
Trichloroethene ug/L 50.950 102 70-130
Trichlorofluoromethane ug/L 46.350 93 63-130
Vinyl acetate ug/L 106100 106 55-143
Vinyl chloride ug/L 49.350 99 70-131
Xylene (Total)ug/L 149150 99 70-130
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 13 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92415883006
2490028
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 500 106 73-134105 1500ND530527
1,1,1-Trichloroethane ug/L 500 104 82-143107 2500ND522534
1,1,2,2-Tetrachloroethane ug/L 500 101 70-136103 2500ND503515
1,1,2-Trichloroethane ug/L 500 102 70-135106 4500ND511532
1,1-Dichloroethane ug/L 500 101 70-139102 2500ND503511
1,1-Dichloroethene ug/L 500 105 70-154108 2500ND526538
1,1-Dichloropropene ug/L 500 100 70-149101 2500ND498506
1,2,3-Trichlorobenzene ug/L 500 119 70-135110 8500ND597550
1,2,3-Trichloropropane ug/L 500 103 71-13798 5500ND515491
1,2,4-Trichlorobenzene ug/L 500 114 73-140108 6500ND572540
1,2-Dibromo-3-chloropropane ug/L 500 101 65-134101 0500ND504505
1,2-Dibromoethane (EDB)ug/L 500 104 70-137106 2500ND520530
1,2-Dichlorobenzene ug/L 500 105 70-133102 3500ND526508
1,2-Dichloroethane ug/L 500 89 70-13796 7500ND446479
1,2-Dichloropropane ug/L 500 102 70-140102 1500ND508512
1,3-Dichlorobenzene ug/L 500 104 70-135103 1500ND519514
1,3-Dichloropropane ug/L 500 106 70-143106 0500ND530529
1,4-Dichlorobenzene ug/L 500 103 70-133100 3500ND514501
2,2-Dichloropropane ug/L 500 80 61-14879 1500ND399396
2-Butanone (MEK)ug/L 1000 99 60-139104 51000ND9901040
2-Chlorotoluene ug/L 500 104 70-144104 0500ND520519
2-Hexanone ug/L 1000 99 65-138101 21000ND9871010
4-Chlorotoluene ug/L 500 104 70-137102 1500ND518512
4-Methyl-2-pentanone (MIBK)ug/L 1000 94 65-13597 31000ND943969
Acetone ug/L 1000 94 60-14895 11000ND939950
Benzene ug/L 500 104 70-151105 1500ND518523
Bromobenzene ug/L 500 104 70-136104 0500ND519521
Bromochloromethane ug/L 500 108 70-141109 1500ND538544
Bromodichloromethane ug/L 500 98 70-138100 1500ND491499
Bromoform ug/L 500 93 63-13096 3500ND463478
Bromomethane ug/L 500 99 15-15295 4500ND493476
Carbon tetrachloride ug/L 500 101 70-143103 2500ND505514
Chlorobenzene ug/L 500 103 70-138104 1500ND514519
Chloroethane ug/L 500 108 52-163108 0500ND540541
Chloroform ug/L 500 93 70-13995 2500ND482493
Chloromethane ug/L 500 101 41-139100 1500ND505499
cis-1,2-Dichloroethene ug/L 500 101 70-141104 35008.6J 516 529
cis-1,3-Dichloropropene ug/L 500 98 70-13799 1500ND488494
Dibromochloromethane ug/L 500 98 70-13497 1500ND489485
Dibromomethane ug/L 500 102 70-138105 3500ND508523
Dichlorodifluoromethane ug/L 500 103 47-155104 2500ND513521
Diisopropyl ether ug/L 500 97 63-14499 2500ND485493
Ethylbenzene ug/L 500 103 66-153104 0500ND517520
Hexachloro-1,3-butadiene ug/L 500 120 65-149111 8500ND602557
m&p-Xylene ug/L 1000 104 69-152104 01000ND10401040
Methyl-tert-butyl ether ug/L 500 100 54-156101 0500ND501503
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 14 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92415883006
2490028
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Methylene Chloride ug/L 500 93 42-15993 0500ND498498
Naphthalene ug/L 500 112 61-148105 7500ND559523
o-Xylene ug/L 500 108 70-148107 1500ND539535
p-Isopropyltoluene ug/L 500 108 70-146106 2500ND542530
Styrene ug/L 500 104 70-135103 2500ND521513
Tetrachloroethene ug/L E50013559-143547 48500262033005360
Toluene ug/L 500 98 59-14899 2500ND488497
trans-1,2-Dichloroethene ug/L 500 103 70-146105 3500ND513526
trans-1,3-Dichloropropene ug/L 500 95 70-13598 3500ND476489
Trichloroethene ug/L 500 107 70-147114 650011.8J 548 580
Trichlorofluoromethane ug/L 500 101 70-148101 0500ND503503
Vinyl acetate ug/L 1000 99 49-15196 31000ND990962
Vinyl chloride ug/L 500 109 70-156107 2500ND544534
Xylene (Total)ug/L 1500 105 63-158105 01500ND15801580
1,2-Dichloroethane-d4 (S)%95 70-13094
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%97 70-13096
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Page 15 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456010
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Associated Lab Samples:92416093001, 92416093002, 92416093003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2488458
Associated Lab Samples:92416093001, 92416093002, 92416093003
Matrix:Water
Analyzed
Fluoride mg/L ND 0.10 02/02/19 12:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2488459LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoride mg/L 2.52.5 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488460MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416071001
2488461
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 103 90-110104 12.5ND 2.6 2.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488462MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416071011
2488463
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 100 90-110100 12.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Page 16 of 26
#=ARR#
ANALYTICAL RESULTS - RADIOCHEMISTRY
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-1 Lab ID:92416093001 Collected:01/30/19 14:15 Received:02/01/19 10:00 Matrix:Water
Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod
PWS:Site ID:Sample Type:
Total Uranium 0.138 ± 0.009 (0.262)
C:NA T:NA ug/L 02/13/19 13:57 7440-61-1ASTM D5174-97
Uranium-234 0.094 ± 0.056 (0.066)
C:NA T:95%pCi/L 02/12/19 14:24 13966-29-5 N2HSL-300
Uranium-235 0.043 ± 0.040 (0.054)
C:NA T:95%pCi/L 02/12/19 14:24 15117-96-1 N2HSL-300
Uranium-238 0.038 ± 0.029 (0.015)
C:NA T:95%
pCi/L 02/12/19 14:24 N2HSL-300
REPORT OF LABORATORY ANALYSIS
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Page 17 of 26
#=ARR#
ANALYTICAL RESULTS - RADIOCHEMISTRY
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-2 Lab ID:92416093002 Collected:01/30/19 14:30 Received:02/01/19 10:00 Matrix:Water
Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod
PWS:Site ID:Sample Type:
Total Uranium 3.88 ± 0.150 (0.262)
C:NA T:NA ug/L 02/13/19 13:59 7440-61-1ASTM D5174-97
Uranium-234 1.65 ± 0.297 (0.041)
C:NA T:93%pCi/L 02/12/19 14:20 13966-29-5 N2HSL-300
