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HomeMy WebLinkAbout08-0284 CHANGE ORDER New Hanover County DATE: May 8, 2008 Project Name: STACK TESTING SERVICES CHANGE ORDER NUMBER: 1 New Hanover County CONTRACTOR: DEECO, INC CONTRACT 08-0284 NORTH 4 C A R O L I N A The Contractor is directed to make the following changes to this contract: Description: WASTEC HAS A NEED TO PERFORM CARBON EVALUATION TESTING ON UNIT 3A. DETAIL OF THIS ADDITIONAL SERVICE IS ATTACHED. WORK IS TO BE COMPLETED BY 711/2009. Total Cost: $15,500.00 Original Contract Sum: $181,800.00 Net Change byPrevious Change Orders No. 00 to No. 00 0 The Contract Sum Prior to this Change Order Was: $181,800.00 The Contract Sum Will Be (Increased) By This Change Order: $15,500.00 The New Contract Sum Including This Change Order Will Be: $197,300.00 The Contract Time Will 8e (Increased) By: 0 The Date of Substantial Completion Therefore Is: change order only ( 7/9109) Recommended: Accepted: Approved: Project Manager Contractor Owner New Hanover County DEECO, INC. New Hanover County Firm JrG91- AUT JORIZE SIGNATURE AUTHORIZED SIGNATURE AUTHORIZED SIGNATU DATE DATE DATE This Space for County Use Only APPROVED AS TO FORM Budget Account 70080400-700000 Balance Prior to this Change Order: $16,526.00 COUNTY ATTORNEY Amount of this Change Order: $15,500.00 THIS INSTRUMENT HAS BEEN PRE-AUDITED IN THE MANNER REQUIRED BY LOCAL Budget Account Balance: $1,026.00 GOVERNMENT AND FISCAL CONTROL ACT Change Order Percentage for this Contract 0.085258526 ~2t FINANCE DIR OR ORIGINAL i I DEECO Lro. I 3404 Lake Woodard Road Raleigh, NC 27604 www.stacksam lin .com 919 250-0285 (h 919 250-1835 Fax April 26, 2009 i Mr. Paul Marlow New Hanover County Department of Environmental Management Wilmington, NC 28401 i REF: Quote for Carbon Evaluation Engineering Testing on Unit 3A i Dear Mr. Marlow: i DEECO, Inc (DEECO) is pleased to submit this quotation pursuant to your request. DEECO will conduct carbon evaluation engineering testing on Unit 3A for a firm fixed cost of $15,500. Six simultaneous inlet and outlet Method 29 (mercury) runs will be conducted. The runs will be conducted as follows: I Unit 3A will be operated for at least 6 hrs at 4 lbs/hr j DEECO will conduct 2 1-hr runs at inlet and outlet Unit 3A will be switched to 5 lbs/hr and wait 2 hrs DEECO will conduct 2 1-hr runs at inlet and outlet Unit 3A will be operated overnight at 6 lb/hr DEECO will conduct 2 1-hr runs at inlet and outlet i Unit 3A will be switcced to 7 lb/hr and wait 2 hrs DEECO will conduct 2 1-hr runs at inlet and outlet DEECO will provide you with our availability on May 1. A delay rate of $60/man-hr will be charged for any delay beyond the control of DEECO. The Project Manager and On-site Coordinator will be Mr. Bill DeWees. If you have any questions or need additional information, please give Mr. Marc Hamilton or me a call at (800) 733-3261. Sincerely, 1 W.G. DeWees President DEECO, Inc Q New Hanover County Routing Slip Contract # Department Acct. # Initials Date To: Risk Manager Grants Coordinator Finance Director County Manager Commission Chairman Clerk to the Board County Attorney From: Legal Dept. Date Re: Contract for/Dept. Q~ucl I~"t UC ~.~-x New Hanover County Contract # 08-0284 NORTH CAROLINA NEW HANOVER COUNTY r ,_ THIS CONTRACT, mad. aod .ole,.d ;010 Ih;, 29- day of 1m ' 200_, by and between NEW HANOVER COUNTY, a political subdivision of the State of North Carolina, hereinafter referred to as "County"; and DEE CO, INC., a North Carolina corporation, hereinafter referred to as "Contractor"; WITNESSETH: AGREEMENT That the Contractor, for the consideration hereinafter fully set out, hereby agrees with the County as follows: 1. Scope of Services. Contractor shall provide protocol preparation, conduct engineering tests, perform stack testing, perform analytical testing and associated report preparation at the New Hanover County Waster to Energy Conversion (WASTEC) facility located at 3002 U.S. Hwy. 421 N., Wilmington, NC, in accordance with "Exhibit A" attached hereto and incorporated herein by reference. 2. Time of Performance. Contractor shall commence work upon Notice to Proceed. The duration of this contract will be for three (3) years, with the first event being in 2008, in accordance with the provisions of Exhibit "A". 3. Pavment. County hereby agrees to pay for the cost of the contract as set forth in "Exhibit A", not to exceed Fifty Nine Thousand Five Hundred ($59,500) dollars in year 2008; Sixty Thousand Six Hundred ($60,600) dollars in year 2009; and Sixty One Thousand Seven Hundred ($61,700) dollars in year 2010. 4. Extra Work. County and Contractor shall negotiate and agree upon the value of any extra work prior to the issuance of a Change Order covering said extra work. Such Change Order shall set forth the corresponding adjustment, if any, to the Contract Price and Contract Time. 5. Indemnitv. Contractor shall indemnify and hold New Hanover County, its agents and employees, harmless against any and all claims, demands, causes of action, or other liability, including attorney fees, on account of contract or -1- ORIG'NAL New Hanover County Contract # 08-0284 personal injuries or death or on account of property damages arising out of or relating to the work to be performed by Contractor hereunder, resulting from the negligence of or the willful act or omission of Contractor, his agents, employees and subcontractors. 6. Insurance. Contractor shall maintain insurance from companies licensed to write business in North Carolina, with an A.M. Best rating of "A" or higher, and acceptable to County, of the kinds and minimum amounts specified below. 7. Certificates and Notice of Cancellation. Before commencing work under this contract, Contractor shall furnish County with certificates of all insurance required below. Certificates shall indicate the type, amount, class of operations covered, effective date and expiration date of all policies, and shall contain the following statement: "The insurance covered by this certificate will not be canceled or materially altered, except after thirty (30) days written notice has been received by County". The Certificate of Insurance, naming New Hanover County as an additional insured, shall be further evidenced by an actual endorsement furnished to the County from the insurer within thirty (30) days of the signing of the contract between the Contractor and the County. 8. Workers Compensation and Emplovers Liability Insurance. Covering all of the Contractor's employees to be engaged in the work under this contract, providing the required statutory benefits under North Carolina Workers Compensation Law, and employers' liability insurance providing limits at least in the amount of $100,000/500,000/100,000. applicable to claims due to bodily injury by accident or disease. 9. Commercial General Liabilitv. Including coverage for independent contractor operations, contractual liability assumed under the provisions of this contract, products/completed operations liability and broad form property damage liability insurance coverage. The policy shall provide liability limits at least in the amount of -2 - New Hanover County Contract # 08-0284 $1,000,000 per occurrence, combined single limits, applicable to claims due to bodily injury and/or property damage. New Hanover County shall be named as an additional insured under this policy. 10. Automobile Liability Insurance. Covering all owned, non-owned and hired vehicles, providing liability limits at least in the amount of $1,000,000 per occurrence combined single limits applicable to claims due to bodily injury and/or property damage. 11. Professional Liability Insurance. The Contractor will be required to take out and maintain Professional Liability Insurance providing liability insurance limits at least in the amount of $500,000.00. The Contractor will be required to maintain this coverage for a period of at least two (2) years beyond substantial completion of the contract. 12. Independent Contractor. It is mutually agreed that Contractor is an independent contractor and not an agent of the County, and as such the Contractor shall not be entitled to any County employment benefits, such as, but not limited to, vacation, sick leave, insurance, workmen's compensation, or pension and retirement benefits. 13. Warranty. The Contractor warrants County that any and all labor furnished to progress the work under this contract will be competent to perform the tasks undertaken, in a workmanlike manner, so as to meet the standards of workmanlike quality prevailing in North Carolina at the time of construction, that any and all materials and equipment furnished will be of good quality and that the work will be of good quality, free from faults and defects and in strict conformance with this contract. All work not conforming to these requirements may be considered defective. All work shall conform to applicable Federal, State and local laws and regulations. Contractor shall be responsible for all costs, damages and expenses including, but not limited to, penalties, fines and fees, that the County may incur as a result of Contractor's failure to perform under this Agreement. -3- New Hanover County Contract # 08-0284 14. Default and Termination. If Contractor fails to prosecute the work with such diligence as will insure its completion within the contract time, or if Contractor breaches any of the terms or conditions contained in this contract and fails to cure said breach within two (2) days of County's mailing of Notice of Default, or otherwise fails to perform the work hereunder to the County's reasonable satisfaction, County may terminate this contract forthwith. Upon termination, County may, without prejudice to an action for damages or any other remedy, take the prosecution of the work out of the hands of Contractor. County may enter into another contract for the completion of the contract, or use such other methods as may be required for the completion of the contract. County may deduct all costs of completing the contract from any monies due or which may become due to Contractor. In the event this project is terminated prior to completion of the services by the Contractor, the Contractor shall be paid for services performed to the date of termination. In no event will the amount due Contractor in the event of termination exceed that amount set forth in paragraph 3 of this Contract. Nothing contained herein shall prevent the County from pursuing any other remedy which it may have against Contractor, including claims for damages. 15. Nonwaiver of RiQhts. It is agreed that either party's failure to insist upon the strict performance of any provision of this Contract, or to exercise any right based upon a breach thereof, or the acceptance of any performance during such breach, shall not constitute a waiver of any rights under this Contract. 16. Conflict of Interest. No paid employee of the County shall have a personal or financial interest, direct or indirect, as a contracting party or otherwise, in the performance of this Contract. 17. Subcontracts. The Contractor shall utilize no subcontractors for carrying out the services to be performed under this Contract without the written approval of the County. 18. Entire AQreement. This agreement constitutes the entire understanding of the parties. -4- New Hanover County contract # 08-0284 19. Bindino Effect. This contract shall be binding upon the parties hereto, and their heirs, successors, executors, administrators and assigns. 20. Further Actions. The parties will make and execute all further instruments and documents required to carry out the purposes and intent of this contract. 21. Inclusive Terms. Use of the masculine herein shall include the feminine and neuter, and the singular shall include the plural. 22. Governino Law. All of the terms and conditions contained herein shall be interpreted in accordance with the laws of the State of North Carolina. 23. Notices. All notice required hereunder to be sent to either party shall be sent to the following designated addresses, or to such other address or addresses as may hereafter be designated by either party by mailing of written notice of such change of address, by Certified Mail, Return Receipt Requested: To County: New Hanover County WASTEC Attention: Paul Marlow 3002 U.S. Hwy 421 N. Wilmington, North Carolina 28401 To Contractor: DEECO, Inc. Attention: Bill DeWees 3404 Lake Woodard Drive Raleigh, NC 27604 24. Assionabilitv. It is mutually agreed by the parties hereto that this contract is not transferable and shall not be assigned by either party without the written consent of the other party to this contract. 25. Amendments. This Contract shall not be modified or otherwise amended except in writing signed by the parties. IN WITNESS WHEREOF, the parties have hereunto set their hands and seals, the day and year first above written and by authority duly given. - 5- New Hanover County Contract # 08-0284 NEW HANOVER COUNTY :.1 . Bruce T. Shell, County Manager Clerk to the Board [COR_~()RA TE SEAL] DEECO, INC. pJJ;(J~~ ~resident ATTEST: sej~UA- ~ This instrument has been pre- audited in the manner required by the Local Government Budget and Fiscal Control Act. Approved as to form: ~'~)'r Z/.2.5JoR C nty Finance Director ~a, '-cOunty Attorney "-~ NORTH CAROLINA NEW HANOVER COUNTY I, - ~ wll ( , a Notary Public of the State and County afore aid, cert' that Sheila L. Schult acknowledged that she is Clerk to the Board of Commissioners of New Hanover County, and that by authority duly given and as the act of the Board, the foregoing instrument was signed in its name by its Manager, sealed with its corporate seal and attested by herself as its Clerk. -C-L WITNESS my hand and official seal, this dqi!; day of ~fUa~ ' ~OO~'''''' ~ n / /I (!.. . A J "",""'~o)~::.~:,?:o>"'~, -7)~ .dU ~." b. .~ of '$>"'.... .... @ijo ~ N tary Publ ~ ~ ..' o1:p,.ll'l' ". ~ ~ -li:' .~ .- g .: ~~~ comfn. ~ ~ My commission expires: ~ 1 . ",?i"S : ~ :: . ",<).(..1,'.')'" ! := - . ~\I"" '. ~. - ~ .... "\JB\,lC/ ~i ~ ....~ ".." '" ~ - ........ Ai .......' r''''''' "'" 'VStr (..'-1 " ..../...."1 Hano\Je\ " \\\\\' /1/1/1111/':11\11;"\\"'\ New Hanover County Contract # 08-0284 NORTH CAROLINA NEW HANOVER COUNTY I, ~'\.y- ~("(\t)~~~b ,a Notary Public of the State and County aforesaid, certify that bnCc, :C eo L1 \la.k.., came before me this day and acknowledged that (s)he is Secretary of DEECO, INC. and that by authority duly given and as the act of the corporation, the foregoing instrument was signed in its name as its President, sealed with its corporate seal and attested by him/herself as its Secretary. .-- ~ WITNESS h_ rU.t1 ~1l / my hand and , 20....0 8 official seal, this r:re- day ~ <'fr-zjjt~^~ Nqt'ary Public ./ a of My commission expires: LjI2-E I 'UJ /0 ~.""""""""''''''''''..., .... <>."'E.LMo,. .... ..' ,v';......."'.....v,..., " ~..., ....."/,,0.'.. . "- /', AR .. ....'" ;. '."...0 r....;. 'iif'~ . . [.d \ ~ .. ~ .. i, ,\" jCJ E :: 't :: " .... CJ ~. \ J;;.,.. 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ATTACHMENT 1 PROJECT SPECIFICATIONS GENERAL CONDITIONS 1.1 Proiect Description: The contract work generally consists of protocol preparation, conducting engineering tests, performing stack testing, performing analytical testing, and associated report preparation for a period of three (3) years at the New Hanover County Waste to Energy Conversion (W ASTEC) facility located at 3002 U.S. Highway 421 North, Wilmington, North Carolina. 1.2 Existing Conditions: It is the responsibility of the Contractor, before submitting a proposal, to thoroughly investigate the facility, examine existing records, Federal and state requirements and regulations, associated plans and specifications; clearly understanding all requirements necessary to perform the testing, analysis and reporting; that the Contractor is prepared to provide all necessary tools, equipment, labor and materials to successfully complete the work. 1.3 Background: The W ASTEC facility consists of two (2) 100 TPD Mass Bum Municipal Solid Waste combustors and one (1) 300 TPD Mass Bum Municipal Solid Waste combustor. Control devices consist of wet scrubbers and bag filters, activated carbon injection, followed by a 200-foot stack with work platform. The 300 TPD unit also utilizes the injection of urea for control of various pollutants. TESTING PROTOCOL 2.1 Protocol Preparation: The Contractor shall on an annual basis prepare and submit for review a testing protocol which outlines the proper EP A test methods which will be followed while testing at the W ASTEC facility. The testing protocol and completed "Protocol Submittal Form" shall be submitted for review and signature by the Department before submittal to the NC Division of Air Quality. It is critical that the test protocol be prepared and submitted to meet the specified minimum of 45 days advance notice oftesting. 2.2 Protocol Aporoval: The submitted testing protocol must be approved by the NC Division of Air Quality. The Contractor shall be responsible for subsequent amendments to the test protocol until approval is granted. The protocol must be submitted to the NC Division of Air Quality within the time frame specified in advance of actual testing. ENGINEERING TEST 3.1 Purnose: An engineering test may be performed at a mutually convenient time prior to compliance stack testing. The engineering test is designed to allow an evaluation of operating conditions and equipment performance; evaluate routine maintenance effectiveness and identify the need for additional maintenance prior to compliance testing. The need for engineering testing shall be determined by the Department on an annual basis. 