Uranium-235 0.109 ± 0.057 (0.020)
C:NA T:93%pCi/L 02/12/19 14:20 15117-96-1 N2HSL-300
Uranium-238 1.53 ± 0.279 (0.041)
C:NA T:93%
pCi/L 02/12/19 14:20 N2HSL-300
REPORT OF LABORATORY ANALYSIS
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Page 18 of 26
#=ARR#
ANALYTICAL RESULTS - RADIOCHEMISTRY
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Sample:TMW-3 Lab ID:92416093003 Collected:01/30/19 14:45 Received:02/01/19 10:00 Matrix:Water
Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod
PWS:Site ID:Sample Type:
Total Uranium 7.11 ± 0.280 (0.262)
C:NA T:NA ug/L 02/13/19 14:02 7440-61-1ASTM D5174-97
Uranium-234 3.31 ± 0.619 (0.139)
C:NA T:79%pCi/L 02/12/19 14:20 13966-29-5 N2HSL-300
Uranium-235 0.252 ± 0.148 (0.157)
C:NA T:79%pCi/L 02/12/19 14:20 15117-96-1 N2HSL-300
Uranium-238 3.22 ± 0.603 (0.095)
C:NA T:79%
pCi/L 02/12/19 14:20 N2HSL-300
REPORT OF LABORATORY ANALYSIS
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Page 19 of 26
#=QCR#
QUALITY CONTROL - RADIOCHEMISTRY
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329379
ASTM D5174-97
ASTM D5174-97
D5174.97 Total Uranium KPA
Associated Lab Samples:92416093001, 92416093002, 92416093003
Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers
METHOD BLANK:1602577
Associated Lab Samples:92416093001, 92416093002, 92416093003
Matrix:Water
Analyzed
Total Uranium ug/L 02/13/19 13:180.085 ± 0.006 (0.262) C:NA T:NA
REPORT OF LABORATORY ANALYSIS
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Page 20 of 26
#=QCR#
QUALITY CONTROL - RADIOCHEMISTRY
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329227
HSL-300
HSL-300
HSL300(AS) Actinides
Associated Lab Samples:92416093001, 92416093002, 92416093003
Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers
METHOD BLANK:1601815
Associated Lab Samples:92416093001, 92416093002, 92416093003
Matrix:Water
Analyzed
Uranium-234 pCi/L N202/12/19 14:200.072 ± 0.047 (0.054) C:NA T:87%
Uranium-235 pCi/L N202/12/19 14:200.031 ± 0.037 (0.056) C:NA T:87%
Uranium-238 pCi/L N202/12/19 14:200.012 ± 0.040 (0.077) C:NA T:87%
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 21 of 26
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Act - Activity
Unc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval).
Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval)
(MDC) - Minimum Detectable Concentration
Trac - Tracer Recovery (%)
Carr - Carrier Recovery (%)
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - GreensburgPASI-PA
ANALYTE QUALIFIERS
Analyte concentration exceeded the calibration range. The reported result is estimated.E
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Page 22 of 26
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92416093
Castle Hayne Sand Mine
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92416093001 456399TMW-1 EPA 8260B
92416093002 456399TMW-2 EPA 8260B
92416093003 456399TMW-3 EPA 8260B
92416093001 329379TMW-1 ASTM D5174-97
92416093002 329379TMW-2 ASTM D5174-97
92416093003 329379TMW-3 ASTM D5174-97
92416093001 329227TMW-1 HSL-300
92416093002 329227TMW-2 HSL-300
92416093003 329227TMW-3 HSL-300
92416093001 456010TMW-1 EPA 300.0 Rev 2.1 1993
92416093002 456010TMW-2 EPA 300.0 Rev 2.1 1993
92416093003 456010TMW-3 EPA 300.0 Rev 2.1 1993
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 23 of 26
Page 24 of 26
Page 25 of 26
Page 26 of 26
#=CL#
February 13, 2019
LIMS USE: FR - SARAH KORDON
LIMS OBJECT ID: 92416096
92416096
Project:
Pace Project No.:
RE:
Sarah Kordon
ECS Southeast
9001 Glenwood Ave
Raleigh, NC 27617
Castle Hayne Sand Mine II
Dear Sarah Kordon:
Enclosed are the analytical results for sample(s) received by the laboratory on February 01, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
taylor.ezell@pacelabs.com
Project Manager
(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 1 of 20
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Pennsylvania Certification IDs
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Guam Certification
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PA014572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TNI Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/TNI Certification #: PA200002-010
Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
Tennessee Certification #: 02867
Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
West Virginia DEP Certification #: 143
West Virginia DHHR Certification #: 9964C
Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 2 of 20
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92416096001 TMW-4 EPA 8260B 63 PASI-CSAS
ASTM D5174-97 1 PASI-PARMK
HSL-300 3 PASI-PALAL
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 3 of 20
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92416096001 TMW-4
Total Uranium 4.97 ±
0.194
(0.262)
C:NA T:NA
ug/L 02/13/19 14:06ASTM D5174-97
Uranium-234 1.91 ±
0.399
(0.137)
C:NA T:90%
pCi/L 02/12/19 14:20 N2HSL-300
Uranium-235 0.177 ±
0.104
(0.040)
C:NA T:90%
pCi/L 02/12/19 14:20 N2HSL-300
Uranium-238 1.77 ±
0.377(0.123)
C:NA T:90%
pCi/L 02/12/19 14:20 N2HSL-300
Fluoride 0.36 mg/L 02/02/19 21:450.10EPA 300.0 Rev 2.1 1993
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 4 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Sample:TMW-4 Lab ID:92416096001 Collected:01/30/19 12:00 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Acetone ND ug/L 02/05/19 18:51 67-64-125.0 1
Benzene ND ug/L 02/05/19 18:51 71-43-21.0 1
Bromobenzene ND ug/L 02/05/19 18:51 108-86-11.0 1
Bromochloromethane ND ug/L 02/05/19 18:51 74-97-51.0 1
Bromodichloromethane ND ug/L 02/05/19 18:51 75-27-41.0 1
Bromoform ND ug/L 02/05/19 18:51 75-25-21.0 1
Bromomethane ND ug/L 02/05/19 18:51 74-83-92.0 1
2-Butanone (MEK)ND ug/L 02/05/19 18:51 78-93-35.0 1
Carbon tetrachloride ND ug/L 02/05/19 18:51 56-23-51.0 1
Chlorobenzene ND ug/L 02/05/19 18:51 108-90-71.0 1
Chloroethane ND ug/L 02/05/19 18:51 75-00-31.0 1
Chloroform ND ug/L 02/05/19 18:51 67-66-35.0 1
Chloromethane ND ug/L 02/05/19 18:51 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/05/19 18:51 95-49-81.0 1