3.2 Reporting: A written report providing results of the engineering tests shall be provided along with observations and recommendations for adjustments or modifications to operating conditions and/or equipment. Reports shall be provided as quickly as possible following conclusion of testing activities, Reports shall be provided directly to the Department for review as this is not intended to demonstrate compliance, STACK TESTING 4,1 Requirements: Currently, the W ASrEC facility air emissions permit requires annual stack testing for particulate matter (PM), It should be noted that although not regulated as a permit limit, condensible PM must be included in the testing and reporting. In addition, annual testing will be required for the following pollutants: dioxin! furan, hydrogen chlorides (HC1), and metals (Cd, Pb, Hg). It should be noted that testing will also be required at the scrubber inlet for both hydrogen chlorides (HC1) and mercury (Hg). Otherwise, testing will take place at outlet only. The same requirements will apply for all three units. 4.2 Scheduling: Contractor shall coordinate and schedule events at a time that the facility will be operating the equipment necessary to provide proper testing results. Bids should include time and materials costs in the event that a unit suffers mechanical failure or shuts down before testing can begin or be completed. Owner will not be responsible for costs encountered by the Contractor if the Contractor is testing at other than previously agreed upon times and a unit is required to shut down for repair or maintenance. Owner will not be responsible for costs encountered by the Contractor for delays due to contractor equipment failure, or unsafe weather conditions at the test site. 4.3 Retesting: Should a unit fail to meet emission limits during a compliance test, the Contractor shall coordinate a date for retesting at a mutually convenient time. '. ANALYTICAL TESTING 5.1 Methods: All analytical testing of pollutants captured during stack testing activities shall follow and comply with the currently specified EP A method or other method approved by the NC Division of Air Quality, Any contract laboratories used for analytical work should have appropriate licenses and certifications to perform the testing. REPORTING 7.1 Requirements: A complete written summary report of all stack testing activities and results shall be prepared and provided to W ASTEC in a timely manner, not to exceed 45 days, following each compliance stack testing event. Five (5) copies of each summary report shall be prepared and forwarded to W ASTEC, Three (3) of the copies will be paper and other two (2 ) will be in electronic format. All data required to be captured by the NC Division of Air Quality during testing shall be recorded by the contractor and included in the summary report in a manner acceptable to the Division, There are a number of particulate matter (PM) limits and results must be reported in units to show compliance with each standard ie. lb/MMBtu, gr/dscf etc. Results of other pollutants must be reported in both concentration and mass units ie. mg/dscf, lb/hr etc, ADDITIONAL CONSIDERATIONS 8,1 Safety: Contractor and subcontractor employees on-site will be required to follow all facility safety policies and procedures. Contractors may be required to submit documentation of safety training or related records as determined by the Department of Environmental Management Safety Officer. Owner will provide climbing apparatus for safe access to the stack platform. Contractor must provide' safety harness and any other safety equipment deemed necessary by the Safety Officer. 8.2 Site-Visit: Contractor will be required to make a site visit prior to the start of any work to review the site with staff and assist staff in review of sampling ports and/or other items necessary to prevent delays in testing activities. 7.3 Bid Summary: Bidder should provide a narrative describing work required in each item. Narrative should also include any subcontractor( s) to be used, relevant certifications and experience in similar projects. 14:14 FEB 20. 2BB8 TEL ~: 366-5421 +172136 PAGE: 2/3 ACORDn, CERTIFICATE OF LIABILITY INSURANCE I DATI: (MMItlD/YVYY) 0212012008 PRODUCER THIS CERTIFICATE IS ISSUED AS A MATTER OF INFORMATION Wachovia Insu ranee Serv-RA, NC ONLY AND CONFERS NO RIGHTS UPON THE CERTIFICATE 8540 Colonnade Ctr Dr, Ste 111 HOLDER. THIS CERTIFICATE DOES NOT AMEND, EXTEND OR ALTER THE COVERAGE AFFORDED BY THE POLICIES BELOW. PO Box 97787 Raleigh, NC 27624-7787 INSURERS AFFORDING COVERAGE NAICtI INSURED INSURER A;, Hartford Casualty Insurance Comoanv 29424 Deeco, Inc. INSURER B: Hartford Underwriters Insurance Comp 30104 3404 Lake Woodard Drive INSURER c: Raleigh, NC 27604 INSURER D: INSURER 1:: Cllenl#' 129586 DEECINC COVERAGES THE POLICIES OF INSURANCE LISTED BELOW HAVE BEEN ISSUED TO THE INSURED NAMED ABOVE FOR THE POLICY PERIOD INDICATED. NOTWITHSTANDING ANY REQUIREMENT, TERM OR CONDmON OF mf CONTRACT OR OTHER DOCUMENTwrrH RESPECT TO WHICH THIS CERTIFICATE MAY BE ISSUED OR MAY PERTAIN, THE INSURANCE AFFORDED BY THE POliCIES DESCRIBED HEREIN IS SUBJECT TDAll THE TERMS, EXCLUSIONS AND CONDITIONS OF SUCH POLICIES. AGGREGATE L1Mrrs SHOlNN MAY HAVE BEEN REDUCED BY PAID ClAIMS. LTR NS TYPE OF INSURANCE POUCY NUMBER I P8,H~Y~:O~~E Pg~f.I!.':.o~N UMITS A r!-ENERAL UABIUTY 22UUNUB9277 03110107 03110108 EACH OCCURRENCE 11 000 000 X COMMERCIAL GENERAl LIABILITY OAMAGE TO ReITEO 1300 000 I ClAIMS MADE [i] OCCUR MEa EXP (Anv one penon) 110 000 - PERSONAL & ADV INJURY 11000000 - GENERAL AGGREGATE 12 000 000 ~\. AG~En ~lIMIT APriS :ER PRClDUCTS. COMPfOP AGG I POLICY ~g: LOC A ~OMOBLE LlABIUTY 22UUNUB9277 03110107 03110108 COMBINED SINGLE LIMIT !... ANY AUTO (ElIaeddent) 11,000,000 - ALLOWNEDAUTOS BOOL Y INJURY I X SCHEDUl.f:D AUTOS (PerpelSoo) HIRED AUTOS ~ BaDLY INJURY I NON.oWNED AUTOS (Perllccidenl) "- - PROPERTY DAMAGE I (Perllecicle!1l) ~E LlA8LITT AUTO ON'- Y . EA ACCIDENT I ANY AUTO OTHER THAN EAACC I AUTO aNI. Y: AGG I A EXCESSAlMBREUA LlABlUTY 22RHUUB9300 03110107 03110108 EACH OCCURRENCE 110000000 ~.OCCUR D ClAIMS MADE AGGREGATE 110000000 I ~ ~OOCTBLE I X RETENTION 110000 I B WORKERS COMPENSATlONAND 22WEKK2332 03110107 03110108 I T~~S>f~m.;, I 10TH. EMPLOYERS'LlABLITV 11 000 000 ANY PROPRIETORlPARTNERfEXECUTIVE E.L. EACH ACCIDENT OFFICERfMEMBER exCLUDED? E.l. OISE.I\SE . H. EMPLOYEE 11 000000 ~~~lde~:~~ONS below E.L. DISEASE. pOliCY LIMIT 11000000 OTHER DESCRIPTION Of OPERATIONS f LOCATIONS I Vl:HICLES I EXCLUSIONS ADDED BY ENDORSEMENT I SPECIAL PROVISIONS Certificate holder is listed as additional Insured CERTIFICATE HOLDER New Hanover County Office of County Attorney 230 Government Center Drive, Suite 125 Wilmington, NC 28403 CANCELLATION SHOULD ANY Of THE ABOVE DE8CRBED POUCES BE CANCELLED BEFORE THE EXPIRATION DATE THEREOF, THE ISSUING INSURER WILL ENDEAVOR TO MAL .....30.... DAVS WRlTIEN NOTICE!; TO THE CERTIFICATE HOLDERNAMED TO THE LEFT, BUTFAlWRE TO DO so SHALL IMPOSE NO OBUGAllON OR LIABILITY OF ANY KtID UPON THE "SURER, ITS ADENTS OR REPRESENTAT1VE8. AUTHOIUZB) REPRESENTATIVE ACORD 25 (2001108) 1 of 2 tlS13188081M1161251 LHA02 @ ACORD CORPORATION 1988 14:15 FEB 20, 2008 TEL NO: 366-5421 +172136 PAGE: 3/3 IMPORTANT If the certificate holder is an ADDITIONAL INSURED, the policy(ies) must be endorsed. A statement on this certificate does not confer rights to the certificate holder in lieu of such endorsement(s). If SUBROGATION IS WAIVED, subject to the terms and cond~ions of the policy, certain policies may require an endorsement. A statement on this certificate does not confer rights to the certifICate holder in lieu of such endorsement(s). DISCLAIMER The Certificate of Insurance on the reverse side of this form does not constitute a contract between the issuing insurer(s), authorized representative or producer, and the certificate holder, nor does it affirmatively or negatively amend, extend or alter the coverage afforded by the policies listed thereon. ACORD 2S.S (2001108) 2 of 2 #S1318808/M1161251 ACORD. CERTIFICATE OF LIABILITY INSURANCE OP 10 B~ DATE (MMIDDIYYYY) DEECO-1 02/27/08 PRODUCER THIS CERTIFICATE IS ISSUED AS A MATTER OF INFORMATIO ONLY AND CONFERS NO RIGHTS UPON THE CERTIFICATE Ralph Whitehurst Ins Agcy, Inc HOLDER. THIS CERTIFICATE DOES NOT AMEND, EXTEND OR 8320 LitchfoM Road, Suite 200 ALTER THE COVERAGE AFFORDED BY THE POLICIES BELOW Raleigh HC 27615-3860 Phone: 919-872-3757 Fax: 919-872-5778 INSURERS AFFORDING COVERAGE NAIC# INSURED INSURER A: Indian Harbor INSURER B: Deeco Inc. INSURER C P.O. Box 4159 INSURER D. Cary NC 27519 INSURERE COVERAGES THE POLICIES OF INSURANCE LISTED BELOW HAVE BEEN ISSUED TO THE INSURED NAMED ABOVE FOR THE POLICY PERIOD INDICATED. NOTWITHSTANDING ANY REQUIREMENT. TERM OR CONDITION OF ANY CONTRACT OR OTHER OOClRlJlENT WITH RESPECT TO WHICH ntlS CERTIFICATE MAY BE ISSUED OR MAY PERTAIN, THE INSURANCE AFFORDED BY THE POlICIES DESCRIBED HEREIN IS SUBJECT TO ALL THE TERMS, EXCLUSIONS AND CONOITIONS OF SUCH POLICIES. AGGREGATE LMTS SHOWN MAY HAVE BEEN REDUCED BY PAlO CLAIMS. LT" .... TYPE 01" INSURANCE POlICY NUMBER DATE fMMlDD/YY1- DATE MMID~ LIMITS GENERAL L.IABILlTY EACH OCCURRENCE $ r---- COMMERCIAl GENERAL LIABJUTY PREMISES (Ea occurenoe) $ I CLAIMS MADE 0 OCCUR MED EXP (Anyone person) $ PERSONAL & mv INJURY $ r---- GENERAL AGGREGAlE $ rrAGG~n~;n,PER PRODUCTS-COMProPAGG $ POUCY JECT LOC ~TOMOBlLE LIABILITY COMBINED SINGLE LIMIT $ ANY AUTO (Ea accIdent) r---- ALL OWNED AUTOS BODILY INJURY $ SCHEDULED AUTOS {Per person) r---- HIRED AUTOS BODILY INJURY r---- $ NON-QWNED AUTOS {Per accident) r---- r---- PROPERTY DAMAGE $ (Per accident) GARAGE LlABtUTY AUTO ONLY - EA ACCIDENT $ R ANY AUTO OTHER THAN EA ACe $ AUTO ONLY: AGG $ EXCESSAIMBRELLA LIABILITY EACH OCCURRENCE $ tJ OCCUR n ClAIMS MADE AGGREGATE $ $ H DEDUCTIBLE $ RETENTION $ $ WORKERS COMPENSATION AND ITORYlIMm; I IUE~- EMPLOYERS' UABlLITY ANY PROPRIETORJPARlNERlEXECU11VE EL EACH ACCIDENT $ OFFICERlMEMBER EXCLUDED? E.l. DISEASE - EA EMPlOYE $ ~WClt.SP~~~~~ below EL DISEASE - POLICY LIMIT $ OTHER A Professional Liahi. PECOOO068407 01/15/07 01/15/08 Ded: S 50 000 RETRO DATE 12/15/96 DESCRIPTION OF OPERATIONS' lOCAT1ONS 'VEHICLES' EXClUSlONSADDED BY ENDORSEMENT' SPECIAl PROVISIONS Fax.: 910-798-7157 CERTIFICATE HOLDER NEWRA-3 CANCELLATION SHOULD ANY OF THE ABOVE DESCRIBED POUCfES BE CANCellED BEFORE THE EXPIRATlO~ DATE THEREOF, THE ISSUING INSURER WIll ENDEAVOR TO MAIL ~ DAYS WRITTEN NOTICE TO THE CERTIFICATE HOLDER NAMED TO THE LEFT, BUT FAILURE;: TO DO so SHAll. IMPOSE NO OBLIGATION OR LIABILITY c- - un .-...- . .--.. -..- ...-..--- .-- . --..-- -- New Hanover County Atten: Margaret Dunlap 230 Government Center Dr 1/125 Wilmington HC 28403 REPRESENTA11VES. AUTHORIZED REPRESENTATIVE Ralnh Whitehurst 41u... iLl ;fa.M.t.~ - Ins. """&A........ @ACORD CORPORATION 1988 ACORD 25 (2001/08) IMPORTANT If the certificate holder is an ADDITIONAL INSURED. the policy(ies) must be endorsed. A statement on this certificate does not confer rights to the certificate holder in lieu of such endorsement(s). If SUBROGATION IS WAIVED, subject to the terms and conditions of the policy, certain policies may require an endorsement. A statement on this certificate does not confer rights to the certificate holder in lieu of such endorsement(s). DISCLAIMER The Certificate of Insurance on the reverse side of this form does not constitute a contract between the issuing insurer(s), authorized representative or producer, and the certificate holder, nor does it affirmatively or negatively amend, extend or alter the coverage afforded by the policies listed thereon. ACURD 25 (2001/08) ---------- --::. NEW HANOVER COUNIY WANDA M. COPLEY County Attorney KEMP P. BURPEAU Deputy COWity AUomey SHARON J. HUFFMAN Assistant COWity AUomey March 4, 2008 Deeco, Inc. Attn: Bill DeWees 3404 Lake Woodard Drive Raleigh, NC 27604 RE: New Hanover Contract # 08-0284 Dear Mr. DeWees: Enclosed please find your copy of the above referenced contract. Thank you for your assistance in this matter. If you have any questions please give us a call. Sincerely, ~~~w~ Margaret Dunlap Administrative Support Specialist Office of the County Attorney Enclosure 230 Govemment Center Drive - Suite # 125 - Wilmington, N C 28403 Phone: 910-798-7153 - Fax: 910-798-7157 www.nhcgov.com 3404 Lake Woodard Road Raleigh, NC 27604 (919) 250-0285 (Ph); (919) 250-1835 (Fax) www.deeco.com www.stacksampling.com PROPOSAL FOR AIR EMISSIONS COMPLIANCE TEST PROGRAM Prepared for: l', -----./ Mr. Paul Marlow New Hanover County Department of Environmental Management Wilmington, NC 28401 Prepared by: W.G. DeWees DEECO, Inc. 3404 Lake Woodard Dr. Raleigh, NC 27604 c. c c I' '---/ Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: i Revision No: 0 Date: December 1, 2007 TABLE OF CONTENTS Section Pal!e 1. INTRODUCTION ...................................................... 1 2. STACK TESTING SUMMARIES........................................ 10 3. EMISSION TESTING PROGRAM PHASES . . . . . . . . . . . . . . . . . . . . . . .. 20 4. QUALITY ASSURANCE AND QUALITY CONTROL ................. 22 5. TESTING SCHEDULE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 40 6. REPORTING. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 41 7. UTILITIES AND OTHER REQUIREMENTS OF FACILITY. . . . . . . . . . . . . . .. 42 8. PROJECT COSTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 45 9. SAMPLING AND ANALYTICAL TEAM EXPERIENCE ................... 49 10. TERMS AND CONDITIONS............................................ 55 LIST OF TABLES TABLE PAGE TABLE 1.1. BID INFORMATION FOR TASK 1 ................................. 4 TABLE 1.2 BID INFORMATION FOR TASK 2 ENGINEERING TEST ............ 5 TABLE 1.3 BID INFORMATION FOR TASK 3 COMPLIANCE .................. 6 TABLE 1.3A PROGRAM OUTLINE AND TENTATIVE TEST SCHEDULE. . . . . .. 7 TABLE 1.4 BID INFORMATION FOR TASK 4 AUDIT SAMPLE ............. 8 TABLE 1.5 BID INFORMATION FOR TASK 5COMPLIANC TEST REPORT .... 9 TABLE 2.1 PCDDs/PCDFs GLASSWARE CLEANING PROCEDURE............ 17 TABLE 4.1 QUALITY CONTROL SAMPLES................................. 39 TABLE 8.1 BID SUMMARY FOR YEARS 2005, 2006, 2007 . ...... .......,....... 45 TABLE 8.2 OVERALL PROJECT COSTS BY TASKS ......................... 46 TABLE8.3 PROJECT COST BREAKDOWN FOR 2005 ........................ 47 TABLE 8.4 ANALYTICAL COST BREAKDOWN FOR 2005 .................... 47 TABLE 8.5 BILLING INFORMATION FOR EMISSION TESTING....... ........ 48 TABLE 9.1 DEE CO TESTING EXPERIENCE - CONFIDENTIAL ............ 53 o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 1 Revision No: 0 Date: December 1, 2007 1.0 INTRODUCTION DEECO, lnc (DEECO) is pleased to submit this quotation pursuant to our discussions and your Request for Proposal. This contract work generally consists of protocol preparation, conducting engineering tests, performing stack testing, performing analytical testing, and associated report preparation for a period of three (3) years at the New Hanover County Waste to Energy Conversion (WASTEC) facility located at 3002 U.S. Highway 421 North, Wilmington, North Carolina. The W ASTEC facility consists of two (2) 100 TPD Mass Burn Municipal Solid Waste combustors and one (1) 300 TPD Mass Burn Municipal Solid Waste combustor. Control devices consist of wet scrubbers and bag filters, followed by a 200-foot stack with work platform. The 300 TPD unit also utilized the injection of urea and activated carbon for control of various pollutants. In 2001,2002,2003,2004,2005,2006, and 2007 DEECO conducted almost $1,000,000 of MWC testing each year. DEECO tested fifteen (15) different facilities for five (5) different companies in ten (10) different states. The references are presented in Section 9. o DEECO's knowledge of MWC emissions (i.e. waiting time after startup to conduct dioxin/furan testing) and extra efforts (on-site analysis of HCl) can be critical to the success of your testing program. The test methods, sampling locations, and proposed sampling duration is presented below in Section 2. The Project Manager and On-site Coordinator will be Mr. Bill DeWees (President of DEECO and Mechanical Engineer). Mr. DeWees have been Project Manager on all MWC testing program over the past eight years. The test program has been divided into five (5) separate tasks. The Bid Summary is presented in Section 8. Task 1 (see Table 1.1) Compliance Test Protocol Development. A final test protocol will be developed for submission to the NC DAQ. Mr. Bill DeWees will make a pretest visit to the facility. The test plan can be developed in two days after the site visit. Task 2 Engineering Test (see Tables 1.2) will be conducted on a mutually agreeable date. No test schedule is presented because the schedule will vary with the selected test program. The engineering test is designed to allow an evaluation of operating conditions and equipment performance; evaluate routine maintenance effectiveness and identify the need for additional maintenance prior to compliance testing. DEECO has conducted numerous lime slurry and carbon injection evaluation tests. DEECO is aware of the standard rates of lime slurry and o carbon injection. DEECO conducts on-site analysis for HCl which provides on-site evaluation. c c c Air Emissions Compliance Test Program New Hanover County Dept of Enviromnental Management Wilmington, NC Page: 2 Revision No: 