4-Chlorotoluene ND ug/L 02/05/19 18:51 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 18:51 96-12-82.0 1
Dibromochloromethane ND ug/L 02/05/19 18:51 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 02/05/19 18:51 106-93-41.0 1
Dibromomethane ND ug/L 02/05/19 18:51 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 02/05/19 18:51 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 02/05/19 18:51 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 02/05/19 18:51 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 02/05/19 18:51 75-71-81.0 1
1,1-Dichloroethane ND ug/L 02/05/19 18:51 75-34-31.0 1
1,2-Dichloroethane ND ug/L 02/05/19 18:51 107-06-21.0 1
1,1-Dichloroethene ND ug/L 02/05/19 18:51 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 02/05/19 18:51 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 02/05/19 18:51 156-60-51.0 1
1,2-Dichloropropane ND ug/L 02/05/19 18:51 78-87-51.0 1
1,3-Dichloropropane ND ug/L 02/05/19 18:51 142-28-91.0 1
2,2-Dichloropropane ND ug/L 02/05/19 18:51 594-20-71.0 1
1,1-Dichloropropene ND ug/L 02/05/19 18:51 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 02/05/19 18:51 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 02/05/19 18:51 10061-02-61.0 1
Diisopropyl ether ND ug/L 02/05/19 18:51 108-20-31.0 1
Ethylbenzene ND ug/L 02/05/19 18:51 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 02/05/19 18:51 87-68-31.0 1
2-Hexanone ND ug/L 02/05/19 18:51 591-78-65.0 1
p-Isopropyltoluene ND ug/L 02/05/19 18:51 99-87-61.0 1
Methylene Chloride ND ug/L 02/05/19 18:51 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 18:51 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 02/05/19 18:51 1634-04-41.0 1
Naphthalene ND ug/L 02/05/19 18:51 91-20-31.0 1
Styrene ND ug/L 02/05/19 18:51 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 18:51 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 18:51 79-34-51.0 1
Tetrachloroethene ND ug/L 02/05/19 18:51 127-18-41.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Page 5 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Sample:TMW-4 Lab ID:92416096001 Collected:01/30/19 12:00 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Toluene ND ug/L 02/05/19 18:51 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 02/05/19 18:51 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 02/05/19 18:51 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 02/05/19 18:51 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 02/05/19 18:51 79-00-51.0 1
Trichloroethene ND ug/L 02/05/19 18:51 79-01-61.0 1
Trichlorofluoromethane ND ug/L 02/05/19 18:51 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/05/19 18:51 96-18-41.0 1
Vinyl acetate ND ug/L 02/05/19 18:51 108-05-42.0 1
Vinyl chloride ND ug/L 02/05/19 18:51 75-01-41.0 1
Xylene (Total)ND ug/L 02/05/19 18:51 1330-20-71.0 1
m&p-Xylene ND ug/L 02/05/19 18:51 179601-23-12.0 1
o-Xylene ND ug/L 02/05/19 18:51 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)99 %02/05/19 18:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %02/05/19 18:51 17060-07-070-130 1
Toluene-d8 (S)101 %02/05/19 18:51 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.36 mg/L 02/02/19 21:45 16984-48-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Page 6 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456399
EPA 8260B
EPA 8260B
8260 MSV Low Level
Associated Lab Samples:92416096001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2490025
Associated Lab Samples:92416096001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09
1,1,1-Trichloroethane ug/L ND 1.0 02/05/19 13:09
1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09
1,1,2-Trichloroethane ug/L ND 1.0 02/05/19 13:09
1,1-Dichloroethane ug/L ND 1.0 02/05/19 13:09
1,1-Dichloroethene ug/L ND 1.0 02/05/19 13:09
1,1-Dichloropropene ug/L ND 1.0 02/05/19 13:09
1,2,3-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2,3-Trichloropropane ug/L ND 1.0 02/05/19 13:09
1,2,4-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2-Dibromo-3-chloropropane ug/L ND 2.0 02/05/19 13:09
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/05/19 13:09
1,2-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2-Dichloroethane ug/L ND 1.0 02/05/19 13:09
1,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09
1,3-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,3-Dichloropropane ug/L ND 1.0 02/05/19 13:09
1,4-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
2,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09
2-Butanone (MEK)ug/L ND 5.0 02/05/19 13:09
2-Chlorotoluene ug/L ND 1.0 02/05/19 13:09
2-Hexanone ug/L ND 5.0 02/05/19 13:09
4-Chlorotoluene ug/L ND 1.0 02/05/19 13:09
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/05/19 13:09
Acetone ug/L ND 25.0 02/05/19 13:09
Benzene ug/L ND 1.0 02/05/19 13:09
Bromobenzene ug/L ND 1.0 02/05/19 13:09
Bromochloromethane ug/L ND 1.0 02/05/19 13:09
Bromodichloromethane ug/L ND 1.0 02/05/19 13:09
Bromoform ug/L ND 1.0 02/05/19 13:09
Bromomethane ug/L ND 2.0 02/05/19 13:09
Carbon tetrachloride ug/L ND 1.0 02/05/19 13:09
Chlorobenzene ug/L ND 1.0 02/05/19 13:09
Chloroethane ug/L ND 1.0 02/05/19 13:09
Chloroform ug/L ND 5.0 02/05/19 13:09
Chloromethane ug/L ND 1.0 02/05/19 13:09
cis-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09
cis-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09
Dibromochloromethane ug/L ND 1.0 02/05/19 13:09
Dibromomethane ug/L ND 1.0 02/05/19 13:09
Dichlorodifluoromethane ug/L ND 1.0 02/05/19 13:09
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Huntersville, NC 28078
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Page 7 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2490025
Associated Lab Samples:92416096001
Matrix:Water
Analyzed
Diisopropyl ether ug/L ND 1.0 02/05/19 13:09
Ethylbenzene ug/L ND 1.0 02/05/19 13:09
Hexachloro-1,3-butadiene ug/L ND 1.0 02/05/19 13:09
m&p-Xylene ug/L ND 2.0 02/05/19 13:09
Methyl-tert-butyl ether ug/L ND 1.0 02/05/19 13:09
Methylene Chloride ug/L ND 5.0 02/05/19 13:09
Naphthalene ug/L ND 1.0 02/05/19 13:09
o-Xylene ug/L ND 1.0 02/05/19 13:09
p-Isopropyltoluene ug/L ND 1.0 02/05/19 13:09
Styrene ug/L ND 1.0 02/05/19 13:09
Tetrachloroethene ug/L ND 1.0 02/05/19 13:09
Toluene ug/L ND 1.0 02/05/19 13:09
trans-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09
trans-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09
Trichloroethene ug/L ND 1.0 02/05/19 13:09
Trichlorofluoromethane ug/L ND 1.0 02/05/19 13:09
Vinyl acetate ug/L ND 2.0 02/05/19 13:09
Vinyl chloride ug/L ND 1.0 02/05/19 13:09
Xylene (Total)ug/L ND 1.0 02/05/19 13:09
1,2-Dichloroethane-d4 (S)%95 70-130 02/05/19 13:09
4-Bromofluorobenzene (S)%99 70-130 02/05/19 13:09
Toluene-d8 (S)%100 70-130 02/05/19 13:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2490026LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.550 105 70-130
1,1,1-Trichloroethane ug/L 49.450 99 70-130
1,1,2,2-Tetrachloroethane ug/L 51.150 102 70-130
1,1,2-Trichloroethane ug/L 51.050 102 70-130
1,1-Dichloroethane ug/L 48.650 97 70-130
1,1-Dichloroethene ug/L 50.850 102 70-130
1,1-Dichloropropene ug/L 47.850 96 70-130
1,2,3-Trichlorobenzene ug/L 52.750 105 70-130
1,2,3-Trichloropropane ug/L 49.550 99 70-130
1,2,4-Trichlorobenzene ug/L 51.850 104 70-130
1,2-Dibromo-3-chloropropane ug/L 47.650 95 70-130
1,2-Dibromoethane (EDB)ug/L 52.750 105 70-130
1,2-Dichlorobenzene ug/L 48.750 97 70-130
1,2-Dichloroethane ug/L 43.950 88 70-130
1,2-Dichloropropane ug/L 48.850 98 70-130
1,3-Dichlorobenzene ug/L 47.950 96 70-130
1,3-Dichloropropane ug/L 51.850 104 70-131
1,4-Dichlorobenzene ug/L 47.750 95 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Huntersville, NC 28078
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Page 8 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2490026LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 50.150 100 69-130
2-Butanone (MEK)ug/L 105100 105 64-135
2-Chlorotoluene ug/L 47.950 96 70-130
2-Hexanone ug/L 103100 103 66-135
4-Chlorotoluene ug/L 47.450 95 70-130
4-Methyl-2-pentanone (MIBK)ug/L 98.7100 99 70-130
Acetone ug/L 93.0100 93 61-157
Benzene ug/L 49.550 99 70-130
Bromobenzene ug/L 48.350 97 70-130
Bromochloromethane ug/L 49.850 100 70-130
Bromodichloromethane ug/L 49.150 98 70-130
Bromoform ug/L 50.550 101 70-130
Bromomethane ug/L 43.050 86 38-130
Carbon tetrachloride ug/L 48.150 96 70-130
Chlorobenzene ug/L 49.050 98 70-130
Chloroethane ug/L 45.050 90 37-142
Chloroform ug/L 45.450 91 70-130
Chloromethane ug/L 45.950 92 48-130
cis-1,2-Dichloroethene ug/L 47.450 95 70-130
cis-1,3-Dichloropropene ug/L 51.850 104 70-130
Dibromochloromethane ug/L 47.250 94 70-130
Dibromomethane ug/L 49.950 100 70-130
Dichlorodifluoromethane ug/L 48.850 98 53-134
Diisopropyl ether ug/L 48.950 98 70-135
Ethylbenzene ug/L 49.050 98 70-130
Hexachloro-1,3-butadiene ug/L 51.050 102 68-132
m&p-Xylene ug/L 98.5100 98 70-130
Methyl-tert-butyl ether ug/L 51.250 102 70-130
Methylene Chloride ug/L 45.250 90 67-132
Naphthalene ug/L 50.450 101 70-130
o-Xylene ug/L 50.750 101 70-130
p-Isopropyltoluene ug/L 48.950 98 70-130
Styrene ug/L 51.650 103 70-130
Tetrachloroethene ug/L 52.250 104 69-130
Toluene ug/L 46.450 93 70-130
trans-1,2-Dichloroethene ug/L 48.150 96 70-130
trans-1,3-Dichloropropene ug/L 51.450 103 70-130
Trichloroethene ug/L 50.950 102 70-130
Trichlorofluoromethane ug/L 46.350 93 63-130
Vinyl acetate ug/L 106100 106 55-143
Vinyl chloride ug/L 49.350 99 70-131
Xylene (Total)ug/L 149150 99 70-130
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 9 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92415883006
2490028
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 500 106 73-134105 1500ND530527
1,1,1-Trichloroethane ug/L 500 104 82-143107 2500ND522534
1,1,2,2-Tetrachloroethane ug/L 500 101 70-136103 2500ND503515
1,1,2-Trichloroethane ug/L 500 102 70-135106 4500ND511532
1,1-Dichloroethane ug/L 500 101 70-139102 2500ND503511
1,1-Dichloroethene ug/L 500 105 70-154108 2500ND526538
1,1-Dichloropropene ug/L 500 100 70-149101 2500ND498506
1,2,3-Trichlorobenzene ug/L 500 119 70-135110 8500ND597550
1,2,3-Trichloropropane ug/L 500 103 71-13798 5500ND515491
1,2,4-Trichlorobenzene ug/L 500 114 73-140108 6500ND572540
1,2-Dibromo-3-chloropropane ug/L 500 101 65-134101 0500ND504505
1,2-Dibromoethane (EDB)ug/L 500 104 70-137106 2500ND520530
1,2-Dichlorobenzene ug/L 500 105 70-133102 3500ND526508
1,2-Dichloroethane ug/L 500 89 70-13796 7500ND446479
1,2-Dichloropropane ug/L 500 102 70-140102 1500ND508512
1,3-Dichlorobenzene ug/L 500 104 70-135103 1500ND519514
1,3-Dichloropropane ug/L 500 106 70-143106 0500ND530529
1,4-Dichlorobenzene ug/L 500 103 70-133100 3500ND514501
2,2-Dichloropropane ug/L 500 80 61-14879 1500ND399396
2-Butanone (MEK)ug/L 1000 99 60-139104 51000ND9901040
2-Chlorotoluene ug/L 500 104 70-144104 0500ND520519
2-Hexanone ug/L 1000 99 65-138101 21000ND9871010
4-Chlorotoluene ug/L 500 104 70-137102 1500ND518512
4-Methyl-2-pentanone (MIBK)ug/L 1000 94 65-13597 31000ND943969
Acetone ug/L 1000 94 60-14895 11000ND939950
Benzene ug/L 500 104 70-151105 1500ND518523
Bromobenzene ug/L 500 104 70-136104 0500ND519521
Bromochloromethane ug/L 500 108 70-141109 1500ND538544
Bromodichloromethane ug/L 500 98 70-138100 1500ND491499
Bromoform ug/L 500 93 63-13096 3500ND463478
Bromomethane ug/L 500 99 15-15295 4500ND493476
Carbon tetrachloride ug/L 500 101 70-143103 2500ND505514
Chlorobenzene ug/L 500 103 70-138104 1500ND514519
Chloroethane ug/L 500 108 52-163108 0500ND540541
Chloroform ug/L 500 93 70-13995 2500ND482493
Chloromethane ug/L 500 101 41-139100 1500ND505499
cis-1,2-Dichloroethene ug/L 500 101 70-141104 35008.6J 516 529
cis-1,3-Dichloropropene ug/L 500 98 70-13799 1500ND488494
Dibromochloromethane ug/L 500 98 70-13497 1500ND489485
Dibromomethane ug/L 500 102 70-138105 3500ND508523
Dichlorodifluoromethane ug/L 500 103 47-155104 2500ND513521
Diisopropyl ether ug/L 500 97 63-14499 2500ND485493
Ethylbenzene ug/L 500 103 66-153104 0500ND517520
Hexachloro-1,3-butadiene ug/L 500 120 65-149111 8500ND602557
m&p-Xylene ug/L 1000 104 69-152104 01000ND10401040
Methyl-tert-butyl ether ug/L 500 100 54-156101 0500ND501503