0 Date: December 1,2007 Our spreadsheet will give the stoichiometric ratio for each run. DEECO has also conducted numerous carbon optimization test to establish the proper carbon rate. Task 3 Compliance Test (see Tables 1.3, 1.3A and 1.38) will be conducted at mutually agreeable dates in accordance with the methods and scope shown in Table 1.3. The testing schedule for 2008,2009 and 2010 is presented in Table 1.3A. Method 29 for trace metals analysis was developed/evaluated by Mr. Bill DeWees and Dr. Scott Steinsberger under EPA Contract. The EPA Methods for hexavalent chromium was developed/evaluated by Mr. Bill DeWees and Dr. Scott Steinsberger under EPA Contract. The condensible particulate EPA Method 202 was developed/evaluated by Mr. Bill DeWees and Dr. Scott Steinsberger under EPA Contract. The EPA Method 26 and 26A for HCL was developed/evaluated by Mr. Bill DeWees and Dr. Scott Steinsberger under EPA Contract. Mr. Bill DeWees and Dr. Scott Steinsberger also evaluated the toluene rinse for Method 23 and helped develop the EPA audit program for dioxin/furans. In addition to conducting numerous testing program of similar scopes on MWCs, Mr. DeWees and Dr. Steinsberger also have several publications on sampling and QA/QC for MWC testing. For year 2008, 2009 and 20010, all three units will be tested for compliance during one week. As discussed in Section 3, DEECO has six specially designed trailers. For this task an Air Toxic Recovery trailer will be brought on-site, DEECO will conduct on-site analysis for HCI. Task 4 Analytical Testing (see Table 1.4) will be conducted by DEECO and their specified laboratories. North Carolina currently does not require laboratory certification. However, several of the states that DEECO tests in do require laboratory certification. DEECO's two labs are NELAP certified and certified in many other states: Analytical Perspectives and Element One. Therefore, if North Carolina requires lab certification in the future, all of the labs with be certified. Audit Samples (see Table l.5)may be required to be analyzed for M23, M26 and M29. If the samples are supplied, DEECO will have the appropriate lab analyze the sample. Task 5 Final Compliance Test Report (see Table 1.6). The draft report will be prepared and submitted for review within 45 days after field test completion. Review comments will be incorporated in final report. Five (5) copies of the final report will be submitted - Three hard copies and two copies submitted as a CD report. The scope of work is presented in detail in the Sections 2 through 6. Section 2, Stack Testine Summaries presents a summary of the stack sampling and analytical methods for each analyte to the measured. The stack sampling summary is presented in Table 2.1 for Task 1, Table 2.2 for Task 2, and Table 2.3 for Task 3. Section 3. Emission Testine Proeram Phases presents the staffing and equipment necessary to complete the each task. An overview will be given for all the tasks along the responsibilities. Section 4. Oualitv Control SamDles presents quality control samples to be collected and the minimum quality control to be implemented. The c c: o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 3 Revision No: 0 Date: December I, 2007 quality control samples are presented in Table 4.1. Section 5. Testing Schedule provides a tentative schedule for testing, analyses, and data reporting. The overall test schedule is presented in Table 5.1. Section 6. ReDortinl! presents the data reporting requirements. Section 7. Utilitv and Other requirements discusses the electrical and other facility requirements. Section 8. Proiect Cost~rovides the costs. The Bid Summary presented in Table 8.1. The overall costs by tasks are presented in Table 8.2. The Project Cost Breakdown for Year 2008 is presented in Table 8.3 with the analytical breakdown for Year 2008 in Table 8.4. For Year 2009 and 2010 a 2% cost escalation was used. These costs will remain valid for 60 days. DEECO standard costs are presented in Table 8.5. However, as shown in Section 10, the delay rate will be $60 per man hour plus per diem ($100/day/man). The last two sections deal with sample and analytical team experience and terms and conditions. Section 9. Samplinl! and Analytical Team Experiencdescribes team responsibility and individual responsibilities and experience. Also the laboratory subcontractors are presented. Section 10. Terms and Conditions presents DEECO's terms and conditions. o G o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 4 Revision No: 0 Date: December 1, 2007 TABLE 1.1 BID INFORMATION - TASK 1 COMPLIANCE TEST PROTOCOL DEVELOPMENT WITH SITE VISIT Task Description Objective General Information Develop test protocol Finalize all testing requirements DEECO develop protocol in two and make site visit days after site visit Cost for Task Make site visit 2005 - No Charge and develop test protocol 2006 - No Charge See Section 8 for 2004 - No Charge Bid Summary Requires a staff of one Program Management Bill DeWees Conducted at fifteen MWC facilities Complete descriptions See Section 2 for descriptions No deviations will be made and references or and references or deviations for deviations all sampling and analytical methods Analytical None Required None Required Subcontractor Summary of Conducted at thirteen See Table 9.1 forreferences on Experience different facilities similar tasks Standby and $601hr plus $1 OO/day perdiem Postponement No postponement charges are Charges are only at cost made unless an effort has been made Daily Test Matrix N/A N/A ()AJ~CProcedures N/A N/A c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 5 Revision No: 0 Date: December 1, 2007 TABLE 1.2 BID INFORMATION - TASK 2 ENGINEERING TEST Task Description Objective Generallnformation Compliance Test on Complete Performance Test 40 Testing conducted on mutually One Unit CFR 60 Subpart Cb and per agreeable dates NC DAQ Cost for Task Compliance Test on Three Units See Section 8 for costing see cost breakdown in Section 8 and Bid Summary Program Management Bill DeWees All large scale MWC tests have Dr. Scott Steinsberger - backup been managed by Bill DeWees Complete descriptions See Section 2 for descriptions and No deviations will be made and references or references or deviations for all deviations sampling and analytical methods Analytical Metals Element One - conducts all MWC Subcontractor tasks PCDD/PCDF Analytical Perspective - has conducted all MWC tasks Particulate and HCI DEECO Summary of This type of testing has been Bill DeWees have managed Experience conducted at thirteen numerous tests of this type at facilities MWC and other facilities Standby and $601hr plus $lOO/day perdiem Postponement No postponement charges are Charges are only at cost made unless an effort has been made Daily Test Matrix See Table 1.2A See Table 1.2A QA/QC Procedures See Section 4 Meet 40 CFR 60 Requirements and NC DAQ o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 6 Revision No: 0 Date: December 1, 2007 TABLE 1.3 BID INFORMATION - TASK 3 COMPLIANCE TEST Task Description Objective Generallnformation Compliance Test on Complete Performance Test 40 Testing conducted on mutually One Unit CFR 60 Subpart Cb and per agreeable dates NC DAQ Cost for Task Compliance Test on Three Units 2008 - $57,500 see cost breakdown in Section 8 2009 - $58,600 and Bid Summary 20010 - $59,700 Program Management Bill DeWees -likely All large scale MWC tests have Dr. Scott Steinsberger - backup been managed by Bill DeWees or Scott Steinsberger Complete descriptions See Section 2 for descriptions and No deviations will be made and references or references or deviations for all deviations sampling and analytical methods Analytical Metals Element One - conducts Subcontractor all MWC tasks PCDD/PCDF Analytical Perspective - has conducted all MWC tasks Particulate and HCl DEECO Summary of This type of testing has been Both men have managed Experience conducted at thirteen numerous tests of this type at facilities MWC and other facilities Standby and $601hr plus $1 OO/day perdiem Postponement No postponement charges are Charges are only at cost made unless an effort has been made Daily Test Matrix See Table 1.3A See Table 1.3A QNQC Procedures See Section 4 Meet 40 CFR 60 Requirements and NC DAO c c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 7 Revision No: 0 Date: December 1, 2007 TABLE 1.3A PROGRAM OUTLINE AND TENTATIVE TEST SCHEDULE SAMPLING SAMPLING NUMBER RUN TIME LOCATION TEST PARAMETER METHOD OF RUNS DURATION DAY I Arrive on-site and setup test equipment on Units 1,2 and 3 - Test in afternoon Unit 2 Boiler Exit HC1 Modified M26A 1 60 min 10 hr Unit 2 FF Outlet HC1 EP A Method 26A 1 60 min 4-8 Dioxin/Furans EP A Method 23 1 240 min DAY 2 Unit 1&2 Boiler Exits and Unit 1& 2 FF Outlets Unit I Boiler Exit Mercury EP A Method 29 3 120 min 10 hr Unit I FF Outlet Fil/Cond Particulate EP A Method 5/202 3 120 min Opacity EPA Method 9 3 60 min Mu1timetalsl EP A Method 29 3 120 min Unit 2 Boiler Exit HC1 Modified M26A 2 60 orin Unit 2 FF Outlet HC1 EP A Method 26A 2 60 min 4-8 DioxinlFurans EP A Method 23 2 240 min DAY 3 Units 1,2 & 3 Boiler Exits and FF Outlets Unit 3 Boiler Exit Mercury EP A Method 29 3 120 min IOhr Unit 3 Particulate EP A Method 5 3 120 min FF Outlet Opacity EP A Method 9 3 60 min Mu1timetals I EP A Method 29 3 120 min Unit I Boiler Exit HC1 Modified M26A 2 60 min Unit 1 HC1 EP A Method 26A 2 60 min FF Outlet 4-8 DioxinlFurans EP A Method 23 2 240 orin DAY 4 Unit 1,2 and 3 Boiler Exits and FF Outlets Unit 2 Boiler Exit Mercury EP A Method 29 3 120 min 10 hr Unit 2 Particulate EP A Method 5126A 3 120 min FF Outlet Opacity EP A Method 9 3 60 min Multimeta1s1 EP A Method 29 3 120 min Unit 1 Boiler Exit HCI Modified M26A 1 60 min Unit 1 FF Outlet HC1 Modified M26A I 60 min 4-8 DioxinlFurans EP A Method 23 1 240 min Unit 3 Boiler Exit HC1 Modified M26A 1 60 min Unit 3 FF Outlet HC1 Modified M26A 1 60 min 4-8 Dioxin/Furans EPA Method 23 1 240 min DAY 5 Unit 3 Boiler Exit and FF Outlet Unit 3 Boiler Exit Hel Modified M26A 2 60 min 10 hr Unit 3 FF Outlet HCI EPA Method 26A 2 60 min 4-8 Dioxin/Furans EPA Method 23 2 240 min Facility Ash Fugitive Emissions EPA Method 22 3 60 min Handline System o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 8 Revision No: 0 Date: December 1, 2007 TABLE 1.4 BID INFORMATION - AUDIT SAMPLES Task Description Objective General Information Audit Samples Evaluate accuracy of Method Ifno audit samples are received, no 23, 26, and 29 cost will be incurred for Task 5 Cost for Task Method 23 $1100 per sample Method 26 $50 per sample Method 29 $500 per sample Program Management Bill DeWees -likely Matt Winkeler, Lab Manager, will Scott Steinsberger - backup coordinate with subcontract labs as he does with all other samples Complete descriptions Analyze in same manner as No deviations and references or applicable method deviations Analytical Metals Element One. conducts all other Subcontractor MWC tasks and audits PCDD/PCDF Analytical Perspective - has conducted all MWC tasks and audits HCI DEECO Summary of Experience Same as Testing See Table 9.1 Standby and Postponement N/A N/A Daily Test Matrix N/A N/A QNQC Procedures See Section 4 Meet 40 CFR 60 Requirements and NC DAQ c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 9 Revision No: 0 Date: December 1, 2007 TABLE 1.5 BID INFORMATION - TASK 6 - COMPLIANCE TEST REPORT Task Description Obiective General Information Final Compliance Use report format acceptable Four copies of draft within Tests Report to W ASTEC and NC DAQ 45 days of completion of testing. The final and submit on time Report will be submitted within 2 days after receiving comments Cost for Task Report Preparation 2008,2009 & 20010 - $2,000 Program Bill DeWees - reviewer Marc Hamilton has also written all of the Management Marc Hamilton - author MWC reports. This approach has provided and Chemical Engineer outstanding quality and consistency Complete Report will use report format No deviations descriptions and acceptable to W ASTEC references or and NC DAQ deviations Analytical Subcontractor None Required None Required Summary of This type of reporting has Experience been conducted at numerous See Table 9.1 MWC faclities Standby and Postponement N/A N/A Daily Test Matrix N/A 30 days of completion of testing final 2 days after comments QNQC See Section 4 Meet 40 CFR 60 Requirements Procedures and NC DAQ o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 10 Revision No: 0 Date: December I, 2007 SECTION 2. STACK TESTING SUMMARIES All sampling and analytical methods employed for this program will be performed in accordance with the procedures outlined in the Standards of Performance for New Stationary Sources, 40 CFR 60.58b and 40 CFR 60.38b. 2.1 SAMPLE POINT AND PORT LOCATIONS The number and location of the sampling or traverse points will be determined according to the procedures outlined in EP A Method 1. The sample location will be inspected to insure EP A Method 1 criteria is met. A cyclonic flow check will be performed before the start of testing. All points will be more than 0.5 inches from the stack wall. 2.2 FLUE GAS VELOCITY AND VOLUMETRIC FLOW RATE - EPA METHOD 2 The flue gas velocity and volumetric flow rate will be determined according to the procedures outlined in EPA Method 2. Velocity measurements will be made using type S pitot tubes conforming to the geometric specifications outlined in EPA Method 2. Accordingly, each has been assigned a coefficient of 0.84. Differential pressures will be measured with Magnehelic gauges of appropriate range or with fluid manometers. Effluent gas temperatures will be measured with chromel-alumel thermocouples equipped with hand-held digital readouts, 2.3 FLUE GAS COMPOSITION - EPA METHOD 3 Flue gas analysis for oxygen (02) and carbon dioxide (C02) concentrations, and the calculation of percent excess air and flue gas dry molecular weight will be performed in accordance with EPA Method 3. Multi-point, integrated sampling will be used to obtain a flue gas sample concurrent with any isokinetic testing. A diaphragm pump, delivering 500 to 750 cubic centimeters-per-minute (cc/min) of flue gas will be used to fill a Tedlar bag. Moisture will be removed from the sample with a knockout jar located at the exit of the sampling probe. Sampling will be of the same duration as the test runs, except for purges following port changes. Concentration measurements will be made using an orsat analyzer. Prior to each series of analyses, the Orsat will be leak checked to confirm that there is less than 0.2 milliliter (mL) change in five minutes. Analysis for a given sample will repeated until the dry molecular weights for any three analyses differ by less than 0.3 Ib/lb-mole from their mean, and the 0 2 analyses less than 0.3% from their mean. o o o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 11 Revision No: 0 Date: December 1,2007 2.4 FLUE GAS MOISTURE CONTENT - EPA METHOD 4 The flue gas moisture content will be determined in conjunction with each EP A Method 5 type train and according to the sampling and analytical procedures outlined in EP A Method 4. The impingers will be connected in series and will contain reagents as described below. The impingers will be contained in an ice bath in order to assure condensation of the moisture in the flue gas stream. Any moisture that is not condensed in the impingers is captured in the silica gel, therefore all moisture can be weighed and entered into moisture content calculations. 