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
(704)875-9092
Page 10 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92415883006
2490028
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Methylene Chloride ug/L 500 93 42-15993 0500ND498498
Naphthalene ug/L 500 112 61-148105 7500ND559523
o-Xylene ug/L 500 108 70-148107 1500ND539535
p-Isopropyltoluene ug/L 500 108 70-146106 2500ND542530
Styrene ug/L 500 104 70-135103 2500ND521513
Tetrachloroethene ug/L E50013559-143547 48500262033005360
Toluene ug/L 500 98 59-14899 2500ND488497
trans-1,2-Dichloroethene ug/L 500 103 70-146105 3500ND513526
trans-1,3-Dichloropropene ug/L 500 95 70-13598 3500ND476489
Trichloroethene ug/L 500 107 70-147114 650011.8J 548 580
Trichlorofluoromethane ug/L 500 101 70-148101 0500ND503503
Vinyl acetate ug/L 1000 99 49-15196 31000ND990962
Vinyl chloride ug/L 500 109 70-156107 2500ND544534
Xylene (Total)ug/L 1500 105 63-158105 01500ND15801580
1,2-Dichloroethane-d4 (S)%95 70-13094
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%97 70-13096
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 11 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456010
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Associated Lab Samples:92416096001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2488458
Associated Lab Samples:92416096001
Matrix:Water
Analyzed
Fluoride mg/L ND 0.10 02/02/19 12:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2488459LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoride mg/L 2.52.5 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488460MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416071001
2488461
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 103 90-110104 12.5ND 2.6 2.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488462MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416071011
2488463
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 100 90-110100 12.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Huntersville, NC 28078
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Page 12 of 20
#=ARR#
ANALYTICAL RESULTS - RADIOCHEMISTRY
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Sample:TMW-4 Lab ID:92416096001 Collected:01/30/19 12:00 Received:02/01/19 10:00 Matrix:Water
Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod
PWS:Site ID:Sample Type:
Total Uranium 4.97 ± 0.194 (0.262)
C:NA T:NA ug/L 02/13/19 14:06 7440-61-1ASTM D5174-97
Uranium-234 1.91 ± 0.399 (0.137)
C:NA T:90%pCi/L 02/12/19 14:20 13966-29-5 N2HSL-300
Uranium-235 0.177 ± 0.104 (0.040)
C:NA T:90%pCi/L 02/12/19 14:20 15117-96-1 N2HSL-300
Uranium-238 1.77 ± 0.377 (0.123)
C:NA T:90%
pCi/L 02/12/19 14:20 N2HSL-300
REPORT OF LABORATORY ANALYSIS
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Page 13 of 20
#=QCR#
QUALITY CONTROL - RADIOCHEMISTRY
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329379
ASTM D5174-97
ASTM D5174-97
D5174.97 Total Uranium KPA
Associated Lab Samples:92416096001
Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers
METHOD BLANK:1602577
Associated Lab Samples:92416096001
Matrix:Water
Analyzed
Total Uranium ug/L 02/13/19 13:180.085 ± 0.006 (0.262) C:NA T:NA
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 14 of 20
#=QCR#
QUALITY CONTROL - RADIOCHEMISTRY
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329227
HSL-300
HSL-300
HSL300(AS) Actinides
Associated Lab Samples:92416096001
Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers
METHOD BLANK:1601815
Associated Lab Samples:92416096001
Matrix:Water
Analyzed
Uranium-234 pCi/L N202/12/19 14:200.072 ± 0.047 (0.054) C:NA T:87%
Uranium-235 pCi/L N202/12/19 14:200.031 ± 0.037 (0.056) C:NA T:87%
Uranium-238 pCi/L N202/12/19 14:200.012 ± 0.040 (0.077) C:NA T:87%
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 15 of 20
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Act - Activity
Unc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval).
Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval)
(MDC) - Minimum Detectable Concentration
Trac - Tracer Recovery (%)
Carr - Carrier Recovery (%)
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - GreensburgPASI-PA
ANALYTE QUALIFIERS
Analyte concentration exceeded the calibration range. The reported result is estimated.E
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 16 of 20
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92416096
Castle Hayne Sand Mine II
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92416096001 456399TMW-4 EPA 8260B
92416096001 329379TMW-4 ASTM D5174-97
92416096001 329227TMW-4 HSL-300
92416096001 456010TMW-4 EPA 300.0 Rev 2.1 1993
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 17 of 20
Page 18 of 20
Page 19 of 20
Page 20 of 20
#=CL#
February 13, 2019
LIMS USE: FR - SARAH KORDON
LIMS OBJECT ID: 92416095
92416095
Project:
Pace Project No.:
RE:
Sarah Kordon
ECS Southeast
9001 Glenwood Ave
Raleigh, NC 27617
Castle Hayne Sand Mine III
Dear Sarah Kordon:
Enclosed are the analytical results for sample(s) received by the laboratory on February 01, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
taylor.ezell@pacelabs.com
Project Manager
(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 1 of 20
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Pennsylvania Certification IDs
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Guam Certification
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PA014572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TNI Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/TNI Certification #: PA200002-010
Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
Tennessee Certification #: 02867
Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
West Virginia DEP Certification #: 143
West Virginia DHHR Certification #: 9964C
Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 2 of 20
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92416095001 TMW-5 EPA 8260B 63 PASI-CSAS
ASTM D5174-97 1 PASI-PARMK
HSL-300 3 PASI-PALAL
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 3 of 20