2.5 PARTICULATE MATTER - EPA METHOD 5 AND METHOD 202 An EP A Method 5 sampling train will be used to collect particulate matter and particulate matter. The condensible PMIO will be determined by EPA Method 202. The sample train used for collecting particulate matter samples is an EP A Method 5 design. All particulate and condensible matter collected will be assumed to be less than 10 microns in diameter since emissions are controlled by a fabric fIlter. Condensible matter will exclude ammonium, chloride and sulfate (optional). Samples are collected over a two (2) hour period to assure adequate amounts of particulate matter are collected for accurate weighing. The gas is drawn from the stack through a glass nozzle and heated probe liner, through a pre-tared front-half filter, and through three (3) impingers containing 100 milliliters (m!) of deionized (D!) water, through an empty impinger, and through a bubbler containing indicating silica gel desiccant. All glassware will be thoroughly cleaned and rinsed with DI water, acetone, and methylene chloride (CHzClz) prior to use. The probe and filter boxed heaters will be kept at settings to maintain a temperature of248 :t250F during the test. The back-half is maintained at a temperature below 68 OF by adding ice to the condenser section throughout sampling. The sample train is connected to a control box by means of an umbilical cord which contains a vacuum hose, pitot lines, thermocouple wires and a 4-wire electrical cord. The control box (meter box) is used to monitor stack conditions and to facilitate isokinetic sampling. The control box consists of a leak-free pump used to pull the stack gas through the sample train, fine and coarse metering valves to control the sampling rate, a vacuum gauge which measures the pressure drop from the sampling nozzle to the metering valves, and a calibrated dry gas meter readable to 0.001 cubic feet. The dry gas meter inlet and outlet temperatures are monitored by thermocouples which are connected to a multichannel thermocouple indicator. The dry gas meter calibration factor, Y, is determined by calibJating the meter against a wet test meter or calibrated dry gas meter. At the outlet of the dry gas meter is a calibrated orifice which is used to monitor the flow of gas through the metering system to assure that samples are collected isokinetically. The pressure drop across the orifice is monitored at each sample point. The pitot tubes utilized to measure stack gas velocity are connected to the control box via the umbilical cord. The control box contains an inclined manometer used for the velocity measurement. Stack condition measurements are made prior to collecting a sample, including measurements of velocity, temperature and a check for cyclonic flow in the stack. A sample nozzle is selected and isokinetic operating parameters are established utilizing a programmable calculator. o o o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 12 Revision No: 0 Date: December I, 2007 The sampling nozzle, probe and prefilter connective glassware are cleaned and rinsed with dichloromethane prior to use. The sample train is assembled and determined to be leak-free following the procedures outlined in EPA Method 5. The sample nozzle is positioned in the stack at the first sample point. The sample pump is turned on, and the gas sampling rate is adjusted for isokinetic sampling. At the conclusion of the test, the pump is turned off, the probe is removed from the stack, and a post-test leak check is performed per Method 5 procedures. The Method 5/202 sample train will be purged with nitrogen (or air, per EPA Method 202) following each test to minimize sulfate (SO. ) formation in the impingers. The front-half of the sample train will be recovered with acetone per Method 5 procedures and the particulate matter will be quantified gravimetrically after evaporation of the acetone. Comments regarding the filter condition and the color of the particulate matter will be made on each data sheet. The back-half of the sample train will be recovered and analyzed per EPA Method 202. To perform the Method 202 back-half analysis, the impinger solutions are recovered into a graduated cylinder. The impingers are rinsed with DI water and the rinses are combined with the contents of the graduated cylinder and the final volume is recorded. The pH of each sample is measured and recorded. The condensible matter is quantified by performing a solvent extraction using a separatory funnel on the remaining impinger solution. The impingers are given a final rinse with 75 ml of CH2CI2, which are collected in a glass sample container for later use in the first extraction. Two (2) additional 75 ml portions of CH2CI2 are used for a total of three (3) 75 ml extractions. The organic layer is transferred to a tared 150 ml beaker and this beaker's contents are allowed to evaporate in an evaporation chamber at ambient temperature to dryness, the beakers are desiccated, then weighed to a constant weight. The water layer is transferred to a tared 150 ml beaker with glass boiling beads and this beaker's contents are heated on a hot plate to boiling until approximately 50 ml remain in the beaker. The remaining 50 ml in the beaker are evaporated to dryness in an oven at 1050C. The following measurements are optional and not included in the quote. The dried residue from the water layer for each sample is redissolved in 100 ml DI water. The solution is titrated with 0.1 N ammonium hydroxide (NHPH) to a pH of approximately 7.0 and the evaporation step is repeated. Sulfuric acid (H2S04) present in the condensible particulate matter is hydroscopic, which creates an erroneous particulate weight. The ammonium reacts with the H2SO. in an acid-base reaction which occurs during the titration procedure allowing a more accurate weight of condensible particulate matter to be obtained. Sample blanks containing DI water and CH2CI2 are analyzed in an identical fashion as the representative "section". All beakers are desiccated for at least 24 hours and weighed to constant weights of :1:0.5 milligrams (mg) after their contents have evaporated. The total particulate matter weight is the sum of the net weights of the particulate matter found on the filter plus the net weights found in the beakers containing the sample, minus the weight of the NH4 + added minus the acetone, water and methylene chloride blank concentrations. Comments regarding the color of the contents of each beaker will be made on each data sheet. Method 202 allows a correction only of the ammonium added during the titration procedure. The mass of SO. - is calculated based on the known amount of NH. + added and is shown on the o o o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 13 Revision No: 0 Date: December I, 2007 individual computer printouts in the appendices, but is not used in the correction calculation. The IC results for SO. - are used in the SO. - correction calculation which is allowed under permitting standards. The SO. - corrected particulate matter weight is the final net weight minus the net weight of the SO. - 2.6 SAMPLING AND ANALYSIS FOR FLUE GAS METALS (Cd, Pb and Hg) - EPA METHOD 29 EPA Method 29 will be used to collect Cadmium (Cd), Lead (Pb) , and Mercury (Hg) stack gas samples on both boilers. Three 120-min runs will be conducted. A reagent blank will be recovered for blank correction. The Method 29 sample train will consist of a glass nozzle and glass probe liner with a quartz fiber filter and a Teflon filter support. The reagents placed in the impingers will most likely be as follows: an empty first impinger, 100 mL of 5% HNQ'IO% HP2 in each of the second and third impingers, the fourth will remain empty, 100 mL of acidic KMnO. in the fifth and sixth, and 200 grams of silica gel in the seventh impinger. In addition, a low metals quartz filter, such as Pallflex 2500QA T -UP, will be used. The filter will be placed between the probe exit and the first impinger and the probe and filter will be maintained at a temperature of 248 :!: 25 F. At the conclusion of sampling the train is leak checked and transported to the sample recovery trailer. The probe and filter housing are removed and the impingers are weighed for EP A Method 4 moisture determination. The front half of the sampling train (nozzle, probe, & front half of the filter housing) will be brushed and rinsed with 100 mL of 0.1 N nitric acid into a uniquely identified glass sample jar to recover the metals. The brush will be Teflon, The contents (condensate & reagent) of the first three impingers will be placed in a uniquely identified glass sample jar. The backhalf of the filter holder through the third impinger will then be rinsed into the same uniquely identified glass sample jar using 100 mL of O.IN nitric acid solution. The fourth imp inger's condensate will be placed into a separate uniquely identified glass sample jar, and the impinger and connecting glassware will be rinsed with 100 mI of O.IM HNO, into the same jar. The contents (condensate & reagent) of the fifth and sixth impingers will be placed in a uniquely identified glass sample jar. The impingers and connecting glassware will then be rinsed into the same uniquely identified glass sample jar using 100 mI of acidic KMnO . solution. After the KMnO. rinse the impingers and connecting glassware will then be rinsed into the same uniquely identified glass sample jar using 100 ml of Dr water. To remove residual brown deposits, the fifth and sixth impingers will be rinsed with 25 ml of 8N HCL into a uniquely identified glass sample jar containing 200 ml of Dr water. Sample recovery from this combined train will include: I. 2. 3. Container No. I - Filter, quartz fiber Container No.2 - O.IN HNO, rinses of nozzle, probe and front-half of filter holder Container No.3 - Contents HNO ,1HP2 impingers, and O.IN HNO, rinse of impingers and back -half of filter holder o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 14 Revision No: 0 Date: December 1, 2007 4. Container No.4 - Contents of knockout impinger, and O.IN HNO 3 rinse of impingers 5. Container No.5 - Contents H2S04/KMn04 impingers, and H2SOiKMn04 and DI Hp rinse of impingers 6. Container No.6 - 8N HCL rinse of H2S04/KMn04 impingers (optional) Analytical procedures follow those outlined in EPA Method 29,40 CFR Pt. 60, App. A. The probe and nozzle rinses and the quartz filter will be subjected to microwave digestion with concentrated hydrogen fluoride and nitric acid. The 5 % nitric acid/l 0% hydrogen peroxide solution is reduced to near dryness, and digested with nitric acid and hydrogen peroxide. The target metals (except Hg) in these solutions and the front half fractions will be measured employing primarily graphite furnace atomic absorption spectroscopy (GFAAS). If greater analytical sensitivity can be obtained by ICP or FLAAS, arsenic, beryllium, cadmium, chromium, lead, nickel, and zinc will be measured the more sensitive technique. The front half, the 5 %/10%, the fourth (empty), and fifth and sixth (KMn04) impingers' reagent/ condensate/rinses and HCL rinse will be analyzed for mercury using cold vapor atomic absorption spectroscopy (CV AAS). The analytical methods are as follows: Metals Cadmium Lead Mercury SW-846 7131 7420 7470 (M29) Duplicate analyses will be performed on all mercury samples. In addition, a field blank, reagent blanks, and a filter blank will be collected and analyzed. Spikes will also be added to determine metal recovery efficiencies. Also duplicate analysis will be conducted on 10% of samples. 2.7 MERCURY - EPA METHOD 29 (Inlet Only) A second EPA Multi-Metal Sampling Train will be used to collect emissions samples for mercury only. This train is operated in the same manner as a regular EP A Method 5 sampling train. Pretest preparations, preliminary determinations, and leak check procedures will be those outlined in EP A Method 5. 2.7.1 Sample Collection The average sampling rate for each run will be within :!: 10 % of 100 % isokinetic conditions. Each test run will be a minimum of two (2) hours in duration and will sample a minimum of 60 dry standard cubic feet. Borosilicate glass or quartz probe liners and nozzles will be used to avoid possible contamination. The reagents placed in the impingers will be as follows: 100 ml of 5% HNO/IO% HP2 in each of the first two impingers, the third will remain empty, 100 ml of acidic KMnO 4 in the fourth, and 200 grams of silica gel in the fifth impinger. In addition, a low metals quartz filter, o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 15 Revision No: 0 Date: December I, 2007 such as Pallflex 2500QAT-UP, will be used. The filter will be placed between the probe exit and the first impinger. 2.7.2 Sample Recovery The front half of the sampling train will be rinsed with 0.1 N nitric acid to recover the metals. After impinger absorbing solutions recovery, all sample exposed components will be rinsed into appropriate containers with 0.1 N nitric acid, Surgical gloves will be used during recovery. The condensate catch determination will be performed according to EPA Method 4 procedures. SW-846 Methods will be used to determine metal concentrations. 2.7.3 Sample Analysis The filter, filter rinses, the first three impinger catches and rinses, and the KMn04 impinger reagent and rinse will be analyzed for mercury using cold vapor AA (CV AA). Duplicate analyses will be performed on all mercury samples. In addition, a field blank, reagent blanks, and a filter blank will be collected and analyzed. Spikes will also be added to determine mercury recovery efficiencies. 2.8 HYDROGEN CHLORIDE - EPA METHOD 26A The sampling and analytical procedures outlined in the EPA Method 26A will be used to determine hydrogen chloride (HCL) emissions. The sampling train impinger system will contain 100 ml ofO.lN sulfuric acid in each of the fITst two impingers, 100 ml ofO.lN sodium hydroxide in the third and fourth impingers, and 200 grams of silica gel in the fifth impinger. The optional cyclone will not be used since the gas stream is not saturated with moisture. The optional knockout impinger will not be used since the gas stream moisture is relatively low. The nozzle and probe liner will be constructed of borosilicate glass of quartz. The filter holder will be constructed of borosilicate glass with a Teflon frit filter support and a sealing gasket. A quartz-fiber filter will be used. Nozzles, probe liners, and filter holders will be rinsed thoroughly prior to testing. This train is operated in the same manner as a regular EPA Method 5 sampling train. Pretest preparations, preliminary determinations, and leak check procedures will be those outlined in EPA Method 5. The average sampling rate for each run will be within :t 10% of 100% isokinetic conditions. Each test run Will be a minimum of one (1) hours in duration and will sample a minimum of 30 dry standard cubic feet. The probe and filter will be maintained at between 35B and 400'F to prevent a bias from the ammonia. The impingers will be weighed to determine moisture gain in accordance with EP A Method 4. o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 16 Revision No: 0 Date: December I, 2007 Sample recovery will involve quantitative recovery of the sulfuric acid impinger contents, followed by three rinses with deionized, distilled water of the impingers and all connecting glassware. The back half of the filter holder and the connecting glassware to the first impinger will also be rinsed three times with deionized, distilled water. The impinger contents and rinses will be combined and sealed in a tare-weighed, precleaned glass sample container. The container will be labeled, and weighed to determine the final sample volume. The liquid level will be marked on the sample container. The sulfuric acid impinger solutions will be analyzed using ion chromatography techniques for chloride ions (Cr). Duplicate analyses will be performed on the samples and a reagent blank. Precision will be demonstrated by duplicate injection of each sample, the results of each individual analysis must be within 5 % of their mean to be acceptable. If the precision criteria is not met, analysis of the sample is repeated until consecutive injections meet the criteria. 2.9 PCDDs/PCDFs - EPA METHOD 23 Samples for PCDD/PCDFs will be withdrawn isokinetically from the source using an EP A Method 23 sampling train. Three 240 minute runs will be conducted. A field blank will be collected. The sampling train will consist of a glass-lined or Teflon-lined heat-traced probe with a glass button hook nozzle, and attached thermocouple and pitot tube. The probe will be maintained at a temperature of 248 OF + 250F. After leaving the probe, the sample gas will pass through a heated glass fiber fIlter (Reeve Angel 934 AH), a water-cooled condenser, and a sorbent module containing approximately 25 g of XAD-2 resin. The XAD module is followed by a series of five impingers. The XAD inlet temperature is monitored to ensure that the temperature of the flue gas sample entering the module is maintained below 20oC. This temperature will be maintained by continuously circulating ice-chilled water through the condenser jacket and the jacket on the XAD module. The first impinger, acting as a condensate reservoir, is connected to the outlet ofthe XAD module and is modified with a short stem so that the sample gas did not bubble through the collected condensate. The first and fourth impingers are empty, the second and third contained 100 mL of distilled water, and the fifth contains a known weight of silica gel. The impingers are weighed prior to assembling the sampling train to permit gravimetric moisture determination. All sample-exposed surfaces within the train will be made of glass or Teflon; no sealant greases will be used. The impingers are followed by a standard Method 5-type pump, dry gas meter, and calibrated orifice meter. The glassware is cleaned according to the procedure in Table 2.1. The filter and XAD will be predeaned for contamination according to procedures described in Method 23. o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 17 Revision No: 0 Date: December I, 2007 TABLE 2.2 PCDDs/PCDFs GLASSWARE CLEANING PROCEDURE I. Soak all glassware in hot, soapy water (AJconox). 2. Rinse with tap water, three times. 3. Rinse with deionized water, three times. 4. Rinse with pesticide grade acetone, three times. 5. Rinse with pesticide grade 50% MeCI2/50% Methanol, three times. 6. Bake at 4500F for 2 hours'. 7. Cap glassware with clean glass plugs; teflon tape or MeCl2-rinsed aluminum foil. 8. Leave cleaned glassware capped until field assembly. 'Step 4 not used for probe lines or non-glass (e.g., Teflon, nylon) components which cannot withstand 450oF. 2.9.1 PCDD/PCDF Sampling Procedures Sampling will be conducted isokinetically <.:t 10%) with readings of flue gas parameters recorded at traverse points selected according to EPA Method I. Leak-checks on the Method 23 sampling train are performed before and after each sampling run and for any port change. In the event that any portion of the train needed to be disassembled and reassembled (i.e., due to filter or resin changes), leak-checks are performed. The sampling train leak-checks and leakage rate (where applicable) are documented on the field test data sheet for each respective run. Allleak checks will be acceptable. Following each sampling run, the probes will be removed from the sampling train, the openings will be capped, and the sampling train returned to the sample recovery area. Blanks of reagents, XAD modules, and filters are collected. Reagent blanks of the recovery solvents are collected directly out of the dispensing bottles employed during sample recovery. All blank samples will be archived. Following completion of each test run, the Method 23 trains will be transported to the sample recovery area on site, out of the sunlight. The impingers and XAD-2 trap are weighed and final and initial weights are compared to determine moisture catch and the impinger contents are placed in a uniquely identified sample jar. Acetone followed by methylene chloride (MeC~) will be used to conduct the initial rinses of the sampling train (front half components only, including nozzle, probe and front half of filter holder). The same rinses are repeated in the back half components of the train up to but not including the XAD-2 trap and placed in a uniquely identified sample jar. These rinses are followed by a final toluene rinse (three times) which is kept separate from the rest of the sample fraction for analysis (this is performed on all but the impingers, up to the XAD-2 trap). All Method 23 samples will be stored at 40C until they are delivered to the laboratory for analysis. After all components are recovered/rinsed the following sample jars will be included/contained in a typical run recovery: o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 18 Revision No: 0 Date: December 1, 2007 Container 1 Container 2 Filter(s) Rinses of nozzle, probe and front half of the filter holder (acetone & MeClz) Rinses of the back half of the filter holder, transfer line (if used), and condenser (acetone & MeClz) Toluene rinse of the entire train up to the XAD-2 trap XAD-2 trap Container 3 Container 4 Container 5 2.9.2 PCDD/PCDF Sample Analysis The PCDD/PCDF train samples are analyzed for PCDD/PCDFs following EPA Method 23. The analysis of PCDD/PCDFs by high resolution gas chromatography coupled to high resolution mass spectrometry (HRGC/HRMS) involves highly specialized procedures that require a complex series of extraction and clean-up steps. These procedures are described in EP A Method 23. The actual analysis by HRGC/HRMS requires highly trained individuals and computerized data acquisition and data interpretation. To monitor the extraction, clean-up, and analysis of the PCDD/PCDFs, labeled internal standards are added to the field samples and laboratory blanks. One set of labeled internal standards as added for all the Soxhlet extraction steps and the recoveries of these standards is used to adjust the results. The specific internal standards, surrogate standards, alternative standards, and recovery standards that will be employed. Once the trace organic compounds are identified and confirmed by the procedures described above, the compounds will be quantified by comparison of the response factors of the sample analytes to the response factors of known amounts of native trace organic compound external standards. The recoveries of the internal standards, added to the Soxhlet extraction step, will be then used to adjust the results of the corresponding native PCDD/PCDF's (i.e., 13C12-2,3,7,8- TCDD recovery is used to adjust results for all native TCDD's and TCDF's). For validating analytical data, the extraction and cleanup system is demonstrated to be free of contamination. Method blanks and matrix blanks are analyzed. Once the trace organic compounds are identified and confirmed by the procedures 2.10 VISUAL EMISSIONS - EPA METHOD 9 The opacity of emissions from stationary sources will determined visually by a qualified observer. The qualified observer will stand at a distance sufficient to provide a clear view of the emissions with the sun oriented in the 1400 sector to the observer's back. Consistent with maintaining the above requirement, the observer will, as much as possible, make observations from a position such that the observer's line of vision is approximately perpendicular to the plume direction and, when observing opacity of emissions from rectangular outlets (e.g., roof monitors, open baghouses, noncircular stacks), approximately perpendicular to the longer axis of the outlet. The observer's line of sight should not include more than one plume at a time when multiple stacks c /\ V c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 19 Revision No: 0 Date: December I, 2007 are involved, and in any case the observer will make his observations with a line of sight perpendicular to the longer axis of such a set of multiple stacks (e.g., stub stacks on baghouses). Opacity observations will be made at the point of greatest opacity in that portion of the plume where condensed water vapor is not present. The observer will not look continuously at the plume but instead shall observe the plume momentarily at 15-second intervals. When condensed water vapor is present within the plume as it emerges from the emission outlet, opacity observations will be made beyond the point in the plume at which condensed water vapor is no longer visible. The observer will record the approximate distance from the emission outlet to the point in the plume at which the observations are made. When water vapor in the plume condenses and becomes visible at a distinct distance from the emission outlet, the opacity of emissions will be evaluated at the emission outlet prior to the condensation of water vapor and the formation of the steam plume. Opacity observations will be recorded to the nearest 5 percent at 15-second intervals on an observational record sheet. A minimum of 24 observations will be recorded. Each momentary observation recorded will be deemed to represent the average opacity of emissions for a 15-second period. The observations recorded on the record sheet will be divided into sets of 24 consecutive observations. For each set of 24 observations, the average will be calculated by summing the opacity of the 24 observations and dividing this sum by 24. 2,11 VISIBLE FUGITIVE EMISSIONS - EPA METHOD 22 Visible fugitive emissions will be monitored using EPA Method 22. Method 22 uses an observer to determine the presence of visible fugitive emissions. The observer uses two stopwatches, one to measure the total time of the test, and the second to record the amount of time during the test when visible emissions are present. The observer is not to observe for periods of more than 20 minutes without taking a rest break. (EPA Method 22, section 5.4.2). 2,12 EQUIPMENT DEECO has sufficient equipment to have all the sampling trains prepared prior to the start of each day's testing. DEECO also has sufficient spares of other sample boxes and other equipment to ensure that there are no extended delays due to sampling equipment malfunctions and waiting for sample trains to be recovered. D EECO will supply all required equipment and supplies including standard safety gear (hard hats, safety glasses, and steel-toe boots). o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 20 Revision No: 0 Date: December I, 2007 SECTION 3. EMISSION TESTING PROGRAM PHASES This program has five tasks I) Site visit and review protocol, 2) Engineering Testing, 3) Compliance Test,4) Analytical Testings, and 5) Test Coordination. As shown in the company experiences in Section 9, DEECO has conducted numerous tests with similiar scopes of work. These responsibilities, timing and goals of these phases are discussed below: 3.1 Task 1 Compliance Test Protocol Development. A final test protocol will be developed within two days the site visit. Mr. Bill DeWees will attend a pretest at the facility to review the protocol. In the past, DEECO has conducted testing at fifteen different MWC facilities. 3.2 Task 2 Engineering Test (see Tables 1.4) will be conducted on one boiler. DEECO has six specially designed trailers. For this task, an Air Toxic Recovery trailer will be brought on-site. DEECO will conduct on-site analysis for HCI. 3.3 Task 3 Compliance Test (see Tables 1.2, 1.2A and 1.2B) will be conducted on three boiler trains in accordance with the methods and scope shown in Table 1.1. DEECO has six specially designed trailers. For this task, an Air Toxic Recovery trailer will be brought on-sitiEECO will conduct on-site analysis for HCI. The reporting requirements are discussed in greater detail in Section 6. Critical sampling parameters, such as volumetric flowrate, gas stream moisture, isokinetic sampling rates, oxygen content and carbon dioxide content, will be calculated following each test run, and provided to WASTEC on-site. DEECO will not leave the site with unacceptable sample runs. Testing will be conducted with a field staff of nine and a recovery trailer. The Project Manager and On-site Coordinator will likely be Mr. Bill DeWees. 3.4 Task 5 Report Development (see Table 1.6) a complete written summary report of all stack testing activities and results will be prepared and provided to W ASTEC in a timely manner, not to exceed 45 days, following each compliance stack testing event. 3.5 Test Coordination Mr. Paul Marlow will serve as test coordinator. He will be responsible for: 1. Scheduling the start of all testing 2. Principal contact with the agency officials concerning the tests 3. Principal contact with DEECO concerning the tests 4. Recording the process data during the testing 5. Providing copies of any field test data to the agency If there is a temporary equipment malfunction in the middle of a test, radio contact will be made with the test crew in order to delay the test. When problems have been corrected, the test will continue from the point where it was delayed. o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 21 Revision No: 0 Date: December 1, 2007 The following are typical examples of mechanical failures which will be considered valid reasons for delaying the testing: 1. Crane outage 2. Fan outage 3. Plugged spray dryer absorber atomizer 4. Broken grate block 5. Plugged feed chute 6. Plugged ash conveyor system 7. Turbine trip 8. Hydraulic failure of stoker equipment 9. Fabric filter failure 10. Carbon injection system upset 11. Other identified process upsets o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 22 Revision No: 0 Date: December 1,2007 SECTION 4. QUALITY ASSURANCE AND QUALITY CONTROL The quality assurance and quality control is divided into three areas (I) Quality Assurance Program Organization and Responsibility, (2) Sample Custody, and (3) Internal Quality Control Checks. Each is described below. 4.1 QUALITY ASSURANCE PROGRAM ORGANIZATION AND RESPONSIBILITY This section provides information regarding the organization of the sampling and analytical program. The following details the key positions and their responsibilities. Once personnel have been assigned to these positions, their qualifications will be provided as an addendum. The organization of the project team, including QA functions, is shown in the project organization chart (see Figure 4.1). Note that the QA structure is independent of the organizational groups who will generate environmental measurement data during this project. 4.1.1 PROJECT DIRECTOR The Project Director (PD) oversees the Project Manager's test program planning, organization and performance. He also assists in technical supervision and oversees protocol development and review, data interpretation, and report preparation. The Project Director for this project will be Dr. Scott Steinsberger. 4.1.2 PROJECT MANAGER The Project Manager (PM) supervises the planning, oversight and review functions associated with the various elements of the test program. Mr. Bill DeWees will be the Project Manager and On-site Coordinator. 4.1.3 PROJECT QUALITY ASSURANCE MANAGER The Quality Assurance Manager (QAM) has the primary responsibility for ensuring that all reported data meet the QA objectives associated with the measurement project. The QAM is independent of project management. o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 23 Revision No: 0 Date: December 1,2007 Project ---------------------------, Director I I I I I I I I I I ! Project -------------- Project Quality Manager Assurance Manager I I I I I I I ,..------------------,--- ______________,__________________J I I I I I I I i I I I I I I I ! i Field Data Report Sample Operations Task Manager Coordinator Manager I DEECO Contract Field Staff Report Staff Laboratory Laboratory Staff Staff Management Lines of Authority Quality Assurance Lines of Authority Figure 4.1 Project organizational chart. o I' V o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 24 Revision No: 0 Date: December 1, 2007 The QAM will provide supervision of all technical aspects of the work effort, which includes but is not limited to, method development, sample analysis, interpretation of test results, and preparation of the final report. The QAM's responsibilities include (1) the review of QA project plans and (2) oversight of QA consideration of field testing projects. During the course of data reduction and report writing, he will audit data quality, inspect field data, raw analysis data, project records and reported QC data. He will develop an independent data quality assessment for inclusion in the test report. If problems arise which have the potential to adversely affect data, he will make recommendations to the project manager, and higher management levels as necessary, to ensure that appropriate corrective actions are taken. 4.1.4 FIELD OPERATIONS COORDINATOR The Field Operations Coordinator's responsibilities include scheduling, coordination of sampling tasks, and support for the sampling teams while they are in the field. The Field Operations Coordinator works together with project managers, equipment and laboratory managers in an effort to identify and eliminate potential.problems that could occur during the test program. He also coordinates changes in the scope of work that develop while in the field. He serves as support should any questions, problems or situations arise which would require the assistance of the home office in the form of equipment, personnel, or technical information. The field operation coordinator will be Mr. Bill DeWees. 4.1.5 SAMPLE MANAGER The Sample Manager supervises the process sampling and insures that all samples are properly labeled and shipped to the appropriate laboratory with necessary tracking documents. The sample recovery and sample management will be handled by Mr. Matt Winkeler. 4.1.6 DATA REPORT TASK MANAGER Data reduction and report preparation will be performed by the data report task manager. He is responsible for the management of the report progress. After the field data has been reduced and analytical results have been evaluated, he will calculate the pollutant concentrations and emission rates and present them in a report that meets guidelines established by the EP A and state agency. Mr. Marc Hamilton will be Report Manager. Mr. Hamilton has written more than fifty MWC compliance report over the past nine years. 4.2 SAMPLE CUSTODY Sample custody procedures for this program are based on EPA recommended procedures. Since samples will be analyzed by one or more laboratories as well as in the field, the custody procedures emphasize careful documentation of sample collection and field analytical data and the use of chain of custody records for samples being transported. The procedures which will be used are discussed below. o c c Air Emissions Compliance Test Program New Hanover County Dept of Enviromnental Management Wilmington, NC Page: 25 Revision No: 0 Date: December 1, 2007 4.3 FIELD SAMPLING OPERATIONS The project manager will be responsible for ensuring that proper custody and documentation procedures are followed for the field sampling and field analytical efforts. He will be assisted in this effort by key sampling personnel involved in sampling recovery. Samples will be collected, transported, and stored in clean containers which are constructed of materials inert to the analytical matrix such as glass jars. Only containers which allow air tight seals will be used. Amber glass jars will be employed when containers are needed to inhibit photochemical reactions. All sampling data, including information regarding sampling times, locations, and any specific considerations associated with sample acquisition will be recorded on preformatted data sheets. An example field sampling data form for an isokinetic type sampling train is shown in Figure 4.2. An example sample recovery data form for an isokinetic type sampling train is shown in Figure 4.3. Following sample collection, all samples will be given a unique alphanumeric sample identification code as shown in Figure 4.4. Actual sample code could vary slightly depending upon sample location and type. Figure 4.5 is the chain of custody sheet which will accompany all isokinetic type reagent boxes used during the testing program and process samples that are collected during testing. The chain of custody forms will be completed for each shipment box. The chain of custody forms and a letter specifying the treatment of each sample will also be enclosed in the sample shipment container. Samples to be combined and analyzed immediately, extracted and stored for later analysis, or simply stored as is, will be clearly stated in this letter. The purpose of the letter will be to ensure that the correct samples are combined, that samples containing moisture will be analyzed on an as-received basis, and that samples with a limited shelf life (those containing water) are extracted within the allowable time of 7 to 10 days after collection. Samples will be stored for transport from the lab to the field to the lab in storage boxes constructed in a fashion which minimizes movement and thus prevents breakage of containers. For example, boxes used for transporting glass containers will have foam inserts with form-fitting cutouts. Sample transport boxes will be locked except when in use. Vans containing equipment and samples will be locked whenever they are left unattended. Air Emissions Compliance Test Program Page: 26 New Hanover County Dept of Environmental Management Revision No: 0 Wilmington, NC Date: December 1,2007 C Sampling Sample Facility Location Type Run Number Sample Fraction W ASTEC Inlet M29HG Run I FHAR Wilmington, NC Run 2 PF Unit 3 Run 3 5%/10% BHAR KMn04 HCL M26A Run I H2SO4 Run 2 Run 3 W ASTEC Outlet M29HG Run 1 FHAR Wilmington, NC Run 2 PF Unit 3 Run 3 5%/10% BHAR KMn04 HCL C M26A Run 1 H2SO4 Run 2 Run 3 M5129 Run I FHAC Run 2 FHAR Run 3 PF 5%/10% M23 Run 1 FHSOL Run 2 XAD Run 3 CON/SOL Example for Unit 3, Inlet Stack Sample, Method 29 for mercury, Front Half Acid Rinse Unit 3-Inlet-M29HG-RI-FHAR Figure 4.4 Alphanumeric sample identification number. c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 27 Revision No: 0 Date: December I, 2007 c A daily activity log will be maintained by the project supervisor. This will be an informal log used to record various types of information, such as minor problems which arise, sketches of sampling locations, names and phone numbers of plant contacts. daily activity summaries, etc, 4.4 ANALYTICAL OPERATIONS Analytical operations will be performed on-site in the laboratory as well as in the remote laboratories. The analytical data form to be used for on-site fixed gas (molecular weight) determinations using Orsat analyzer is shown in Figure 4.6, Samples analyzed by outside laboratories are transported with a Chain-of-Custody form as shown in 4.5, This form will list sample identifications, analytical parameters, sample matrices, anticipated date of results, and other relevant information necessary to ensure the appropriate analyses are performed and to document the progress of the samples. 