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92416095001 TMW-5
Total Uranium 3.55 ±
0.178
(0.262)
C:NA T:NA
ug/L 02/13/19 14:04ASTM D5174-97
Uranium-234 2.48 ±
0.498
(0.167)
C:NA T:84%
pCi/L 02/12/19 14:20 N2HSL-300
Uranium-235 0.199 ±
0.116
(0.045)
C:NA T:84%
pCi/L 02/12/19 14:20 N2HSL-300
Uranium-238 2.06 ±
0.432(0.118)
C:NA T:84%
pCi/L 02/12/19 14:20 N2HSL-300
Fluoride 0.39 mg/L 02/02/19 21:290.10EPA 300.0 Rev 2.1 1993
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 4 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Sample:TMW-5 Lab ID:92416095001 Collected:01/30/19 17:00 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Acetone ND ug/L 02/05/19 18:34 67-64-125.0 1
Benzene ND ug/L 02/05/19 18:34 71-43-21.0 1
Bromobenzene ND ug/L 02/05/19 18:34 108-86-11.0 1
Bromochloromethane ND ug/L 02/05/19 18:34 74-97-51.0 1
Bromodichloromethane ND ug/L 02/05/19 18:34 75-27-41.0 1
Bromoform ND ug/L 02/05/19 18:34 75-25-21.0 1
Bromomethane ND ug/L 02/05/19 18:34 74-83-92.0 1
2-Butanone (MEK)ND ug/L 02/05/19 18:34 78-93-35.0 1
Carbon tetrachloride ND ug/L 02/05/19 18:34 56-23-51.0 1
Chlorobenzene ND ug/L 02/05/19 18:34 108-90-71.0 1
Chloroethane ND ug/L 02/05/19 18:34 75-00-31.0 1
Chloroform ND ug/L 02/05/19 18:34 67-66-35.0 1
Chloromethane ND ug/L 02/05/19 18:34 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/05/19 18:34 95-49-81.0 1
4-Chlorotoluene ND ug/L 02/05/19 18:34 106-43-41.0 1
1,2-Dibromo-3-chloropropane ND ug/L 02/05/19 18:34 96-12-82.0 1
Dibromochloromethane ND ug/L 02/05/19 18:34 124-48-11.0 1
1,2-Dibromoethane (EDB)ND ug/L 02/05/19 18:34 106-93-41.0 1
Dibromomethane ND ug/L 02/05/19 18:34 74-95-31.0 1
1,2-Dichlorobenzene ND ug/L 02/05/19 18:34 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 02/05/19 18:34 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 02/05/19 18:34 106-46-71.0 1
Dichlorodifluoromethane ND ug/L 02/05/19 18:34 75-71-81.0 1
1,1-Dichloroethane ND ug/L 02/05/19 18:34 75-34-31.0 1
1,2-Dichloroethane ND ug/L 02/05/19 18:34 107-06-21.0 1
1,1-Dichloroethene ND ug/L 02/05/19 18:34 75-35-41.0 1
cis-1,2-Dichloroethene ND ug/L 02/05/19 18:34 156-59-21.0 1
trans-1,2-Dichloroethene ND ug/L 02/05/19 18:34 156-60-51.0 1
1,2-Dichloropropane ND ug/L 02/05/19 18:34 78-87-51.0 1
1,3-Dichloropropane ND ug/L 02/05/19 18:34 142-28-91.0 1
2,2-Dichloropropane ND ug/L 02/05/19 18:34 594-20-71.0 1
1,1-Dichloropropene ND ug/L 02/05/19 18:34 563-58-61.0 1
cis-1,3-Dichloropropene ND ug/L 02/05/19 18:34 10061-01-51.0 1
trans-1,3-Dichloropropene ND ug/L 02/05/19 18:34 10061-02-61.0 1
Diisopropyl ether ND ug/L 02/05/19 18:34 108-20-31.0 1
Ethylbenzene ND ug/L 02/05/19 18:34 100-41-41.0 1
Hexachloro-1,3-butadiene ND ug/L 02/05/19 18:34 87-68-31.0 1
2-Hexanone ND ug/L 02/05/19 18:34 591-78-65.0 1
p-Isopropyltoluene ND ug/L 02/05/19 18:34 99-87-61.0 1
Methylene Chloride ND ug/L 02/05/19 18:34 75-09-25.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/05/19 18:34 108-10-15.0 1
Methyl-tert-butyl ether ND ug/L 02/05/19 18:34 1634-04-41.0 1
Naphthalene ND ug/L 02/05/19 18:34 91-20-31.0 1
Styrene ND ug/L 02/05/19 18:34 100-42-51.0 1
1,1,1,2-Tetrachloroethane ND ug/L 02/05/19 18:34 630-20-61.0 1
1,1,2,2-Tetrachloroethane ND ug/L 02/05/19 18:34 79-34-51.0 1
Tetrachloroethene ND ug/L 02/05/19 18:34 127-18-41.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Page 5 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Sample:TMW-5 Lab ID:92416095001 Collected:01/30/19 17:00 Received:02/01/19 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8260B8260 MSV Low Level
Toluene ND ug/L 02/05/19 18:34 108-88-31.0 1
1,2,3-Trichlorobenzene ND ug/L 02/05/19 18:34 87-61-61.0 1
1,2,4-Trichlorobenzene ND ug/L 02/05/19 18:34 120-82-11.0 1
1,1,1-Trichloroethane ND ug/L 02/05/19 18:34 71-55-61.0 1
1,1,2-Trichloroethane ND ug/L 02/05/19 18:34 79-00-51.0 1
Trichloroethene ND ug/L 02/05/19 18:34 79-01-61.0 1
Trichlorofluoromethane ND ug/L 02/05/19 18:34 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/05/19 18:34 96-18-41.0 1
Vinyl acetate ND ug/L 02/05/19 18:34 108-05-42.0 1
Vinyl chloride ND ug/L 02/05/19 18:34 75-01-41.0 1
Xylene (Total)ND ug/L 02/05/19 18:34 1330-20-71.0 1
m&p-Xylene ND ug/L 02/05/19 18:34 179601-23-12.0 1
o-Xylene ND ug/L 02/05/19 18:34 95-47-61.0 1
Surrogates
4-Bromofluorobenzene (S)99 %02/05/19 18:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %02/05/19 18:34 17060-07-070-130 1
Toluene-d8 (S)99 %02/05/19 18:34 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.39 mg/L 02/02/19 21:29 16984-48-80.10 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456399
EPA 8260B
EPA 8260B
8260 MSV Low Level
Associated Lab Samples:92416095001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2490025
Associated Lab Samples:92416095001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09
1,1,1-Trichloroethane ug/L ND 1.0 02/05/19 13:09
1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/05/19 13:09
1,1,2-Trichloroethane ug/L ND 1.0 02/05/19 13:09
1,1-Dichloroethane ug/L ND 1.0 02/05/19 13:09
1,1-Dichloroethene ug/L ND 1.0 02/05/19 13:09
1,1-Dichloropropene ug/L ND 1.0 02/05/19 13:09
1,2,3-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2,3-Trichloropropane ug/L ND 1.0 02/05/19 13:09
1,2,4-Trichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2-Dibromo-3-chloropropane ug/L ND 2.0 02/05/19 13:09
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/05/19 13:09
1,2-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,2-Dichloroethane ug/L ND 1.0 02/05/19 13:09
1,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09
1,3-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
1,3-Dichloropropane ug/L ND 1.0 02/05/19 13:09
1,4-Dichlorobenzene ug/L ND 1.0 02/05/19 13:09
2,2-Dichloropropane ug/L ND 1.0 02/05/19 13:09
2-Butanone (MEK)ug/L ND 5.0 02/05/19 13:09
2-Chlorotoluene ug/L ND 1.0 02/05/19 13:09
2-Hexanone ug/L ND 5.0 02/05/19 13:09
4-Chlorotoluene ug/L ND 1.0 02/05/19 13:09
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/05/19 13:09
Acetone ug/L ND 25.0 02/05/19 13:09