4.5 INTERNAL QUALITY CONTROL CHECKS Specific quality control (QC) procedures will be followed to ensure the continuous production of useful and valid data throughout the course of this test program. The QC checks and procedures described in this section represent an integral part of the overall sampling and analytical scheme. Strict adherence to prescribed procedures is quite often the most applicable QC check. A discussion of both the sampling and analytical QC checks that will be utilized during this C program is presented below. 4.5.1 EQUIPMENT INSPECTION AND MAINTENANCE Each item of field test equipment will be assigned a unique, permanent identification number. An effective preventative maintenance program is necessary to ensure data quality. Each item of equipment returning from the field will be inspected before it is returned to storage. During the course of these inspections, items are cleaned, repaired, reconditioned, and recalibrated where necessary. Each item of equipment transported to the field for this test program will be inspected again before being packed to detect equipment problems which may originate during periods of storage. This minimizes lost time on the job site due to equipment failure. Occasional equipment failure in the field is unavoidable despite the most rigorous inspection and maintenance procedures. For this reason, replacement equipment for all critical sampling train components will be transported to the job site. c o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 28 Revision No: 0 Date: December 1, 2007 4.5.2 EQUIPMENT CALIBRATION New items for which calibration is required will be calibrated before initial field use. Equipment whose calibration status may change with use or time will be inspected in the field before testing begins and again upon return from each field use. When an item of equipment is found to be out of calibration, it will be repaired and recalibrated or retired from service. All equipment will be periodically recalibrated in full, regardless of the outcome of these regular inspections . Calibrations will be conducted in a manner, and at a frequency, which meets or exceeds U.S. EPA specifications. The calibration procedures outlined in the EPA Methods will be followed. When these methods are inapplicable, methods such as those prescribed by the American Society for Testing Materials (ASTM) will be used. Data obtained during calibrations will be recorded on standardized forms, which will be checked for completeness and accuracy by the quality assurance manager. Data reduction and subsequent calculations will be performed using computer facilities. Calculations will be checked at least twice for accuracy. Copies of calibration forms will be included in the test or projects reports. Emissions sampling equipment requiring calibration includes pitot tubes, pressure gauges, thermometers, dry gas meters and barometers. The following sections elaborate on the calibration procedures to be followed for these items of equipment. A: Pitot Tubes. All Type S pitot tubes used, whether separate or attached to a sampling probe, will be constructed in-house or by Apex Corporation, Each new pitot will be calibrated in accordance with the geometry standards contained in EP A Method 2. A Type S pitot tube, constructed and positioned according to these standards, will have a coefficient of 0.84 :t 0.02. This coefficient should not change as long as the pitot tube is not damaged. Each pitot tube will be inspected visually upon return from the field. If a cursory inspection indicates damage or raises doubt that the pitot remains in accordance with the EP A geometry standards, the pitot tube will be refurbished as needed and recalibrated. B: Differential Pressure Gauge. All meter consoles used are equipped with lO-inch water column (W.C.) inclined-vertical manometers. Fluid manometers do not require calibration other than leak checks. Manometers will be leak checked in the field prior to each test series, and again upon return from the field. c c c Air Emissions Compliance Test Program New Hanover County Dept of Enviromnental Management Wilmington, NC Page: 29 Revision No: 0 Date: December 1, 2007 C: Impinger Thermometer. Prior to the start of testing, the thermometer used to monitor the temperature of the gas leaving the last impinger will be compared with a mercury-in-glass thermometer which meets ASTM E-I No. 63F specifications. The impinger thermometer is adjusted if necessary until is agrees within 20F of the reference thermometer. If the thermometer is not adjustable, it is labeled with a correction factor. D: Dry Gas Meter Thermometer. The thermometer used to measure the temperature of the metered gas sample will be checked prior to each field trip against an ASTM mercury-in-glass thermometer. The dry gas meter thermometer is acceptable if the values agree within :t 5.40F. Thermometers not meeting this requirements will be adjusted or labeled with a correction factor. E: Flue Gas Temperature Sensor. All thermocouples employed for the measurement of flue gas temperature are calibrated upon receipt. Initial calibrations will be performed at three points (ice bath, boiling water, and hot oil), An ASTM mercury- in-glass thermometer will be used as a reference. The thermocouple is acceptable if the agreement is within 1.5 percent (absolute) at each of the three calibration points. Before and after each field use, the reading from the flue gas thermocouple- potentiometer combination will be compared with an ASTM mercury-in-glass reference thermometer at ambient conditions. If the two agree within :t 1.5 percent (absolute), the thermocouple and potentiometer are considered to be in proper working order. F: Dry Gas Meter and Orifice. Two procedures will be used to calibrate the dry gas meter and orifice simultaneously. The full calibration will be a complete laboratory procedure used to obtain the calibration factor of the dry gas meter. Full calibrations will be performed over a wide range of orifice settings. A simpler procedure, the pOSHest calibration, will be designed to check whether the calibration factor has changed. PosHest calibrations will be performed after each field test series at an intermediate orifice setting (based on the test data) and at the maximum vacuum reached during the test. A dry gas meter that is calibrated annually against a spirometer will be used as a transfer standard. During the annual calibration, triplicate calibration runs will be performed at seven flow rates ranging from 0.25 to 1.40 cfm. o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 30 Revision No: 0 Date: December I, 2007 G: Dry Gas Meter. Each metering system receives a full calibration at the time of purchase and a post-test calibration after each field use. If the calibration factor,y, deviates by less than five percent form the initial value, the test data are acceptable. If y deviates by more than 5 percent, the meter is recalibrated and the meter coefficient (initial or recalibrated) that yields the lowest sample volume for the test runs is used. EP A Method 5 requires another full calibration anytime the post-test calibration check indicates that y changed by more than 5 percent. Standard practice is to adjust and recalibrate the dry gas meter anytime y is found to be outside the range of 0.97 to 1.03. H: Orifice. An orifice calibration factor will be calculated for each flow setting during a full calibration. Ifthe range of values does not vary by more than 0.15 in H 20 over the range of 0.4 to 4.0 in H20, the arithmetic average of the values obtained during the calibration is used. I: Barometer. Each field barometer will be adjusted before each test series to agree within :t 0.1 inches of a reference aneroid barometer. The reference barometer will be checked against the station pressure value (corrected for elevation difference) reported by the National Weather Service. 4.5.3 SAMPLING QUALITY CONTROL PROCEDURES .The following pretest QC checks will be conducted: . All sampling equipment will be thoroughly checked to ensure clean and operable components. Equipment will be inspected for possible damage from shipment. The oil manometer or Magnehelic gauge used to measure pressure across the Type S pitot tube will be leveled and zeroed. The number and location of the sampling traverse points will be checked before taking measurements. The temperature measurement system will be visually checked for damage and operability by measuring the ambient temperature prior to each traverse. . . . . In addition to the general QC procedures listed above, QC procedures specific to each sampling method will also be incorporated into the sampling scheme. These methods and specific procedures are discussed below. o Air Emissions Compliance Test Program New Hanover County Dept of Enviromnental Management Wilmington, NC Page: 31 Revision No: 0 Date: December 1, 2007 A: Sampling Train QC checks. The following QC procedures will be emphasized: c . . . . . . . . . . . . C Prior to Start of Tests · Keep all cleaned glassware and sample train components sealed until train assembly. · Assemble the sampling trains in an enviromnent free from uncontrolled dust. · Visually inspect each sampling train for proper assembly. · Perform pretest calculations to determine the proper sampling nozzle size. Prior to Testing Each Day · Visually inspect the sampling nozzle. · Visually inspect the Type S pitot tube. · Leak check each leg of the Type S pitot tube. · Leak check the entire sampling train. During Testing Each Day Readings of te.mperature and differential pressure will be taken at each transverse point. All sampling data and calculations will be recorded on preformatted data sheets. All calibration data forms will be reviewed for completeness and accuracy. Any usual occurrences will be noted during each run on the appropriate data form. The project supervisor will review sampling data sheets daily during testing. Properly maintain the roll and pitch axis of the Type S pitot tube and the sampling nozzle. Leak check the train before and after any move from one sampling port to another during a run or if a filter change takes place. Conduct additional leak checks if the sampling time exceeds 4 hours. Maintain the probe, filter, and impingers at the proper temperatures. Maintain ice in the ice bath at all times. Make proper readings of the dry gas meter, delta P and delta H, temperature, and pump vacuum during sampling at each traverse point. Maintain isokinetic sampling within :I: 10% of 100%. c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 32 Revision No: 0 Date: December 1, 2007 After Testing Each Day · Visually inspect the sampling nozzle. · Visually inspect the Type S pitot tube. · Leak check each leg of the Type S pitot tube. · Leak check the entire sampling train. B: QC for Volumetric air flow rate determinations Flue Gas Velocity. Data required to determine the flue gas velocity will be collected using the methodology specified in EPA Method 2. Quality control procedures are as follows. · Visually inspect the Type S pitot tube before and after sampling. · Leak check both legs of the pitot tube before and after sampling. · Check the number and location of the sampling traverse points before taking measurements. Flue Gas Molecular Weight. Samples to be used for determination of flue gas molecular weight will be collected using the integrated sampling technique specified in EPA Method 3. Quality control will focus on the following procedures: · The sampling train will be leak checked before and after each run. . A constant sampling rate will be used in withdrawing a sample. . The sampling train will be purged prior to sample collection. · The sampling port will be properly sealed to prevent air in-leakage. Moisture Content. The moisture content of the gas stream will be determined using the technique specified in EPA Method 4. The following QC checks will be performed: . The sampling train will be leak checked before and after each run. . Ice will be maintained in the ice bath throughout each run. c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 33 Revision No: 0 Date: December I, 2007 4.5.4 ANALYTICAL QUALITY CONTROL PROCEDURES All analyses for this program will be performed using accepted laboratory procedures in accordance with the specified analytical protocols. Adherence to prescribed QC procedures will ensure data of consistent and measurable quality. Analytical QC will focus upon the use of control standards to provide a measure of analytical precision and accuracy. Also, specific acceptance criteria are defmed for various analytical operations including calibrations, control standard analyses, drift checks, blanks, etc. The following general QC procedures will be incorporated into the analytical effort: . The on-site project manager will review all analytical data and QC data on a daily basis for completeness and acceptability , Analytical QC data will be tabulated using the appropriate charts and forms on a daily basis Copies of the QC data tabulation will be submitted to the quality assurance manager following the completion of the test program. All hard copy raw data (i.e., chromatograms, computer printouts, etc.) will be maintained in organized files. . . . Specific analytical QC procedures for the Orsat analyzer are listed below. . The analyzer will be leveled and the fluid levels zeroed prior to use. · The analyzer will be leak checked prior to use. . The analyzer will be thoroughly purged with sample prior to use. . The analyzer will be checked by analyzing an ambient air sample. Particulate Matter Sample Analysis QC Checks are listed below. . Particulate matter collected with the PM/Method 29 sampling train will be determined gravimetrically. The acetone will be evaporated in a tare- weighed beaker to dryness. Both the filter and the acetone residue will be desiccated to a constant weight. Constant weight is defined as no more than 0.5 mg or 1% of the total weight less tare weight, whichever is less, between two consecutive weighings, with no less than 6 hours of desiccation time between weighings. . The analytical balance must be checked against Class-S standard weights, and should agree within 2 mg. c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 34 Revision No: 0 Date: December I, 2007 Multiple Metals Sample Analysis QC Checks are listed below. . The multiple metals emission samples will be prepared for Cd, and Pb analysis by acid digestion. For cadmium and lead, the front half components of the train will be measured by FLAA and the back half components will be measured by GFAA. Hg in the emission samples will be analyzed by Cold Vapor Atomic Absorption Spectroscopy (CV AAS). After evaporation of the acetone rinse, the probe rinse and particulate filter will be subjected to microwave HNO /HF digestion in a pressure relief vessel. The combined nitric acid/hydrogen peroxide impinger solution and nitric acid rinse of the impingers will be reduced to near dryness and digested with HN03. Finally the front and back half digestates will be combined and analyzed for the target metals. The GF AA, FLAA, and CV AA will be calibrated with three series of five standard solutions containing the target metals ranging in concentration from o to 100 ILg/mL (depending on the element). A calibration check sample will be analyzed with every 10 samples. A reagent blank will be carried through the procedure and analyzed with the field samples. Precision of the metals analyses will be demonstrated by duplicate analysis of all the stack gas samples, with a RPD of 35% considered acceptable. Accuracy of the metals analyses will be demonstrated by spikes of each type of sample matrix. Spike recoveries must be between 70% and 130% to be acceptable. A PEA, consisting of a spiked filter, will be analyzed for metals if provided by the regulatory agency. . . . . . . . The minimum amount of quality control samples is presented in Table 4.1. Full quality control measures will be implemented for the data generated. The objective of a quality assurance/quality control (QA/Qc) program is to assure that the precision and accuracy of all environmental data generated by DEECO, Inc. for clients are commensurate with data quality objectives (DQO' s). DQO' s are based on a common understanding of the intended end use(s) of the data, the measurement process, and the availability ofresources. Once DQO's are established, formally or informally, QC protocol can be defined for the measurements. o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 35 Revision No: 0 Date: December I, 2007 4.6 QUALITY OBJECTIVES In this project, the final data user will be WASTEC. The data quality objectives in this project are to generate scientifically sound data to be used for compliance the Air Quality Permit. All of the equipment to be used will be calibrated according to the procedures outlined in the Oualitv Assurance Handbook for Air Pollution Measurement Svstems, Volume III, EP A -600/4- 77-027b. Specific quality control (QC) procedures will be followed to ensure the continuous production of useful and valid data throughout the course of this test program. The QC checks and procedures described in this section represent an integral part of the overall sampling and analytical scheme. Strict adherence to prescribed procedures is quite often the most applicable QC check. All analyses for this program will be performed using accepted laboratory procedures in accordance with the specified analytical protocols. Adherence to prescribed QC procedures will ensure data of consistent and measurable quality. Analytical QC will focus upon the use of control standards to provide a measure of analytical precision and accuracy. Also, specific acceptance criteria are defined for various analytical operations including calibrations, control standard analyses, drift checks, blanks, etc. Care will be exercised to ensure hand recorded data is written accurately and legibly. Additionally, the use of prepared data recording forms, conveniently formatted, is an important aid to verify that all necessary data items are recorded. The collected field and laboratory data will be reviewed by the analyst and the Project Manager. The Project Manager will reduce and validate all of the sampling and analytical data that is collected. The sampling data will include flow measurements, calibrations, etc. Each laboratory will reduce all analytical results prior to their submission to the Project Manager. The analytical data will be used to determine concentrations and emission rates of the compounds of interest. Data reduction follows guidelines published in EPA Reference Methods, where applicable, and by guideline documents where EP A Reference Methods are not available. Validated computer programs will be used to calculate all reported values. A second technical review of the data will be performed and documented by a qualified scientist other than the one who performed the actual analyses. The second reviewer will include evidence (e.g., check marks, recalculations, etc.) that show which data points were checked. o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 36 Revision No: 0 Date: December 1, 2007 Finally, the second reviewer will sign and date the cover page of the data packet or the record that was reviewed. In-situ measurements will be validated by demonstrated acceptable post -test leak checks and calibration verifications according to the reference method used. Analysis data may be validated according to defined criteria by a secondary reviewer or by the analyst. At a minimum, analysis data will be validated according to the following criteria (additional method-specific criteria or project requirements may apply): Sampling records complete and traceable All appropriate QC samples included with the analytical batch and reported with the sample results Routine tuning, calibration and inspection of analytical instrumentation documented and performed prior to analyses Initial and continuing calibration criteria met Methodlreagent blanks confirm no background contamination Surrogate recoveries within criteria Qualitative sample results (e.g., retention times, mass spectra, isotopic ratios) consistent with standard data Sample data within the calibrated range of the instrument Chromatograms or other raw data consistent with computer-generated quantitation reports Accuracy of intermediate data manipulations, transcribed numbers and/or final reported results verified Reference standards, instrumentation, sample identification, analysts, methodology, and sequence of processing clearly identified and traceable in the project records Lost data or corrective actions documented (e.g., loss of sample, reanalysis, redilutions, additional cleanup steps, alternative calculations etc.) a o o o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 37 Revision No: 0 Date: December 1, 2007 Data that does not meet the validation requirements flagged accordingly Data reported in the correct units (e.g., "ppm" should not be used without specifying volume or mass units; "ug/g" are preferred units for data reporting) The results will be presented in a format which meets the requirements of the USEPA Reporting Requirements. The results will be calculated and reported according to acceptable procedures and protocols. Data for all trial burn runs will be reported in the trial burn results. Any data that is not acceptable because of technical difficulties will be indicated, and an explanation of the technical problem will be given. All related QC and calibration data will be in the final report. Additional reporting requirements and project deliverables required for the final report will include the following items: Results of all quality control analyses, including spikes, replicates and performance check/evaluation samples. Spiked sample data will include nanograms applied and nanograms recovered, as well as percent recovery data, Results of all surrogate compound analyses including quanttttes applied and recovered from every program sample. Percent recovery data for the surrogate compound will also be provided. Results of all of the daily performance check samples pertinent to the set of samples submitted for analysis. The performance check solution and the calibration solution data are needed to demonstrate GC/MS resolution, sensitivity, response factor reproducibility and mass range calibration. Copies of actual selected ion current profiles (SICPs) and raw and background subtracted spectra pertinent to each sample. Copies of all calibrant response-factor calculations, plotted concentration calibration curves and computer-derived quantitation reports. A chronological list of all analyses performed, including the data system file name, sample number for each sample, blank, concentration calibration solution and performance check solution. This will include all labeled peaks, as well as the internal standard and surrogate. o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 38 Revision No: 0 Date: December 1,2007 The document control and sample custody package which includes sample tags, custody records, sample tracking records, analyst log book pages, computer printouts, raw data summaries and instrument log book pages. Narrative reports for analyses to indicate methods used, example calculations, modifications and any problem encountered during the analyses that may not be evident in the data files. Complete inventory of sample identifications and type of sample which were collected and analyzed. Holding times for extraction and analysis of samples. QC summary tables (e.g., surrogate recoveries, precision and accuracy of spiked samples, blank results, calibration results, etc.). Summary of audits conducted and results. Validation criteria and procedures used during technical review of the data. Procedures and equations used for calculating MDL (especially those used to derive regulatory emission values). MDL procedures will also be consistent with SW-846 current revision. Flags and explanations of all data which failed one or more QC criteria (e. g., low surrogate recoveries or high blank values, etc.). Copies of the test report will be submitted after the test series has been completed. Results reported will include, but not be limited to emission rates and concentrations of particulates and gaseous pollutants determinations, and any other type of data requested. This report will also include a list of all personnel present during testing, summary results, descriptions of test procedures used, a description of the source and its operation during testing, test locations drawings, example calculations, raw field data, copies of test methods used during the test series and equipment calibrations. c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 39 Revision No: 0 Date: December 1, 2007 TABLE 4.1 QUALITY CONTROL SAMPLES Parameter Matrix Blanks Matrix Spike/Matrix Spike Duplicate Metals Stack Gas Reagent Blank Matrix Spike! Duplicate Analysis Mercury Stack Gas Reagent Blank One Matrix Spike Duplicate Analysis on all runs2 Dioxin/Furans Stack Gas Field Blank Surrogate Spike HCI Stack Gas Reagent Blank One Matrix Spike Duplicates on all runs ! - If matrix recovery < 75 % or > 125 %, reanalyze using Method of Standard Additions. 2 _ Results must be + 25 %, if not, then use Method of Standard Addition c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 40 Revision No: 0 Date: December 1, 2007 SECTION 5. TESTING SCHEDULE The test schedule requirements of the Emissions Compliance Test Program are shown below. It is understood that revisions to the schedule may be necessary in the field. Any changes to the schedule must be approved in advance. Task I - Site Visit and Review Test Protocol Finalize Protocol Two days after site visit Task 2 - Engineering Test on one unit Testing - Mutually agreeable date Task 3- Compliance Test on three units Testing - Mutually agreeable date Task 4 - Conduct Audit Sample Analysis C Analyses Conducted at the same time as compliance test samples Task 5 - Compliance Test Report Draft Test Report Due - Final Test Report Due - 45 days after testing 2 days after receiving comments c c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 41 Revision No: 0 Date: December I, 2007 SECTION 6. REPORTING Critical sampling parameters, such as volumetric flowrate, gas stream moisture, oxygen content, carbon dioxide content, and isokinetic sampling rates, will be calculated following each test run, and can be provided to W ASTEC on-site. DEECO will not leave the site with unacceptable sample runs. Draft Test Report - The draft report will be delivered to W ASTEC within the specified time from the completion of the stack testing. The delivery time is presented in the Section 6. The specified number of report copies will be delivered to Paul Marlow. The report format will be acceptable to W ASTEC and NC DAQ. Typically DEECO has been using the previously approved report with any changes recommended by the facility. Final Test Report - The final report will be delivered to W ASTEC within 2 days after receiving comments. The specified number ofreport copies will be distributed to Paul Marlow. c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 42 Revision No: 0 Date: December 1,2007 SECTION 7. UTILITIES AND OTHER REQUIREMENTS OF FACILITY DEECO requirements are presented below: PLANT ENTRY Client wiJI provide prompt clearance of DEE CO personnel, vehicles, and equipment through plant security for ingress and egress. PROCESS MALFUNCTIONS Client will provide consistent process operations for the duration of each test. If the test team arrives on site and the testing cannot be conducted during scheduled hours on the scheduled day(s) because of Client's process or equipment malfunctions, the Client wiJI be biJIed to cover the additional time and materials needed to complete the testing program. If the Client's process or equipment problems cause a significant delay in the test program that would interfere with DEECO's previously scheduled work, the test program may have to be interrupted and completed at a later date. The client may incur additional costs when these situations occur. CONFIDENTIALITY DEECO will maintain the strictest confidentiality on all information considered by the Client to be Company Confidential Information. All test results wiJI be submitted only to the client, unless otherwise directed. It will be the responsibility of the Client to submit test results to the regulatory agency. Any discussions of the testing and/or results between DEECO and the regulatory agency wiJI be held only with the approval of, or in the presence of, the Client or designated representative. SAMPLING PORTS Client will provide unobstructed sampling ports through which DEECO can gain access to gas ducts. For particulate sampling, a minimum 3-inch opening is required at locations specified by the DEECO Project Manger (particle sizing requires 4-6 inch ports). UTILITIES Electrical power requirement for testing is at least four 20-amp 120-volt circuits within 50 feet of the sampling location and a 220-volt, 100 amp, or 440-volt, single phase, 50-amp electrical for the Recovery Trailer and for the CEMs trailer. o c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 43 Revision No: 0 Date: December 1, 2007 PERSONNEL SAFETY Client will provide safe working conditions for DEECO personnel in accordance with OSHA General Industry and Construction Standards. This includes but is not limited to: a. Written emergency procedures to be followed in the event of accident or injury to DEECO personnel. Procedures shall include instruction for notifying plant emergency and management personnel on site, and phone numbers for local life squad, hospital, physician, and fire department. Any emergency treatment facility on site shall be promptly made available to any DEECO employee requiring medical attention. b. Secured ladders, stairways, or other approved means to gain access to working platforms. c. Approved, rigid working platforms for DEECO personnel and equipment. Working platforms shall support, without failure, at least four times the maximum intended load of 800 pounds. Working platforms, rooftops, and access routes shall be cleaned of any foreign debris (ice, snow, dust, etc. ) that could cause unsafe conditions. d. Fall protection devices such as guardrail's, cages for ladders, safety harnesses, etc. e. Working area where no imminent danger from fIanunable or explosive materials exist. f. The plant is responsible for supplying the DEECO sampling team with any available information on hazardous conditions that exist in the work area such as toxic chemicals, excessive noise levels, heat stress conditions, etc. DEECO reserves the right to postpone testing to obtain appropriate sampling equipment when conditions differ significantly from any information given prior to arrival on site, and to obtain the appropriate safety equipment if it is not available. g. Working areas where the oxygen concentration is above 20.0 percent by volume, or approved breathing equipment. h. Personal protection equipment (other than hard hats, safety glasses, and safety shoes) for all DEECO personnel, when required to ensure personnel protection. I. Electrical and mechanical lockout procedures for all areas that DEECO personnel are required to enter, if such areas could cause health or safety hazards. j. Valid safe operating permits for elevators or other mechanical devices that will be used to transport DEECO personnel and/or equipment to the work platform(s). c c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 44 Revision No: 0 Date: December 1, 2007 Note: DEECO personnel will not make any confined space entries. INCLEMENT WEATHER DEECO will waive its inclement weather policy for WASTEC. DAMAGE TO CLIENT'S FACILITIES DEECO will not be held responsible for normal wear and tear to roofs, gutters, loaned equipment, etc., as the result of the sampling team's work. Every precaution will be taken by the sampling team to protect the client's facilities. A Certificate ofInsurance will be provided upon request. The limits of DEECO' s coverage are one million dollars per occurrence with a six million dollar aggregate. DAMAGE TO DEECO TEST EQUIPMENT Cost incurred due to damage of test equipment at the fault of the client or client's contractor will be billed as an extra item to the client. c c o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 45 Revision No: 0 Date: December 1, 2007 SECTION 8. PROJECT COSTS The Bid Summary presented in Table 8.1. The overall costs by tasks are presented in Table 8.2. The Project Cost Breakdown for Year 2008 is presented in Table 8.3 with the analytical breakdown for Year 2008 in Table 8.4. Year 2009 and 20010 have a 2% cost escalation. These costs will remain valid for 60 days. DEECO standard costs are presented in Table 