Benzene ug/L ND 1.0 02/05/19 13:09
Bromobenzene ug/L ND 1.0 02/05/19 13:09
Bromochloromethane ug/L ND 1.0 02/05/19 13:09
Bromodichloromethane ug/L ND 1.0 02/05/19 13:09
Bromoform ug/L ND 1.0 02/05/19 13:09
Bromomethane ug/L ND 2.0 02/05/19 13:09
Carbon tetrachloride ug/L ND 1.0 02/05/19 13:09
Chlorobenzene ug/L ND 1.0 02/05/19 13:09
Chloroethane ug/L ND 1.0 02/05/19 13:09
Chloroform ug/L ND 5.0 02/05/19 13:09
Chloromethane ug/L ND 1.0 02/05/19 13:09
cis-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09
cis-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09
Dibromochloromethane ug/L ND 1.0 02/05/19 13:09
Dibromomethane ug/L ND 1.0 02/05/19 13:09
Dichlorodifluoromethane ug/L ND 1.0 02/05/19 13:09
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Huntersville, NC 28078
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Page 7 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2490025
Associated Lab Samples:92416095001
Matrix:Water
Analyzed
Diisopropyl ether ug/L ND 1.0 02/05/19 13:09
Ethylbenzene ug/L ND 1.0 02/05/19 13:09
Hexachloro-1,3-butadiene ug/L ND 1.0 02/05/19 13:09
m&p-Xylene ug/L ND 2.0 02/05/19 13:09
Methyl-tert-butyl ether ug/L ND 1.0 02/05/19 13:09
Methylene Chloride ug/L ND 5.0 02/05/19 13:09
Naphthalene ug/L ND 1.0 02/05/19 13:09
o-Xylene ug/L ND 1.0 02/05/19 13:09
p-Isopropyltoluene ug/L ND 1.0 02/05/19 13:09
Styrene ug/L ND 1.0 02/05/19 13:09
Tetrachloroethene ug/L ND 1.0 02/05/19 13:09
Toluene ug/L ND 1.0 02/05/19 13:09
trans-1,2-Dichloroethene ug/L ND 1.0 02/05/19 13:09
trans-1,3-Dichloropropene ug/L ND 1.0 02/05/19 13:09
Trichloroethene ug/L ND 1.0 02/05/19 13:09
Trichlorofluoromethane ug/L ND 1.0 02/05/19 13:09
Vinyl acetate ug/L ND 2.0 02/05/19 13:09
Vinyl chloride ug/L ND 1.0 02/05/19 13:09
Xylene (Total)ug/L ND 1.0 02/05/19 13:09
1,2-Dichloroethane-d4 (S)%95 70-130 02/05/19 13:09
4-Bromofluorobenzene (S)%99 70-130 02/05/19 13:09
Toluene-d8 (S)%100 70-130 02/05/19 13:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2490026LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.550 105 70-130
1,1,1-Trichloroethane ug/L 49.450 99 70-130
1,1,2,2-Tetrachloroethane ug/L 51.150 102 70-130
1,1,2-Trichloroethane ug/L 51.050 102 70-130
1,1-Dichloroethane ug/L 48.650 97 70-130
1,1-Dichloroethene ug/L 50.850 102 70-130
1,1-Dichloropropene ug/L 47.850 96 70-130
1,2,3-Trichlorobenzene ug/L 52.750 105 70-130
1,2,3-Trichloropropane ug/L 49.550 99 70-130
1,2,4-Trichlorobenzene ug/L 51.850 104 70-130
1,2-Dibromo-3-chloropropane ug/L 47.650 95 70-130
1,2-Dibromoethane (EDB)ug/L 52.750 105 70-130
1,2-Dichlorobenzene ug/L 48.750 97 70-130
1,2-Dichloroethane ug/L 43.950 88 70-130
1,2-Dichloropropane ug/L 48.850 98 70-130
1,3-Dichlorobenzene ug/L 47.950 96 70-130
1,3-Dichloropropane ug/L 51.850 104 70-131
1,4-Dichlorobenzene ug/L 47.750 95 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
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Huntersville, NC 28078
(704)875-9092
Page 8 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2490026LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 50.150 100 69-130
2-Butanone (MEK)ug/L 105100 105 64-135
2-Chlorotoluene ug/L 47.950 96 70-130
2-Hexanone ug/L 103100 103 66-135
4-Chlorotoluene ug/L 47.450 95 70-130
4-Methyl-2-pentanone (MIBK)ug/L 98.7100 99 70-130
Acetone ug/L 93.0100 93 61-157
Benzene ug/L 49.550 99 70-130
Bromobenzene ug/L 48.350 97 70-130
Bromochloromethane ug/L 49.850 100 70-130
Bromodichloromethane ug/L 49.150 98 70-130
Bromoform ug/L 50.550 101 70-130
Bromomethane ug/L 43.050 86 38-130
Carbon tetrachloride ug/L 48.150 96 70-130
Chlorobenzene ug/L 49.050 98 70-130
Chloroethane ug/L 45.050 90 37-142
Chloroform ug/L 45.450 91 70-130
Chloromethane ug/L 45.950 92 48-130
cis-1,2-Dichloroethene ug/L 47.450 95 70-130
cis-1,3-Dichloropropene ug/L 51.850 104 70-130
Dibromochloromethane ug/L 47.250 94 70-130
Dibromomethane ug/L 49.950 100 70-130
Dichlorodifluoromethane ug/L 48.850 98 53-134
Diisopropyl ether ug/L 48.950 98 70-135
Ethylbenzene ug/L 49.050 98 70-130
Hexachloro-1,3-butadiene ug/L 51.050 102 68-132
m&p-Xylene ug/L 98.5100 98 70-130
Methyl-tert-butyl ether ug/L 51.250 102 70-130
Methylene Chloride ug/L 45.250 90 67-132
Naphthalene ug/L 50.450 101 70-130
o-Xylene ug/L 50.750 101 70-130
p-Isopropyltoluene ug/L 48.950 98 70-130
Styrene ug/L 51.650 103 70-130
Tetrachloroethene ug/L 52.250 104 69-130
Toluene ug/L 46.450 93 70-130
trans-1,2-Dichloroethene ug/L 48.150 96 70-130
trans-1,3-Dichloropropene ug/L 51.450 103 70-130
Trichloroethene ug/L 50.950 102 70-130
Trichlorofluoromethane ug/L 46.350 93 63-130
Vinyl acetate ug/L 106100 106 55-143
Vinyl chloride ug/L 49.350 99 70-131
Xylene (Total)ug/L 149150 99 70-130
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 9 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92415883006
2490028
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 500 106 73-134105 1500ND530527
1,1,1-Trichloroethane ug/L 500 104 82-143107 2500ND522534
1,1,2,2-Tetrachloroethane ug/L 500 101 70-136103 2500ND503515
1,1,2-Trichloroethane ug/L 500 102 70-135106 4500ND511532
1,1-Dichloroethane ug/L 500 101 70-139102 2500ND503511
1,1-Dichloroethene ug/L 500 105 70-154108 2500ND526538
1,1-Dichloropropene ug/L 500 100 70-149101 2500ND498506
1,2,3-Trichlorobenzene ug/L 500 119 70-135110 8500ND597550
1,2,3-Trichloropropane ug/L 500 103 71-13798 5500ND515491
1,2,4-Trichlorobenzene ug/L 500 114 73-140108 6500ND572540
1,2-Dibromo-3-chloropropane ug/L 500 101 65-134101 0500ND504505
1,2-Dibromoethane (EDB)ug/L 500 104 70-137106 2500ND520530
1,2-Dichlorobenzene ug/L 500 105 70-133102 3500ND526508
1,2-Dichloroethane ug/L 500 89 70-13796 7500ND446479
1,2-Dichloropropane ug/L 500 102 70-140102 1500ND508512
1,3-Dichlorobenzene ug/L 500 104 70-135103 1500ND519514
1,3-Dichloropropane ug/L 500 106 70-143106 0500ND530529
1,4-Dichlorobenzene ug/L 500 103 70-133100 3500ND514501
2,2-Dichloropropane ug/L 500 80 61-14879 1500ND399396
2-Butanone (MEK)ug/L 1000 99 60-139104 51000ND9901040
2-Chlorotoluene ug/L 500 104 70-144104 0500ND520519
2-Hexanone ug/L 1000 99 65-138101 21000ND9871010
4-Chlorotoluene ug/L 500 104 70-137102 1500ND518512
4-Methyl-2-pentanone (MIBK)ug/L 1000 94 65-13597 31000ND943969
Acetone ug/L 1000 94 60-14895 11000ND939950
Benzene ug/L 500 104 70-151105 1500ND518523
Bromobenzene ug/L 500 104 70-136104 0500ND519521
Bromochloromethane ug/L 500 108 70-141109 1500ND538544
Bromodichloromethane ug/L 500 98 70-138100 1500ND491499
Bromoform ug/L 500 93 63-13096 3500ND463478
Bromomethane ug/L 500 99 15-15295 4500ND493476
Carbon tetrachloride ug/L 500 101 70-143103 2500ND505514
Chlorobenzene ug/L 500 103 70-138104 1500ND514519
Chloroethane ug/L 500 108 52-163108 0500ND540541
Chloroform ug/L 500 93 70-13995 2500ND482493
Chloromethane ug/L 500 101 41-139100 1500ND505499
cis-1,2-Dichloroethene ug/L 500 101 70-141104 35008.6J 516 529
cis-1,3-Dichloropropene ug/L 500 98 70-13799 1500ND488494
Dibromochloromethane ug/L 500 98 70-13497 1500ND489485
Dibromomethane ug/L 500 102 70-138105 3500ND508523
Dichlorodifluoromethane ug/L 500 103 47-155104 2500ND513521
Diisopropyl ether ug/L 500 97 63-14499 2500ND485493
Ethylbenzene ug/L 500 103 66-153104 0500ND517520
Hexachloro-1,3-butadiene ug/L 500 120 65-149111 8500ND602557
m&p-Xylene ug/L 1000 104 69-152104 01000ND10401040
Methyl-tert-butyl ether ug/L 500 100 54-156101 0500ND501503
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 10 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2490027MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92415883006
2490028
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Methylene Chloride ug/L 500 93 42-15993 0500ND498498
Naphthalene ug/L 500 112 61-148105 7500ND559523
o-Xylene ug/L 500 108 70-148107 1500ND539535
p-Isopropyltoluene ug/L 500 108 70-146106 2500ND542530
Styrene ug/L 500 104 70-135103 2500ND521513
Tetrachloroethene ug/L E50013559-143547 48500262033005360
Toluene ug/L 500 98 59-14899 2500ND488497
trans-1,2-Dichloroethene ug/L 500 103 70-146105 3500ND513526
trans-1,3-Dichloropropene ug/L 500 95 70-13598 3500ND476489
Trichloroethene ug/L 500 107 70-147114 650011.8J 548 580
Trichlorofluoromethane ug/L 500 101 70-148101 0500ND503503
Vinyl acetate ug/L 1000 99 49-15196 31000ND990962
Vinyl chloride ug/L 500 109 70-156107 2500ND544534
Xylene (Total)ug/L 1500 105 63-158105 01500ND15801580
1,2-Dichloroethane-d4 (S)%95 70-13094
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%97 70-13096
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 11 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456010
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Associated Lab Samples:92416095001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2488458
Associated Lab Samples:92416095001
Matrix:Water
Analyzed
Fluoride mg/L ND 0.10 02/02/19 12:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2488459LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoride mg/L 2.52.5 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488460MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416071001
2488461
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 103 90-110104 12.5ND 2.6 2.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488462MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416071011
2488463
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 100 90-110100 12.5ND 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 12 of 20
#=ARR#
ANALYTICAL RESULTS - RADIOCHEMISTRY
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Sample:TMW-5 Lab ID:92416095001 Collected:01/30/19 17:00 Received:02/01/19 10:00 Matrix:Water
Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No.QualMethod
PWS:Site ID:Sample Type:
Total Uranium 3.55 ± 0.178 (0.262)
C:NA T:NA ug/L 02/13/19 14:04 7440-61-1ASTM D5174-97
Uranium-234 2.48 ± 0.498 (0.167)
C:NA T:84%pCi/L 02/12/19 14:20 13966-29-5 N2HSL-300
Uranium-235 0.199 ± 0.116 (0.045)
C:NA T:84%pCi/L 02/12/19 14:20 15117-96-1 N2HSL-300
Uranium-238 2.06 ± 0.432 (0.118)
C:NA T:84%
pCi/L 02/12/19 14:20 N2HSL-300
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 13 of 20
#=QCR#
QUALITY CONTROL - RADIOCHEMISTRY
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329379
ASTM D5174-97
ASTM D5174-97
D5174.97 Total Uranium KPA
Associated Lab Samples:92416095001
Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers
METHOD BLANK:1602577
Associated Lab Samples:92416095001
Matrix:Water
Analyzed
Total Uranium ug/L 02/13/19 13:180.085 ± 0.006 (0.262) C:NA T:NA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 14 of 20
#=QCR#
QUALITY CONTROL - RADIOCHEMISTRY
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
329227
HSL-300
HSL-300
HSL300(AS) Actinides
Associated Lab Samples:92416095001
Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers
METHOD BLANK:1601815
Associated Lab Samples:92416095001
Matrix:Water
Analyzed
Uranium-234 pCi/L N202/12/19 14:200.072 ± 0.047 (0.054) C:NA T:87%
Uranium-235 pCi/L N202/12/19 14:200.031 ± 0.037 (0.056) C:NA T:87%
Uranium-238 pCi/L N202/12/19 14:200.012 ± 0.040 (0.077) C:NA T:87%
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 15 of 20
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Act - Activity
Unc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval).
Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval)
(MDC) - Minimum Detectable Concentration
Trac - Tracer Recovery (%)
Carr - Carrier Recovery (%)
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - GreensburgPASI-PA
ANALYTE QUALIFIERS
Analyte concentration exceeded the calibration range. The reported result is estimated.E
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 16 of 20
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92416095
Castle Hayne Sand Mine III
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92416095001 456399TMW-5 EPA 8260B
92416095001 329379TMW-5 ASTM D5174-97
92416095001 329227TMW-5 HSL-300
92416095001 456010TMW-5 EPA 300.0 Rev 2.1 1993
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/13/2019 04:02 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
Page 17 of 20
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