8.5. However, as shown in Section 10, the delay rate will be $60 per man hour plus per diem ($100/day/man). TABLE 8.1 BID SUMMARY FOR YEARS 2008,2009 AND 2010, AND ENGINEERING TESTING I Task No.1 I Scope of Work I Costs * I or Year 2008 Federal Limits testing on Units 1, 2, & 3 $59,500 2009 Federal Limits testing on Units 1, 2, & 3 $60,600 2010 Federal Limits testing on Units 1, 2, & 3 $61,700 Mob/Demob Cost for Second Mob/Demob with XAD traps $4,000 and travel Engineering Total Cost of Testing on One Unit $11,500 Testing Field Staff of three Costs reflect reagent blank but no field blank * Note: Costs do not include audit samples. c c f/\ l~ Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 46 Revision No: 0 Date: December 1,2007 TABLE 8.2 OVERALL PROJECT COSTS BY TASK FOR COMPLIANCE TESTING I Task No. I Scope of Work I Costs I I Site Visit and Develop Protocol 2008 - No cost 2009 - No cost 2010 - No cost 2 Engineering test conducted on one boiler Field Staff of three $14,500 Costs reflects no field blank 2 Compliance test conducted on one boiler in 2008 - $57,500 accordance with the requirements under 40 CFR Tables 8.3 & 8.4 60.58b and 40 CFR 60.38b and NC DAQ 2009 - $58,600 (See Table 8.3 and 8.4 for details on 2006 2010 - $59,700 and 2009 and 2010 a 2% escalation) 4 Analysis of Audit Samples (cost not included) Method 23 $IIOO/sample Method 26 $50fsample Method 29 $500fsample 5 Compliance Test Report 2008,2009& 2010- $2,000 o o o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 47 Revision No: 0 Date: December 1, 2007 TABLE 8.3 PROJECT COST BREAKDOWN FOR YEAR 2008 I Task I Comments I Cost I Mobilization/Demobilization Preparation and calibrations $ 1,500 Travel Travel to and from Site Staff of 9 $ 1,000 Stack Sampling Testing with a staff of 9 $35,785 Including Setup Analytical Costs Stack Samples $19,215 From Table 8.4 Total Costs for Samuling and Analvtical Prol!l'am $57,500 TABLE 8.4 ANALYTICAL COST BREAKDOWN FOR YEAR 2005 Type of Parameter Cost per No. of Total Cost Samule Samule Samules Stack Gases Particulate $50 10 $ 500 Condensibles $100 7 $ 700 HCL $50 19* $ 950 Metals $150 10* $1,500 Mercury $235 19* $4,465 PCDD/PCDF $1,100 9** $9,900 XAD-2 Traps $100 12 $1,200 Total Analvtical Costs $19,215 * - Includes a reagent blank ** - Includes a field blank c c. c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 48 Revision No: 0 Date: December I, 2007 TABLE 8.5 BILLING INFORMATION FOR EMISSION TESTING-12/07 I. Hourlv Time Charge Rates Classification Program Director (Bill DeWees) Sr. Program Managers (Lee Cecchi, Scott Steinsberger) Senior Projects Managers (Marc Hamilton, John Martin) Field Team Leaders (Neil Adams, John Martin) Chemists (Barbara DeWees and Matt Winkeler) Senior Technician (R. Rhodes, M. Ossino, J. Fox K.McEenaney, C. Rhodes) RatelHour $95.00 $85.00 $65.00 $60.00 $50.00 $44.00 2. Time Charging The above rates represent all of DEE CO's direct salary costs, overhead, and profit. These rates are subject to periodic adjustment for merit and cost of living increases. The time charges for services performed will be the actual number of hours worked. Travel time shall be considered as work time. Time in excess of 8 hours per day will be billed at the same rate shown above. No extra overtime rate is charged. 3. Travel. Subsistence and Other Direct Costs Travel and subsistence expenses, long distance telephone calls, materials and supplies, and out-of-pocket expenses are to be paid for by Client at cost. 4. Charges for Automobile. Trucks & Vans Vehicle Type Daily Charge Daily Mileage Charge Vans $50.00 $0.45 per mile Trucksrrrailers $50.00 $0.45 per mile CEM Trailer (less than 3 monitors) $250.00 $0.45 per mile CEM Trailer (each additional monitor) $150.00 GCIFID/ECDrrCDIFPD $250.00 FTIR $750.00 Extra FTIR $3,000 per week Daily charges includes gasoline, maintenance, and insurance. Personal car mileage will be charged at the existing approved IRS rate, which is currently $0.40 per mile. Travel days are charged at half of the daily charge for CEM Trailers. c c o Air Emissions Compliance Test Program New Hanover County Dept of Enviromnental Management Wilmington, NC Page: 49 Revision No: 0 Date: December 1, 2007 SECTION 9. SAMPLING AND ANALYTICAL TEAM EXPERIENCE All field work will be conducted by experienced DEECO field staff. Mr. Bill DeWees (Mechanical Engineer and President) will be field team leader for most of the tasks. All of DEECO's permanent staff are current with HAZWOPR Training and are respirator certified. All staff will take the W ASTEC contractor orientation. DEECO has never had an on-site accident and has an EMR of 0.84. Subcontract Laboratories - Analysis of the Method 29 samples will be conducted by Element One lab. DEECO has used Element One on all MWC projects for the past three years. Method 23 stack samples and process samples will be conducted by Analytical Perspective Laboratories, Inc. DEECO has used Analytical Perspective for all MWC projects. Hydrogen chloride samples will be analyzed by DEECO. Method S gravimetric analysis will be conducted by DEECO. The key personnel on the field team proposed by DEECO have gained national recognition in the emissions measurement field. The Project Manager and Field Coordinator will be Mr. Bill DeWees. A description of DEE CO and reswnes of the key personnel proposed for this project are attached. A list of references are present in Table 9.1. Full resumes are attached. A short description of the key personnel is presented below: Proiect Manal!er and Field Coordinator (Bill DeWees) - Mr. DeWees has worked in the field of air pollution for 30 years and is the principal author of EPA's "Quality Assurance Handbook for Air Pollution Measurement Systems, Volume III, Stationary Source Specific Methods." As a result of the development of the handbook, quality assurance workshops, presentations, and participation in panels on quality assurance, Mr. DeWees has gained national recognition in the field of quality assurance for emission measurements and was inducted into the SES Hall of Fame, Mr. DeWees has directed/managed a large nwnber of tasks for the development and/or evaluation of EPA Reference Methods SA, SF, 18, 2S, 26, lOlA, and 202 and Draft Methods (1) hexavalent chromium, (2) HCL, (3) nickel speciation, (4) perchloroethylene, (S) high temperature/high moisture for chlorinated organics, (6) chloroform, (7) butadiene, (8) multiple metals, (9) condensibles, and (10) pathogens. Mr. DeWees has been the Project Manager and Field Team Leader on several BIF tests and/or Trial Bums. Mr. DeWees has conducted testing at Saugus and was the Project Manager for the ash sampling and analytical report developed for RESCO. Alternate Proiect Manaeer and Field Coordinator (Scott Steinsbereer) - Dr. Steinsberger developed/evaluated under EPA contract the majority of the MWC emissions testing methods (Multiple Metals, HCL, Hexavalent Chromium, and Dioxin/Furans), and is a principal author of the EP A Quality Assurance Handbook Sections on Mercury, Multiple Metals, Dioxin/Furans, and Method 18 organic sampling. Dr. Scott Steins berger, the field team leader for this task, was the c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 50 Revision No: 0 Date: December 1, 2007 developer/evaluator for many of the methods used for MWCs. He was the QA/QC officer on several of the EP A standard testing programs including the EP A/Canadian program. A few of the applicable publications have been brought forward and are shown below. He developed a TSDF solids sampling technique for landfills. Dr. Steinsberger developed/validated the HOMER system and Polar Volatile Organic Compound (PVOC) sampling system. Dr. Steinsberger specializes in the development and execution of Air Toxic Emission Measurement Programs. Dr. Steinsberger has been the Project Manager and Field Team Leader on several BIF tests and/or Trial Bums. Stack Coordinator (Marc Hamilton) - Mr. Hamilton is a Section Chief and Chemical Engineer. Mr. Hamilton has been a Project Manager for three years during which he worked on several Air Toxic projects. Mr, Hamilton has been a team leader on three BIF COC tests and about ten DfF CAA HAPs tests, He has been the Field Team Coordinator for large test crews. Sample Recovery (Matt Winkeler) -Mr. Winkeler is a chemist and the manager of DEE CO's wet laboratory. Mr. Winkeler has conducted numerous manual tests, However, his primary duties are sample recovery on air toxic test. Mr. Winkeler has conducted recovery for all methods in this program. C Because the DEECO staff developed/evaluated many of the BIF Methods including HCL, multiple metals, hexavalent chromium, and dioxin/furans, all of the staff have extensive testing experience in these methods. Some of the applicable publications on the methods are shown below: Reference for Method 26 Method 26 - Determination of Hydrogen Chloride Emissions from Stationary Sources 1. Steinsberger, S. C. and 1. H. Margeson, "Laboratory and Field Evaluation of a Methodology for Determination of Hydrogen Chloride Emissions from Municipal and Hazardous Waste Incinerators," V .S. Environmental Protection Agency, Office of Research and Development, Report No. 600/3-89/064, April 1989. Available from the National Technical Information Service, Springfield, VA 22161 as PB89220586/AS. Publications for Method 26 (HCL) "Laboratory and Field Evaluation of a Methodology for Measuring HCL Emissions from Stationary Sources," presented at the EP A/ AMW A 9th Annual International Symposium on Measurement of Toxic and Related Air Pollutants, Raleigh, N.C., May 1-5,1989. "Laboratory and Field Evaluation of a Methodology for Determination of Hydrogen Chloride Emissions from Municipal and Hazardous Waste Incinerators," V.S. EPA, Office of Research and C Development, Report No. 600/3-89/064, April, 1989. c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 51 Revision No: 0 Date: December I, 2007 "Laboratory Evaluation of a Gas Chromatographic/Electrolytic Conductivity Detector Method for Hydrogen Chloride Gas Cylinder Analysis," for presentation at the EP AI A WMA International Symposium on Measurement of Toxic and Related Air Pollutants, Raleigh, N.C. May 1-5, 1989. Publications for Method 29 (Metals) "Measurement Methodology for Toxic Metals from Municipal Waste Combustors." Conference Proceedings, International Conference on Municipal Waste Combustion, Hollywood, Florida, April 11-14,1989. "Sampling and Analysis of Municipal Wastewater Sludge Incinerator Emissions for Metals, Metal Species, and Organics," for presentation at the 83rd Annual Meeting of the Air & Waste Management Association, Pittsburgh, Pennsylvania. June 24-29, 1990. "Measurement Methodology for Stationary Source Toxic Metal Emissions," presented at the 82nd Annual Meeting of the Air Pollution Control Association, Anaheim, California, June 25-30, 1989. Publications for Method 23 (Dioxin/Furans) c "Development and Implementation ofEPA Dioxin/Furan Emission Testing Performance Audit Program," Conference Proceedings, International Conference on Municipal Waste Combustion, Hollywood, Florida, April 11-14, 1989. "Development of EP A's Polychlorinated Dibenzo-p-dioxins and Polychlorinated dibenzofurans Performance Audit Materials for MWCs", to be published in Chemosphere. "Sampling and Analysis of Municipal Wastewater Sludge Incinerator Emissions for Metals, Metal Species, and Organics," for presentation at the 83rd Annual Meeting of the Air & Waste Management Association, Pittsburgh, Pennsylvania. June 24-29, 1990. Publications on testing MWC's and Incinerators "Recommended QAlQC for Municipal Waste Combustor Testing," presented at the 82nd Annual Meeting of the Air Pollution Control Association, Anaheim, California, June 25-30, 1989. "Guideline for Preparation and Review of Site Specific Test Plans", EP A Contract No. 68D90055, U.S. EPA, Research Triangle Park, NC 27711, May 1991. "External Quality Assurance/Quality Control Project Plan for Joint U.S. EP A/Environment Canada Municipal Refuse-Derived Fuel Combustor Characterization and Performance Test Program," Mid- o Connecticut Resource Recovery Facility, Hartford, Connecticut, Dec 1988. c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 52 Revision No: 0 Date: December 1, 2007 Publications on PMI0 and condensibles "PMIO Emissions from Stationary Sources -- How Do We Define, Measure, Control, and Regulate Them?" paper presented at 78th Annual Meeting ofthe Air Pollution Control Association, Detroit, Michigan, June 1985. "Laboratory and Field Evaluation of the EP A Method 5 Impinger Catch for Measuring Condensible Matter from Stationary Sources," presented at the EP AI AMW A 9th Annual International Symposium on Measurement of Toxic and Related Air Pollutants, Raleigh, N.C. 1-5, 1989. Publications on QAlQC for Methods in this program "Quality Assurance Handbook for Air Pollution Measurement Systems: Volume III, Stationary Source Specific Methods," EP A Publication No. 600/4-77-027b. The sections developed include: Method 2 - Determination of Stack Gas Velocity and Volumetric Flow Rate Method 3 - Determination of Carbon Dioxide, Oxygen, Excess Air, and Dry Molecular Weight Method 4 - Determination of Moisture in Stack Gases Method 5 - Determination of Particulate Emissions from Stationary Sources Method 6 - Determination of Sulfur Dioxide Emissions from Stationary Sources Method 8 - Determination of Sulfuric Acid Mist and Sulfur Dioxide Emissions from Stationary Sources Method 10 - Determination of Carbon Monoxide Emissions from Stationary Sources 3,1 3.2 C 3.3 3.4 3.5 3.7 3.8 3.12 Method 9 - Visible Determination of the Opacity of Emissions from Stationary Sources 3.16 Method 18 - Measurement of Gaseous Organic Compound Emissions by Gas Chromatography 3.18 Method 23 - Determination of Polychorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans for Municipal Waste Combustors 3.19 Method 10 IA - Determination of Particulate and Gaseous Mercury Emissions from Stationary Sources 3.20 Method 29 - Determination of Metal Emissions from Stationary Sources c c c o Air Emissions Compliance Test Program New Hanover County Dept of Enviromnental Management Wilmington, NC Page: 53 Revision No: 0 Date: December 1, 2007 TABLE 9.1 DEECO'S MWC TESTING EXPERIENCE Wheelabrator Gloucester - Westville, NJ - 1998, 1999, 2000, 2001, 2002,2003,2004,2005 2006,2007, and Scheduled 2008 Test Type: Contact: Compliance Test Richard Falk (603) 929-3000 Field Staff of 9 Methods 3A, 5, 6C, 7E, 9,10,22,23, 26A, and 29 Wheelabrator Falls - Morrisville, PA -1998,1999,2000,2001, 2002,2003,20042005 2006, 2007, and Scheduled 2008 Compliance Test and RATA Alan Lewis (215) 736-1760 Field Staff of 13 Methods 5, 6C, 7E, 9, 10,22, 25A, 26A, 23, 29, and 0013 Test Type: Contact: Massachusetts Refusetech, Inc - North Andover, MA - 1998, 1999, 2000, 2001, 2002, 2003, 2004, 2006, 2006, 2007, and Scheduled 2008 Compliance Test Peter Marrinan (978) 688-9011 Field Staff of! 0 Methods 5, 9, 13B, 22, 23, 26A, and 29 Test Type: Contact: RESCO SAUGUS - Saugus, MA - 1999,2000,2001,2002,2003, 2004,2005 2006, 2007, and Scheduled 2008 Compliance Test Jack Stark Field Staff of 9 Methods 3A, 5, 6C, 7E, 8, 9, 13B, 22, 10,23, and 29 Test Type: Contact: Wheelabrator Millbury Inc. - Millbury, MA - 1998, 1999,2000,2001 & 2002, 2003 2004,2005,2006,2007, and Scheduled 2008 Compliance Test and RATA Steve Sibinich (508) 791-8900 Field Staff of 9 Methods 3A, 5, 6C, 7E, 8, 13B, 10,23,29 & RATA Test Type: Contact: WASTEC - New Hanover County, NC - 2002, 2003, 2004, 2005 & 2007 Test Type: Compliance Test and RATA Contact: Paul Marlow (910) 341-4340 Field Staff of 7 Methods 3A, 5, 6C, 7E, 9, 10,22,23, 26A, & 2 o G o Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 54 Revision No: 0 Date: December 1, 2007 TABLE 9.1 DEECO'S MWC TESTING EXPERIENCE (cont.) Riley Energy Systems Inc. - Lisbon, CT - 1999, 2000 & 2002, 2003, 2004, 2005 2006, and 2007 Test Type: Contact: Compliance Test John Pasutto (860) 885-3512 Field Staff of 5 Methods 3, 5, 26A, & 29 Wheelabrator Concord - Concord, NH - 1999,2000,2001,2002,2003,2004,2005 2006, 2007, and Scheduled 2008 Test Type: Contact: Compliance Test Robert Faia (603) 753-8411 Field Staff of 8 Methods 3, 5, 9, 22, 23, 26A, & 29 Wheelabrator Claremont - Claremont, NH - 2000, 2005, 2006 and 2007 Test Type: Compliance Test Contact: Robert Faia (603) 753-8411 Field Staff of 7 Methods 3A, 5, 6C, 7E, 10, 23, 26A, & 29 Wheelabrator Spokane - Spokane, W A - 2000, 2001, 2003, 2004, 2005, 2006 & 2007 Test Type: Compliance Test and RATA Contact: Damon Taam (509) 456-7403 Field Staff of? Methods 3A, 5, 6C, 7E, 9, 10,22,23, 26A, & 29 Savannah Energy System Co - Savannah, GA - 2001, 2002, 2003, 2004, 2006 & 2007 Test Type: Compliance Test and RATA Contact: Joel Millsap (912) 236-1014 Field Staff of 7 Methods 3, 5, 9, 22, 23, 26A, & 29 Wheelabrator Bridgeport - Bridgeport, CT - 2004, 2005, 2006 & 2007 Test Type: Compliance Test Contact: Steve Bennett (509) 624-6575 Field Staff of 10 Methods 3, 5, 9, 10,22,23, 26A, & 29 o c c Air Emissions Compliance Test Program New Hanover County Dept of Environmental Management Wilmington, NC Page: 55 Revision No: 0 Date: December I, 2007 SECTION 10. TERMS AND CONDITIONS Our terms of payment are net 55 days from date the facility receives the invoice. Invoicing will be 100% upon completion of sampling for each task. This quote will be in effect until March, 30, 2008. A delay rate of $60.00 per man-hour, if applicable, for any delays in testing which are beyond the control of DEECO as described in Section 7 above.